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1. 发明授权

US5688437A Liquid crystal composition, liquid crystal device using the composition, liquid crystal apparatus and display method 失效
标题翻译：液晶组合物，使用组合物的液晶装置，液晶装置和显示方法
公开(公告)号：US5688437A
公开(公告)日：1997-11-18
申请号：US422262
申请日：1995-04-14
申请人： Koichi Sato , Hiroyuki Kitayama , Kenji Shinjo , Katsutoshi Nakamura , Shinichi Nakamura
发明人： Koichi Sato , Hiroyuki Kitayama , Kenji Shinjo , Katsutoshi Nakamura , Shinichi Nakamura
IPC分类号： C09K19/34 , C09K19/12 , C09K19/20 , C09K19/32
CPC分类号： C09K19/34
摘要： A liquid crystal composition includes a liquid crystal containing at least one mesomorphic compound having a cholesteric phase (Ch phase)-free mesomorphic phase, and at least one compound (e) having a limit of solubility in the liquid crystal and being contained in the composition in a proportion ranging from 20% of the limit of solubility to below the limit of solubility. The liquid crystal composition may preferably include the liquid crystal containing at least one fluorine-containing mesomorphic compound (a) having a fluorocarbon terminal portion and a hydrocarbon terminal portion, and at least one achiral compound (b), a the compound (e), having a specific ring structure and a specific terminal alkyl group free from a perfluorocarbon atom. The compound having a Ch phase-free mesomorphic phase, preferably the compound (a), and the compound (e), preferably the compound (b) are effective in providing the liquid crystal composition with a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.
摘要翻译：液晶组合物包括含有至少一种具有胆甾型相（Ch相） - 自由相态的介晶化合物的液晶和至少一种在液晶中具有极限溶解性并包含在该组合物中的化合物（e）其比例范围从溶解度的20％到低于溶解度的极限。液晶组合物可以优选包含含有至少一种含氟碳末端部分和烃末端部分的含氟介晶化合物（a）的液晶，以及至少一种非手性化合物（b），化合物（e），具有特定的环结构和不含全氟化碳原子的特定末端烷基。具有Ch相无介晶相的化合物，优选化合物（a）和化合物（e），优选化合物（b））有效地为所述液晶组合物提供所谓书架或层结构具有较小的倾斜角度（更靠近书架结构）。液晶组合物可用于改善使用液晶组合物的液晶装置的响应特性和显示特性，特别是对比度。

2. 发明授权

US5948317A Liquid crystal composition, liquid crystal device using the composition, liquid crystal apparatus and display method 失效
标题翻译：液晶组合物，使用组合物的液晶装置，液晶装置和显示方法
公开(公告)号：US5948317A
公开(公告)日：1999-09-07
申请号：US971163
申请日：1997-11-14
申请人： Koichi Sato , Hiroyuki Kitayama , Kenji Shinjo , Shinichi Nakamura , Katsutoshi Nakamura
发明人： Koichi Sato , Hiroyuki Kitayama , Kenji Shinjo , Shinichi Nakamura , Katsutoshi Nakamura
IPC分类号： C09K19/04 , C09K19/34 , C09K19/42 , C09K19/58 , G02F1/1337
CPC分类号： G02F1/133723 , C09K19/04 , C09K19/3469 , C09K19/42 , C09K19/588 , C09K2019/044
摘要： A liquid crystal composition includes at least one fluorine-containing mesomorphic compound (a) having a fluorocarbon terminal portion and a hydrocarbon terminal portion, and at least one optically active compound (b) having an optically active cyclic group and a terminal alkyl group free from a perfluorocarbon atom. The compound (a) and the compound (b) are mutually soluble readily to form a homogeneous liquid crystal composition. The liquid crystal composition shows a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.
摘要翻译：液晶组合物包含至少一种具有碳氟化合物末端部分和烃末端部分的含氟介晶化合物（a）和至少一种光学活性化合物（b），其具有光学活性的环状基团和不具有全氟化碳原子。化合物（a）和化合物（b）易于溶解以形成均匀的液晶组合物。液晶组合物显示出所谓书架的层结构或具有较小倾斜角（更靠近书架结构）的层结构。液晶组合物可用于改善使用液晶组合物的液晶装置的响应特性和显示特性，特别是对比度。

