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1. 发明授权

US08609754B2 Flame-retardant thermoplastic resin composition and molded article thereof 有权
标题翻译：阻燃热塑性树脂组合物及其成型品
公开(公告)号：US08609754B2
公开(公告)日：2013-12-17
申请号：US13510820
申请日：2010-11-18
申请人： Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
发明人： Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
IPC分类号： C08L51/04
CPC分类号： C08L25/12 , C08K5/523 , C08L33/18 , C08L55/02 , C08L2201/02 , C08L2666/24
摘要： Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
摘要翻译：本发明提供一种阻燃热塑性树脂组合物，其中不使用任何卤化阻燃剂，但使用磷阻燃剂，其阻燃性符合美国UL标准94V-2，其在燃烧时表现出优异的滴水性能，性能之间的平衡优异。阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物，乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物（A）和乙烯基共聚物（B）的共聚物混合物，通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物，其质均分子量为90,000至160,000，和5至20质量份与共聚物混合物共混的磷阻燃剂（C）。共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量％，丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量％， | CB1-CB2 | 为0〜3.0质量％。

2. 发明申请

US20120245261A1 FLAME-RETARDANT THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 有权
标题翻译：阻燃热塑性树脂组合物及其制品
公开(公告)号：US20120245261A1
公开(公告)日：2012-09-27
申请号：US13510820
申请日：2010-11-18
申请人： Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
发明人： Yoshitaka Naito , Shigeki Hamamoto , Hirotoshi Saito , Hiroshi Tanigawa , Joichi Watanabe , Koichi Tezuka , Masahito Nakamoto
IPC分类号： C08L9/06 , C08K5/52
CPC分类号： C08L25/12 , C08K5/523 , C08L33/18 , C08L55/02 , C08L2201/02 , C08L2666/24
摘要： Provided is a flame-retardant thermoplastic resin composition in which any halogenated flame retardant is not used but a phosphoric flame retardant is used, which has flame retardancy meeting U.S. UL Standard 94 V-2, which exhibits excellent dripping performance during burning, and which is excellent in balance between properties. The flame-retardant thermoplastic resin composition contains 100 parts by mass of a copolymer mixture containing a graft copolymer (A) obtained by graft-polymerizing a rubbery polymer, a vinyl cyanide compound, and a copolymerizable vinyl compound and a vinyl copolymer (B) which is obtained by copolymerizing the vinyl cyanide compound and the copolymerizable vinyl compound and which has a mass-average molecular weight of 90,000 to 160,000 and 5 to 20 parts by mass of a phosphoric flame retardant (C) blended with the copolymer mixture. The content CB1 of vinyl cyanide units in the acetone-insoluble fraction of the copolymer mixture is 22.0% to 32.0% by mass, the content CB2 of vinyl cyanide units in the acetone-soluble fraction thereof is 22.0% to 34.0% by mass, and |CB1−CB2| is 0% to 3.0% by mass.
摘要翻译：本发明提供一种阻燃热塑性树脂组合物，其中不使用任何卤化阻燃剂，但使用磷阻燃剂，其阻燃性符合美国UL标准94V-2，其在燃烧时表现出优异的滴水性能，性能之间的平衡优异。阻燃性热塑性树脂组合物含有100质量份含有通过使橡胶状聚合物，乙烯基氰化合物和可共聚乙烯基化合物接枝聚合得到的接枝共聚物（A）和乙烯基共聚物（B）的共聚物混合物，通过共聚合乙烯基氰化合物和可共聚的乙烯基化合物，其质均分子量为90,000至160,000，和5至20质量份与共聚物混合物共混的磷阻燃剂（C）。共聚物混合物的丙酮不溶级分中的乙烯基氰单元的含量CB1为22.0〜32.0质量％，丙酮可溶成分中的乙烯基氰单元的含量CB2为22.0〜34.0质量％， | CB1-CB2 | 为0〜3.0质量％。

3. 发明申请

US20120178860A1 REINFORCED THERMOPLASTIC RESIN COMPOSITION AND MOLDED ARTICLE 有权
标题翻译：增强热塑性树脂组合物和成型品
公开(公告)号：US20120178860A1
公开(公告)日：2012-07-12
申请号：US13497758
申请日：2010-09-24
申请人： Masahito Nakamoto , Koichi Tezuka
发明人： Masahito Nakamoto , Koichi Tezuka
IPC分类号： C08K5/521 , C08L51/04
CPC分类号： C08L69/00 , C08K5/521 , C08K9/04 , C08K9/08 , C08L51/04 , C08L55/02 , C08L2666/24
摘要： The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.
摘要翻译：本发明的增强热塑性树脂组合物包含：50〜90重量％的聚碳酸酯树脂（A）; 10重量％至50重量％的接枝共聚物混合物（B）（条件是组分（A）和组分（B）的总量占100重量％），其通过将芳族链烯基化合物单体单元（a）和乙烯基氰化合物单体单元（b）加到橡胶聚合物（B1）上; 和6〜22重量份用水溶性聚酰胺表面处理的无机填料（D）相对于聚碳酸酯树脂（A）和接枝共聚物混合物（B）总计100重量份）。本发明提供一种增塑热塑性树脂组合物，其具有优异的成型性，在成型时产生最少量的气体，并且还能够提高所得模塑制品的刚性和降低产品时的耐冲击性。

4. 发明授权

US08507586B2 Reinforced thermoplastic resin composition and molded article 有权
公开(公告)号：US08507586B2
公开(公告)日：2013-08-13
申请号：US13497758
申请日：2010-09-24
申请人： Masahito Nakamoto , Koichi Tezuka
发明人： Masahito Nakamoto , Koichi Tezuka
IPC分类号： C08K9/04
摘要： The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.

