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    • 1. 发明授权
    • Differential refractometer
    • 差分压力计
    • US5157454A
    • 1992-10-20
    • US618430
    • 1990-11-27
    • Koichi OkaAkira KawaguchiKunio KumagaiYasuhiro Kubo
    • Koichi OkaAkira KawaguchiKunio KumagaiYasuhiro Kubo
    • G01N21/41
    • G01N21/4133
    • A differential refractometer in which: light from a light source is condensed on a lens; the light thus condensed is guided to a cell which houses a sample of which refractive index is to be measured and a reference of which refractive index is used as a reference value, the sample and the reference being housed as separated from each other in the cell; the light having passed through the cell is guided to an image sensor; and the amount of light deflection due to the difference in refractive index between the sample and the reference is measured, thereby to obtain the refractive index of the sample. The differential refractometer comprises: a light permeable member disposed at such a position that the light permeable member and the image sensor are optically conjugate with respect to the lens, the light permeable member carrying an image having at least two identification portions; and a spatial filter disposed between the light permeable member and the image sensor and adapted to spatially filter light portions which have passed through the two identification portions, the spatial filter causing at least one of the light portions thus spatially filtered to pass through the cell. The refractive index of the sample may be obtained based on the distance between the positions of images, on the detecting surface of the image sensor, of the two identification portions of the light permeable member. Such an arrangement may improve the measuring precision and reduce the number of component elements.
    • 一种差示折射计,其中来自光源的光在透镜上会聚; 将如此冷凝的光引导到容纳需要测量折射率的样品的单元和使用折射率的基准作为参考值,将样品和参考物在细胞中彼此分离地容纳 ; 已经通过电池的光被引导到图像传感器; 并且测量由于样品和参考物之间的折射率差引起的光偏转量,从而获得样品的折射率。 所述差示折光计包括:透光部件,其设置在所述透光部件和所述图像传感器相对于所述透镜光学共轭的位置处,所述透光部件承载具有至少两个识别部分的图像; 以及空间滤光器,其布置在所述透光构件和所述图像传感器之间,并且适于空间地过滤已经穿过所述两个识别部分的光部分,所述空间滤光器使得所述空间滤光器中的至少一个光部分经过所述单元。 可以基于图像传感器的检测表面上的可透光构件的两个识别部分之间的图像的位置之间的距离来获得样本的折射率。 这样的结构可以提高测量精度并减少元件数量。
    • 5. 发明授权
    • Difluorovinyl compound, liquid crystal composition and liquid crystal display
    • 二氟乙烯基化合物,液晶组合物和液晶显示
    • US06649227B2
    • 2003-11-18
    • US09899169
    • 2001-07-06
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • C09K1934
    • C07C49/753C07C49/687C07C49/693C07C49/697C07D319/06C09K19/04C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10
    • Provided are liquid crystalline compounds having a wide liquid crystal phase temperature range, low viscosity, a large elastic constant ratio K33/K11 and excellent solubility at low temperature, a liquid crystal composition using the same and a liquid crystal display. Preferred compounds are difluorovinyl compounds represented by Formula (1): wherein Y1, represents H or a straight chain or branched alkyl group having 1 to 10 carbon atoms, and optional —CH2— in the above alkyl group may be replaced by —O— or —CH═CH—, but —O— is not adjacent to each other, and at least one H in Y1 may be substituted with halogen or a cyano group: A1, A2, A3 and A4 each independently represent 1,4-cyclohexylene in which optional —CH2— which is not adjacent to each other may be replaced by —O—, 1,4-phenylene in which optional H may be substituted with halogen, and a single bond, in which at least two of A1, A2, A3 and A4 have the ring structure described above, and at least one of them is 1,4-cyclohexylene in which —CH2— is replaced by —O—; Z1, Z2 and Z3 each independently represent a single bond, —(CH2)2—, —CH═CH—, —(CH2)4—, —O(CH2)3— or —(CH2)3O—; n represents 0 or an integer of 1 to 10, provided that when any of A1, A2, A3 and A4 is 1,4-phenylene, Z1, Z2 and Z3 are single bonds, and among them, when A1 is 1,3-dioxane-2,5-diyl and A2 is 1,4-phenylene and when A3 is 1,4-cyclohexylene and A4 is a single bond, Y1 is H, and n is not 0.