3. 发明授权

US5186858A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5186858A
公开(公告)日：1993-02-16
申请号：US378922
申请日：1989-07-12
申请人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Kazuharu Katagiri , Takao Takiguchi , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
发明人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Kazuharu Katagiri , Takao Takiguchi , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
IPC分类号： C09K19/30 , C09K19/34 , C09K19/42
CPC分类号： C09K19/3066 , C09K19/3458 , C09K19/42
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein, R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.2 denotes a linear alkyl group having 1-12 carbon atoms; X.sub.1 denote a single bond, --O--, ##STR2## respectively denote ##STR3## and at least one compound represented by the following formula (II): ##STR4## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; X.sub.2 and X.sub.3 respectively denote a single bond, --O--, ##STR5## and m and n are respectively 0, 1 or 2 with proviso that m+n is 2 or above.
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中，R 1表示可具有取代基的具有1-18个碳原子的直链或支链烷基; R2表示具有1-12个碳原子的直链烷基; X1表示单键，-O-，分别表示和至少一种由下式（II）表示的化合物：其中R 3和R 4分别表示直链或具有1-18个能够具有取代基的碳原子的支链烷基; X2和X3分别表示单键，-O-，，m和n分别为0,1或2，条件是m + n为2或更高。

4. 发明授权

US5405553A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5405553A
公开(公告)日：1995-04-11
申请号：US76931
申请日：1993-06-16
申请人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takao Takiguchi , Masanobu Asaoka , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
发明人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takao Takiguchi , Masanobu Asaoka , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
IPC分类号： C09K19/34 , C09K19/46 , C07D239/02 , G02F1/13
CPC分类号： C09K19/46 , C09K19/3441
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, at least one of R.sub.1 and R.sub.2 being optically active; X.sub.1 denotes --O--, ##STR2## and X.sub.2 denotes a single bond, --O--, ##STR3## and at least one compound represented by the following formula (II): ##STR4## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched optically inactive alkyl group having 1-18 carbon atoms capable of having an alkoxy group of 1-12 carbon atoms; X.sub.3 and X.sub.4 respectively denote a single bond, --O--, ##STR5## and m and n are respectively 0, 1 or 2 with proviso that both of m and n are not 0.
摘要翻译：包含至少一种由下式（I）表示的光学活性化合物的铁电手性近晶液晶组合物：具有能够具有取代基的具有1-18个碳原子的直链或支链烷基，R 1和R 2中的至少一个光学活性; X1表示-O-，，X2表示单键，-O-，和由下式（II）表示的至少一种化合物：其中R 3和R 4分别表示具有能够具有1-12个碳原子的烷氧基的具有1-18个碳原子的直链或支链的非光学惰性烷基; X3和X4分别表示单键，-O-，，m和n分别为0,1或2，条件是m和n均不为0。

5. 发明授权

US5173211A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5173211A
公开(公告)日：1992-12-22
申请号：US378824
申请日：1989-07-12
申请人： Masataka Yamashita , Takeshi Togano , Masahiro Terada , Akio Yoshida , Yoshiko Kimura , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
发明人： Masataka Yamashita , Takeshi Togano , Masahiro Terada , Akio Yoshida , Yoshiko Kimura , Kenji Shinjo , Hiroyuki Kitayama , Shinichi Nakamura
IPC分类号： C09K19/42
CPC分类号： C09K19/42
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; and X.sub.1 denotes a single bond, ##STR2## and at least one optically active compound represented by the following formula (II): ##STR3## wherein R.sub.3 denotes a linear alkyl group having 1-14 carbon atoms; R.sub.4 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; and X.sub.2 denotes a single bond, ##STR4##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的光学活性化合物：其中R 1表示具有1-18个碳原子的具有取代基的直链或支链烷基 ; R2表示可具有取代基的具有1-14个碳原子的直链或支链烷基; 并且X1表示单键，和下式（II）表示的至少一种光学活性化合物：其中R 3表示具有1-14个碳原子的直链烷基; R4表示可具有取代基的具有1-14个碳原子的直链或支链烷基; X2表示单键，