5. 发明申请

US20100273922A1 Reinforced Thermoplastic Resin Composition And Molded Article 有权
标题翻译：增强热塑性树脂组合物和成型品
公开(公告)号：US20100273922A1
公开(公告)日：2010-10-28
申请号：US12810400
申请日：2008-12-26
申请人： Iwao Fujimoto , Emiko Fujimoto , Koichi Tezuka , Masahito Nakamoto
发明人： Iwao Fujimoto , Emiko Fujimoto , Koichi Tezuka , Masahito Nakamoto
IPC分类号： C08K5/521 , C08L51/00
CPC分类号： C08L67/02 , C08K3/013 , C08K5/521 , C08L25/12 , C08L51/04 , C08L55/02 , C08L63/00 , C08L67/00 , C08L69/00 , C08L2205/03 , C08L2666/02
摘要： The present invention relates to a reinforced thermoplastic resin composition having excellent moldability, processability, and mechanical strengths, as well as being capable of improving the drop impact resistance (surface impact strength determined by a falling ball test). The reinforced thermoplastic resin composition of the present invention includes 10 to 60% by mass of a graft copolymer (A) having a graft chain (A2) grafted to a rubber polymer (A1); 40 to 90% by mass of a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); 0.1 to 50 parts by mass of an inorganic filler (D) and 0.5 to 20 parts by mass of a glycidyl ether unit-containing polymer (E) having a mass average molecular weight of 3,000 to 200,000.
摘要翻译：本发明涉及成型性，加工性和机械强度优异的增强热塑性树脂组合物，以及能够提高耐滴落冲击性（通过落球试验测定的表面冲击强度）。本发明的增强热塑性树脂组合物含有10〜60质量％的接枝共聚物（A），其具有接枝到橡胶聚合物（A1）上的接枝链（A2）; 40〜90质量％的基质聚合物（B），其包含选自乙烯基类共聚物（B-1），聚碳酸酯树脂（B-2）和聚酯中的一种以上的聚合物树脂（B-3）; 0.1〜50质量份无机填料（D）和0.5〜20质量份的质均分子量为3,000〜200,000的含缩水甘油醚单元的聚合物（E）。

6. 发明授权

US09725591B2 Reinforced resin composition for plating base, molded article, and electroplated component 有权
公开(公告)号：US09725591B2
公开(公告)日：2017-08-08
申请号：US12810409
申请日：2008-12-26
申请人： Koichi Tezuka , Iwao Fujimoto , Emiko Fujimoto , Masahito Nakamoto
发明人： Koichi Tezuka , Iwao Fujimoto , Masahito Nakamoto
IPC分类号： C25D5/56 , C08L25/12 , C08L69/00 , C08L67/02 , C08L55/02 , C08L51/04 , C08L67/00 , C08L63/00
CPC分类号： C08L67/02 , C08L25/12 , C08L51/04 , C08L55/02 , C08L63/00 , C08L67/00 , C08L69/00 , C08L2205/03 , C08L2666/02 , C25D5/56
摘要： The present invention relates to a reinforced resin composition for plating bases having excellent moldability, mechanical strengths, and plating ability, as well as being capable of improving the surface appearance of the molded article after plating. The reinforced resin composition for plating bases of the present invention includes: graft copolymer (A) in which a graft chain (A2) is grafted to a rubber polymer (A1) a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); an inorganic filler (D); and a glycidyl ether unit-containing polymer (E). The content of the rubber polymer (A1) is from 5 to 25% by mass, relative to 100% by mass of the total amount of the component of (A) and the component of the matrix polymer (B).