    • 本发明提供具有宽液晶相温度范围,低粘度,大弹性常数比K33 / K11和低温溶解度优异的液晶化合物,使用该液晶组合物的液晶组合物和液晶显示器。 优选的化合物是由式(1)表示的二氟乙烯基化合物:其中Y 1表示H或具有1至10个碳原子的直链或支链烷基,并且上述烷基中任选的-CH 2 - 可以被 - O-或-CH = CH-,但-O-不彼此相邻,并且Y 1中的至少一个H可以被卤素或氰基取代:A 1,A 2, A 3和A 4各自独立地表示1,4-亚环己基,其中不相邻的任选的-CH 2可以被-O-,1,4-亚苯基代替,其中任选的H可以被取代 具有卤素和单键,其中A 1,A 2,A 3和A 4中的至少两个具有上述环结构,并且它们中的至少一个为1,4 - 环己烯,其中-CH 2 - 被-O-取代; Z 1,Z 2和Z 3各自独立地表示单键, - (CH 2)2 - , - CH = CH - , - (CH 2)4 - , - O(CH 2)3 - (CH2)3O-; n表示0或1〜10的整数,条件是当A 1,A 2,A 3和A 4中的任何一个为1,4-亚苯基时,Z 1,Z 2 且Z 3为单键,其中A 1为1,3-二恶烷-2,5-二基,A 2为1,4-亚苯基,当A 3为1时, ,4-环亚己基和A 4为单键,Y 1为H,n为0。
    • 6. 发明授权
    • Cyclohexane derivatives, liquid crystal compositions comprising the same and liquid crystal display devices
    • 环己烷衍生物,含有它们的液晶组合物和液晶显示装置
    • US06500503B2
    • 2002-12-31
    • US09842254
    • 2001-04-26
    • Koichi ShibataShuichi MatsuiHiroyuki TekeuchiKatsuyuki KawanoYasuhiro KuboEtsuo Nakagawa
    • Koichi ShibataShuichi MatsuiHiroyuki TekeuchiKatsuyuki KawanoYasuhiro KuboEtsuo Nakagawa
    • C09K1930
    • C07D239/26C07C17/16C07C17/18C07C17/2635C07C25/18C07C25/24C07C45/29C07C45/513C07C255/50C07C255/54C07C2601/14C07D319/06C07D339/08C09K19/3001C09K19/3028C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10C07C22/08C07C49/813C07C47/24
    • Liquid crystalline compounds are disclosed which have large dielectric anisotropy and relatively low viscosity, and which are represented by formula (1) wherein R1 represents hydrogen or C1-C15 alkyl in which one or more non-adjacent methylene may be replaced by oxygen, sulfur or —CH═CH— and one or more hydrogen may be replaced by halogen; R2 represents hydrogen, cyano, halogen or C1-C15 alkyl in which one or more non-adjacent methylene may be replaced by oxygen, sulfur or —CH═CH— and one or more hydrogen may be replaced by halogen; L represents halogen or hydrogen; A1, A2, A4 and A5 each independently represent trans-1,4-cyclohexylene or 1,4-phenylene, one or more —CH2— in the trans-1,4-cyclohexylene may be replaced by oxygen or sulfur, one or more ═CH— in the 1,4-phenylene may be replaced by nitrogen, and one or more hydrogen in the 1,4-phenylene ring may be replaced by halogen; A3represents trans-1,4-cyclohexylene in which one or more —CH2— may be replaced by oxygen or sulfur; Z1,Z2,Z3 and Z4 each independently represent —COO—, —OCO—, —CH2CH2—, —(CH2)4—, —CH2O —, —OCH2—, —CF2O—, —OCF2— or a single bond; Q represents —CF2CH2— or —CH2CF2—; and k, l, m and n each independently represent 0 or 1 with the condition of k+l+m+n≦2. Further, liquid crystal compositions comprising at least one liquid crystalline compound of formula (1) and liquid crystal display devices composed of the compositions are disclosed.