6. 发明授权

US5885482A Liquid crystal device, production process thereof and liquid crystal apparatus 失效
标题翻译：液晶装置及其制造方法以及液晶装置
公开(公告)号：US5885482A
公开(公告)日：1999-03-23
申请号：US775792
申请日：1996-12-27
申请人： Masanobu Asaoka , Yukio Hanyu , Kenji Shinjo , Koichi Sato , Masahiro Terada , Shosei Mori , Shinichi Nakamura , Syuji Yamada , Ikuo Nakazawa , Koji Noguchi
发明人： Masanobu Asaoka , Yukio Hanyu , Kenji Shinjo , Koichi Sato , Masahiro Terada , Shosei Mori , Shinichi Nakamura , Syuji Yamada , Ikuo Nakazawa , Koji Noguchi
IPC分类号： C09K19/04 , G02F1/1337 , G02F1/1339 , G02F1/141 , C09K19/56 , C09K19/52
CPC分类号： G02F1/13392 , C09K19/04 , G02F1/1337 , G02F1/141 , G02F2001/13373
摘要： A liquid crystal device is constituted by a pair of oppositely disposed substrates including a first substrate provided with a first alignment control layer which has been subjected to a uniaxial aligning treatment and a second substrate provided with a second alignment control layer which has not been subjected to a uniaxial aligning treatment, a sealing member disposed so as to seal up a peripheral portion of the first and second substrates to form a spacing therebetween, and a dispersion member (e.g., spacer beads or adhesive particles) and a liquid crystal disposed in the spacing while contacting the first and second aligning control layers. The dispersion member has been subjected to a surface treatment with a material constituting the second alignment control layer. The surface-treated dispersion member is effective in suppressing an occurrence of a reverse domain within a display region of the liquid crystal device, thus preventing flickering and improving a contrast.
摘要翻译：液晶装置由一对相对设置的基板构成，该基板包括：第一基板，设置有经受单轴取向处理的第一取向控制层;以及第二基板，设置有未经受单轴取向处理，密封构件，其被设置为密封第一和第二基板的周边部分以在其间形成间隔;以及分散构件（例如间隔珠或粘合剂颗粒）和以间隔设置的液晶同时接触第一和第二对准控制层。分散体已经用构成第二取向控制层的材料进行了表面处理。经表面处理的分散体有效地抑制液晶显示装置的显示区域内的反向畴的发生，防止闪烁，提高对比度。

