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    • 2. 发明授权
    • Flame-retardant thermoplastic resin composition and molded article thereof
    • 阻燃热塑性树脂组合物及其成型品
    • US08609754B2
    • 2013-12-17
    • US13510820
    • 2010-11-18
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • C08L51/04
    • C08L25/12C08K5/523C08L33/18C08L55/02C08L2201/02C08L2666/24
    • Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
    • 本发明提供一种阻燃热塑性树脂组合物,其中不使用任何卤化阻燃剂,但使用磷阻燃剂,其阻燃性符合美国UL标准94V-2,其在燃烧时表现出优异的滴水性能, 性能之间的平衡优异。 阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物,乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物(A)和乙烯基共聚物(B)的共聚物混合物, 通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物,其质均分子量为90,000至160,000,和5至20质量份与共聚物混合物共混的磷阻燃剂(C)。 共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量%,丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量%, | CB1-CB2 | 为0〜3.0质量%。
    • 3. 发明申请
    • REINFORCED THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE
    • 增强热塑性树脂组合物和成型品
    • US20120178860A1
    • 2012-07-12
    • US13497758
    • 2010-09-24
    • Masahito NakamotoKoichi Tezuka
    • Masahito NakamotoKoichi Tezuka
    • C08K5/521C08L51/04
    • C08L69/00C08K5/521C08K9/04C08K9/08C08L51/04C08L55/02C08L2666/24
    • The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.
    • 本发明的增强热塑性树脂组合物包含:50〜90重量%的聚碳酸酯树脂(A); 10重量%至50重量%的接枝共聚物混合物(B)(条件是组分(A)和组分(B)的总量占100重量%),其通过将芳族链烯基化合物 单体单元(a)和乙烯基氰化合物单体单元(b)加到橡胶聚合物(B1)上; 和6〜22重量份用水溶性聚酰胺表面处理的无机填料(D)相对于聚碳酸酯树脂(A)和接枝共聚物混合物(B)总计100重量份 )。 本发明提供一种增塑热塑性树脂组合物,其具有优异的成型性,在成型时产生最少量的气体,并且还能够提高所得模塑制品的刚性和降低产品时的耐冲击性。
    • 10. 发明申请
    • FLAME-RETARDANT THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
    • 阻燃热塑性树脂组合物及其制品
    • US20120245261A1
    • 2012-09-27
    • US13510820
    • 2010-11-18
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • Yoshitaka NaitoShigeki HamamotoHirotoshi SaitoHiroshi TanigawaJoichi WatanabeKoichi TezukaMasahito Nakamoto
    • C08L9/06C08K5/52
    • C08L25/12C08K5/523C08L33/18C08L55/02C08L2201/02C08L2666/24
    • Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
    • 本发明提供一种阻燃热塑性树脂组合物,其中不使用任何卤化阻燃剂,但使用磷阻燃剂,其阻燃性符合美国UL标准94V-2,其在燃烧时表现出优异的滴水性能, 性能之间的平衡优异。 阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物,乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物(A)和乙烯基共聚物(B)的共聚物混合物, 通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物,其质均分子量为90,000至160,000,和5至20质量份与共聚物混合物共混的磷阻燃剂(C)。 共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量%,丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量%, | CB1-CB2 | 为0〜3.0质量%。