    • 公开了具有大介电各向异性和相对低粘度的液晶化合物,其由式(1)表示,其中R 1表示氢或C 1 -C 15烷基,其中一个或多个不相邻的亚甲基可被氧,硫或 -CH = CH-,一个或多个氢可被卤素取代; R 2表示氢,氰基,卤素或C 1 -C 15烷基,其中一个或多个不相邻的亚甲基可被氧,硫或-CH = CH-代替,并且一个或多个氢可被卤素取代; L表示卤素或氢; A1,A2,A4和A5各自独立地表示反式-1,4-亚环己基或1,4-亚苯基,反式-1,4-亚环己基中的一个或多个-CH 2 - 可被氧或硫代替,一个或多个 = 1,4-亚苯基中的CH-可以被氮代替,1,4-亚苯基环中的一个或多个氢可被卤素取代; A3表示反式-1,4-亚环己基,其中一个或多个-CH 2 - 可被氧或硫取代; Z 1,Z 2,Z 3和Z 4各自独立地表示-COO - , - OCO - , - CH 2 CH 2 - , - (CH 2)4 - , - CH 2 O - , - OCH 2 - , - CF 2 O-,-OCF 2-或单键; Q表示-CF 2 CH 2 - 或-CH 2 CF 2 - ; 并且k,l,m和n各自独立地表示0或1,条件为k + 1 + m + n <= 2。 此外,公开了包含至少一种式(1)的液晶化合物和由该组合物组成的液晶显示装置的液晶组合物。
    • 10. 发明授权
    • Gas injection amount determining method in isotope gas analysis, and isotope gas analyzing and measuring method and apparatus
    • 同位素气体分析中的气体注入量确定方法和同位素气体分析及测量方法及装置
    • US07749436B2
    • 2010-07-06
    • US10577451
    • 2004-10-29
    • Masaaki MoriYasuhiro KuboYasushi ZasuMasayuki TaniTamotsu Hamao
    • Masaaki MoriYasuhiro KuboYasushi ZasuMasayuki TaniTamotsu Hamao
    • G01N33/00
    • G01N21/3504A61B5/0836
    • As previous processing of measurement in which gas to be measured containing, as gas components, carbon dioxide 13CO2 and carbon dioxide 12CO2, is introduced into a cell, and in which the intensities of transmitted lights having wavelengths suitable for measurement of the respective gas components, are measured and then data-processed to measure the concentrations of the gas components, the air having a predetermined volume Va is sucked by a gas injection device 21, a gas exhaust valve V6 of a cell 11 is closed and the air stored in the gas injection device 21 is transferred to the cell 11 filled with the air at an atmospheric pressure, thereby to pressurize the cell inside. The pressure thus pressurized is measured as P. The cell volume Vc is subtracted from the product obtained by multiplying the sum. V0 of the volume Va and Vc the cell volume Vc, by the ratio P0/P in which P0 is the target pressure of the gas to be measured at which a calibration curve has been prepared for an isotope gas analysis and measurement, thus determining the one-time gas injection amount of the gas injection device 21. Thus, measured concentration variations based on changes in atmospheric pressure can be corrected.
    • 作为先前的测量处理,其中将待测量的气体作为气体组分含有二氧化碳13CO 2和二氧化碳12CO 2,并将其中的辐射强度引入到电池中,并且其中具有适于测量各个气体组分的波长的透射光的强度, 被测量,然后进行数据处理以测量气体组分的浓度,具有预定体积Va的空气由气体注入装置21吸入,单元11的排气阀V6关闭,并且存储在气体中的空气 注入装置21在大气压下转移到填充有空气的电池单元11,从而对电池内部进行加压。 将如此加压的压力测量为P.从通过乘以和获得的乘积中减去单元容积Vc。 V0为体积Va,Vc为电池体积Vc,P0 / P为P0为待测气体的目标压力,其中准备了用于同位素气体分析和测量的校准曲线,从而确定 气体注入装置21的一次气体注入量。因此,可以校正基于大气压变化的测量浓度变化。