7. 发明授权

US5354501A Mesomorphic compound, liquid crystal composition, liquid crystal device, display apparatus and display method 失效
标题翻译：介晶化合物，液晶组合物，液晶装置，显示装置及显示方法
公开(公告)号：US5354501A
公开(公告)日：1994-10-11
申请号：US15826
申请日：1993-02-10
申请人： Shinichi Nakamura , Takao Takiguchi , Kenji Shinjo , Takashi Iwaki , Takeshi Togano , Yoko Yamada
发明人： Shinichi Nakamura , Takao Takiguchi , Kenji Shinjo , Takashi Iwaki , Takeshi Togano , Yoko Yamada
IPC分类号： C07C49/443 , C07C49/67 , C07C49/697 , C07C49/755 , C07C69/63 , C07C69/75 , C07C69/753 , C07C69/757 , C07C69/76 , C07C69/773 , C07C69/86 , C07C69/90 , C07C69/92 , C07C69/94 , C07C255/47 , C07C255/50 , C07C323/20 , C07C327/28 , C07D213/30 , C07D213/50 , C07D213/55 , C07D213/65 , C07D213/79 , C07D213/80 , C07D239/26 , C07D239/28 , C07D239/34 , C07D263/56 , C07D263/57 , C07D277/22 , C07D277/24 , C07D277/30 , C07D277/56 , C07D277/64 , C07D277/66 , C07D285/12 , C07D307/24 , C07D333/16 , C07D333/22 , C07D333/24 , C07D333/32 , C07D333/38 , C07D401/04 , C07D401/12 , C07D409/04 , C07D409/12 , C07D413/04 , C07D417/04 , C07D417/12 , C09K19/32 , C09K19/34 , G02F1/13 , C07C13/45 , C09K19/52
CPC分类号： C07D213/30 , C07C323/20 , C07C49/67 , C07C49/697 , C07C49/755 , C07C69/63 , C07C69/75 , C07C69/757 , C07C69/76 , C07C69/90 , C07C69/92 , C07C69/94 , C07D213/50 , C07D213/55 , C07D213/65 , C07D213/79 , C07D213/80 , C07D239/26 , C07D239/28 , C07D239/34 , C07D263/57 , C07D277/24 , C07D277/30 , C07D277/56 , C07D277/64 , C07D277/66 , C07D285/12 , C07D307/24 , C07D333/16 , C07D333/22 , C07D333/24 , C07D333/32 , C07D333/38 , C07D401/04 , C07D401/12 , C07D409/04 , C07D409/12 , C07D413/04 , C07D417/04 , C07D417/12 , C09K19/32 , C09K19/322 , C09K19/3441 , C09K19/3491 , C09K19/3497 , C07C2101/14 , C07C2102/08
摘要： A mesomorphic compound of the formula (I) according to Claim 1 and an optically active compound of the formula (II) according to Claim 2 are suitable as a component for a liquid crystal composition providing improved response characteristics and having an improved helical pitch at a cholesteric phase or a chiral smectic C phase. The above liquid crystal composition is useful as an element of a liquid crystal device providing a good display characteristics including a gradation display.
摘要翻译：根据权利要求1的式（I）的介晶化合物和根据权利要求2的式（II）的光学活性化合物适合作为液晶组合物的组分，其提供改善的响应特性并且在胆甾醇相或手性近晶C相。上述液晶组合物可用作提供包括灰度显示的良好显示特性的液晶装置的元件。

8. 发明授权

US5119219A Liquid crystal apparatus and chiral smectic liquid crystal composition for use therein 失效
标题翻译：液晶装置及其使用的CHIRAL SMECTIC LIQUID STYSTAL COMPOSITION
公开(公告)号：US5119219A
公开(公告)日：1992-06-02
申请号：US543415
申请日：1990-06-26
申请人： Masahiro Terada , Masataka Yamashita , Shosei Mori , Shinichi Nakamura , Kenji Shinjo , Kazuharu Katagiri
发明人： Masahiro Terada , Masataka Yamashita , Shosei Mori , Shinichi Nakamura , Kenji Shinjo , Kazuharu Katagiri
IPC分类号： G02F1/13 , C09K19/02 , G02F1/133 , G09G3/18 , G09G3/36
CPC分类号： C09K19/02 , G09G3/3629 , G09G2310/06 , G09G2320/041
摘要： A liquid crystal apparatus includes a chiral smectic liquid crystal showing a first and a second orientation state disposed between first and second electrodes of a liquid cell. A drive circuit applies voltages between the first and second electrodes including voltages .vertline.V.sub.S .vertline. and .vertline.V.sub.I .vertline. which provide voltages V.sub.A and V.sub.B (V.sub.B V.sub.A) satisfying the relationship of: .vertline.(V.sub.A -V.sub.B)/(V.sub.A +V.sub.B).vertline.>0.1 at 40.degree. C. V.sub.A is a minimum peak value of a voltage .vertline.V.sub.S .vertline.+.vertline.V.sub.I .vertline. (at a constant pulse width) capable of inverting the first orientation state of the chiral smectic liquid crystal into the second orientation state when a voltage pulse is applied between the first and second electrodes to cause the first orientation state of the chiral smectic liquid crystal and then the voltage .vertline.V.sub.S .vertline.+.vertline.V.sub.I .vertline. is applied between the first and second electrodes as a combination of a voltage .vertline.V.sub.S .vertline. applied to the first electrode and a voltage - V.sub.I .vertline. applied to the second electrode V.sub.B is a value of .vertline.V.sub.S .vertline.+.vertline.V.sub.I .vertline. calculated based on a maximum peak value of a voltage .vertline.V.sub.S .vertline.-.vertline.V.sub.I .vertline. capable of maintaining the first orientation state of the chiral smectic liquid crystal when a voltage pulse is applied between the first and second electrodes to cause the first orientation state and then the voltage .vertline.V.sub.S .vertline.-.vertline.V.sub.I .vertline. is applied between the first and second electrodes as a combination of a voltage .vertline.V.sub.S .vertline. applied to the first electrode and a voltage .vertline.V.sub.I .vertline. applied to the second electrode.