7. 发明授权

US08877854B2 Reinforced thermoplastic resin composition and molded article 有权
标题翻译：增强热塑性树脂组合物和模制品
公开(公告)号：US08877854B2
公开(公告)日：2014-11-04
申请号：US12810400
申请日：2008-12-26
申请人： Koichi Tezuka , Masahito Nakamoto , Emiko Fujimoto
发明人： Iwao Fujimoto , Koichi Tezuka , Masahito Nakamoto
IPC分类号： C08L69/00 , C08L67/00 , C08L67/02 , C08L63/00 , C08L55/02 , C08L51/04 , C08L25/12 , C08K3/00 , C08K5/521
CPC分类号： C08L67/02 , C08K3/013 , C08K5/521 , C08L25/12 , C08L51/04 , C08L55/02 , C08L63/00 , C08L67/00 , C08L69/00 , C08L2205/03 , C08L2666/02
摘要： The present invention relates to a reinforced thermoplastic resin composition having excellent moldability, processability, and mechanical strengths, as well as being capable of improving the drop impact resistance (surface impact strength determined by a falling ball test). The reinforced thermoplastic resin composition of the present invention includes 10 to 60% by mass of a graft copolymer (A) having a graft chain (A2) grafted to a rubber polymer (A1); 40 to 90% by mass of a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); 0.1 to 50 parts by mass of an inorganic filler (D); and 0.5 to 20 parts by mass of a glycidyl ether unit-containing polymer (E) having a mass average molecular weight of 3,000 to 200,000.
摘要翻译：本发明涉及成型性，加工性和机械强度优异的增强热塑性树脂组合物，以及能够提高耐滴落冲击性（通过落球试验测定的表面冲击强度）。本发明的增强热塑性树脂组合物含有10〜60质量％的接枝共聚物（A），其具有接枝到橡胶聚合物（A1）上的接枝链（A2）; 40〜90质量％的基质聚合物（B），其包含选自乙烯基类共聚物（B-1），聚碳酸酯树脂（B-2）和聚酯中的一种以上的聚合物树脂（B-3）; 0.1〜50质量份无机填料（D）; 和0.5〜20质量份的质均分子量为3,000〜200,000的含缩水甘油醚单元的聚合物（E）。

8. 发明授权

US08536248B2 Reinforced thermoplastic resin composition and molded article 有权
标题翻译：增强热塑性树脂组合物和模制品
公开(公告)号：US08536248B2
公开(公告)日：2013-09-17
申请号：US13497758
申请日：2010-09-24
申请人： Masahito Nakamoto , Koichi Tezuka
发明人： Masahito Nakamoto , Koichi Tezuka
IPC分类号： C08K9/04
CPC分类号： C08L69/00 , C08K5/521 , C08K9/04 , C08K9/08 , C08L51/04 , C08L55/02 , C08L2666/24
摘要： The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.
摘要翻译：本发明的增强热塑性树脂组合物包含：50〜90重量％的聚碳酸酯树脂（A）; 10重量％至50重量％的接枝共聚物混合物（B）（条件是组分（A）和组分（B）的总量占100重量％）是通过将芳族链烯基化合物单体单元（a）和乙烯基氰化合物单体单元（b）加到橡胶聚合物（B1）上; 和6〜22重量份用水溶性聚酰胺表面处理的无机填料（D）相对于聚碳酸酯树脂（A）和接枝共聚物混合物（B）总计100重量份）。本发明提供一种增塑热塑性树脂组合物，其具有优异的成型性，在成型时产生最少量的气体，并且还能够提高所得模塑制品的刚性和降低产品时的耐冲击性。

9. 发明申请

US20100276289A1 Reinforced Resin Composition For Plating Base, Molded Article, And Electroplated Component 有权
标题翻译：用于电镀基底，模制品和电镀组件的增强树脂组合物
公开(公告)号：US20100276289A1
公开(公告)日：2010-11-04
申请号：US12810409
申请日：2008-12-26
申请人： Koichi Tezuka , Iwao Fujimoto , Emiko Fujimoto , Masahito Nakamoto
发明人： Koichi Tezuka , Iwao Fujimoto , Emiko Fujimoto , Masahito Nakamoto
IPC分类号： C08L51/00 , B32B15/08
CPC分类号： C08L67/02 , C08L25/12 , C08L51/04 , C08L55/02 , C08L63/00 , C08L67/00 , C08L69/00 , C08L2205/03 , C08L2666/02 , C25D5/56
摘要： The present invention relates to a reinforced resin composition for plating bases having excellent moldability, mechanical strengths, and plating ability, as well as being capable of improving the surface appearance of the molded article after plating. The reinforced resin composition for plating bases of the present invention includes: graft copolymer (A) in which a graft chain (A2) is grafted to a rubber polymer (A1) a matrix polymer (B) which includes one or more types of polymers selected from the group consisting of a vinyl-based copolymer (B-1), a polycarbonate resin (B-2), and a polyester resin (B-3); an inorganic filler (D); and a glycidyl ether unit-containing polymer (E). The content of the rubber polymer (A1) is from 5 to 25% by mass, relative to 100% by mass of the total amount of the component of (A) and the component of the matrix polymer (B).
摘要翻译：本发明涉及具有优异的成型性，机械强度和电镀能力的电镀基材用增强树脂组合物，并且能够改善镀覆后的成形品的表面外观。本发明的电镀用增强树脂组合物包括：接枝共聚物（A），其中将接枝链（A2）接枝到橡胶聚合物（A1）上的基质聚合物（B），其包含一种或多种选择的聚合物来自由乙烯基类共聚物（B-1），聚碳酸酯树脂（B-2）和聚酯树脂（B-3）组成的组; 无机填料（D）; 和含缩水甘油醚单元的聚合物（E）。相对于（A）的成分和基质聚合物（B）的成分的总量的100质量％，橡胶聚合物（A1）的含量为5〜25质量％。

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