9. 发明授权

US5328639A Fluoroalkane derivative, its composition and liquid crystal device using the same 失效
标题翻译：氟烷烃衍生物，其组成和使用其的液晶装置
公开(公告)号：US5328639A
公开(公告)日：1994-07-12
申请号：US999556
申请日：1992-12-31
申请人： Hiroyuki Nohira , Masanao Kamei , Shinichi Nakamura , Kazuharu Katagiri , Masahiro Terada , Masataka Yamashita , Yoko Yamada , Kenji Shinjo , Takashi Iwaki , Chieko Hioki , Akio Yoshida , Toshiharu Uchimi
发明人： Hiroyuki Nohira , Masanao Kamei , Shinichi Nakamura , Kazuharu Katagiri , Masahiro Terada , Masataka Yamashita , Yoko Yamada , Kenji Shinjo , Takashi Iwaki , Chieko Hioki , Akio Yoshida , Toshiharu Uchimi
IPC分类号： C07C69/773 , C09K19/20 , C09K19/28 , C09K19/34 , C09K19/42 , C09K19/46 , C07C69/76 , C07D239/02
CPC分类号： C09K19/46 , C07C327/00 , C09K19/2021 , C09K19/2028 , C09K19/28 , C09K19/42
摘要： A liquid crystal composition, comprising: at least one optically active mesomorphic compound having an asymmetric carbon atom to which a fluorine atom is directly bonded.
摘要翻译：一种液晶组合物，其包含：至少一种具有氟原子直接键合的不对称碳原子的光学活性介晶化合物。

10. 发明授权

US06128064A Liquid crystal device and liquid crystal display apparatus 失效
标题翻译：液晶显示装置及液晶显示装置
公开(公告)号：US06128064A
公开(公告)日：2000-10-03
申请号：US353154
申请日：1999-07-14
申请人： Takashi Moriyama , Takao Takiguchi , Yukio Hanyu , Koichi Sato , Masahiro Terada , Shinichi Nakamura , Yasufumi Asao , Koji Noguchi , Yasushi Shimizu
发明人： Takashi Moriyama , Takao Takiguchi , Yukio Hanyu , Koichi Sato , Masahiro Terada , Shinichi Nakamura , Yasufumi Asao , Koji Noguchi , Yasushi Shimizu
IPC分类号： C09K19/34 , G02F1/1337 , G02F1/141 , C09K19/02 , G02F1/1333
CPC分类号： G02F1/141 , C09K19/3463 , G02F1/133723 , Y10T428/1023
摘要： A liquid crystal device is constituted by a chiral smectic liquid crystal and a pair of substrates sandwiching the chiral smectic liquid crystal therebetween and each having thereon an electrode for applying a voltage to the liquid crystal. At least one of the substrates being provided with an alignment control film comprising a specific aromatic polyimide which has been subjected to a uniaxial aligning treatment. The chiral smectic liquid crystal assumes bistability in a chiral smectic temperature range when incorporated in a test cell which is not provided with an alignment control film and has been subjected to shearing treatment. In the liquid crystal device including the polyimide alignment control film, the chiral smectic liquid crystal at least has a voltage-transmittance characteristic such that an effective tilt angle and a transmittance continuously change depending on an electric field applied thereto.
摘要翻译：液晶装置由手性近晶液晶和夹在其间的手性近晶液晶的一对基板构成，并具有用于向液晶施加电压的电极。至少一个基板设置有包含已经进行单轴对准处理的特定芳族聚酰亚胺的取向控制膜。手性近晶液晶在手性近晶温度范围内呈现双重稳定性，当并入未设置取向控制膜并进行剪切处理的测试电池中时。在包括聚酰亚胺取向控制膜的液晶装置中，手性近晶液晶至少具有电压 - 透射特性，使得有效倾斜角和透射率根据施加到其上的电场而不断变化。

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