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    • 1. 发明授权
    • Difluorovinyl compound, liquid crystal composition and liquid crystal display
    • 二氟乙烯基化合物,液晶组合物和液晶显示
    • US06649227B2
    • 2003-11-18
    • US09899169
    • 2001-07-06
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • C09K1934
    • C07C49/753C07C49/687C07C49/693C07C49/697C07D319/06C09K19/04C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10
    • Provided are liquid crystalline compounds having a wide liquid crystal phase temperature range, low viscosity, a large elastic constant ratio K33/K11 and excellent solubility at low temperature, a liquid crystal composition using the same and a liquid crystal display. Preferred compounds are difluorovinyl compounds represented by Formula (1): wherein Y1, represents H or a straight chain or branched alkyl group having 1 to 10 carbon atoms, and optional —CH2— in the above alkyl group may be replaced by —O— or —CH═CH—, but —O— is not adjacent to each other, and at least one H in Y1 may be substituted with halogen or a cyano group: A1, A2, A3 and A4 each independently represent 1,4-cyclohexylene in which optional —CH2— which is not adjacent to each other may be replaced by —O—, 1,4-phenylene in which optional H may be substituted with halogen, and a single bond, in which at least two of A1, A2, A3 and A4 have the ring structure described above, and at least one of them is 1,4-cyclohexylene in which —CH2— is replaced by —O—; Z1, Z2 and Z3 each independently represent a single bond, —(CH2)2—, —CH═CH—, —(CH2)4—, —O(CH2)3— or —(CH2)3O—; n represents 0 or an integer of 1 to 10, provided that when any of A1, A2, A3 and A4 is 1,4-phenylene, Z1, Z2 and Z3 are single bonds, and among them, when A1 is 1,3-dioxane-2,5-diyl and A2 is 1,4-phenylene and when A3 is 1,4-cyclohexylene and A4 is a single bond, Y1 is H, and n is not 0.
    • 本发明提供具有宽液晶相温度范围,低粘度,大弹性常数比K33 / K11和低温溶解度优异的液晶化合物,使用该液晶组合物的液晶组合物和液晶显示器。 优选的化合物是由式(1)表示的二氟乙烯基化合物:其中Y 1表示H或具有1至10个碳原子的直链或支链烷基,并且上述烷基中任选的-CH 2 - 可以被 - O-或-CH = CH-,但-O-不彼此相邻,并且Y 1中的至少一个H可以被卤素或氰基取代:A 1,A 2, A 3和A 4各自独立地表示1,4-亚环己基,其中不相邻的任选的-CH 2可以被-O-,1,4-亚苯基代替,其中任选的H可以被取代 具有卤素和单键,其中A 1,A 2,A 3和A 4中的至少两个具有上述环结构,并且它们中的至少一个为1,4 - 环己烯,其中-CH 2 - 被-O-取代; Z 1,Z 2和Z 3各自独立地表示单键, - (CH 2)2 - , - CH = CH - , - (CH 2)4 - , - O(CH 2)3 - (CH2)3O-; n表示0或1〜10的整数,条件是当A 1,A 2,A 3和A 4中的任何一个为1,4-亚苯基时,Z 1,Z 2 且Z 3为单键,其中A 1为1,3-二恶烷-2,5-二基,A 2为1,4-亚苯基,当A 3为1时, ,4-环亚己基和A 4为单键,Y 1为H,n为0。
    • 7. 发明授权
    • Fluoroalkylated liquid-crystal compounds, liquid-crystal compositions, and liquid-crystal display elements
    • 氟烷基化液晶化合物,液晶组合物和液晶显示元件
    • US06254941B1
    • 2001-07-03
    • US09269286
    • 1999-03-25
    • Tomoyuki KondouShuichi MatsuiKazutoshi MiyazawaHiroyuki TakeuchiYasuhiro KuboFusayuki TakeshitaEtsuo Nakagawa
    • Tomoyuki KondouShuichi MatsuiKazutoshi MiyazawaHiroyuki TakeuchiYasuhiro KuboFusayuki TakeshitaEtsuo Nakagawa
    • C09K1912
    • C07C17/12C07C17/263C07C17/2635C07C17/361C07C25/18C07C43/174C07C43/225C09K19/12C09K19/14C09K19/20C09K2019/124Y10T428/10C07C25/13
    • The present invention provides liquid crystalline compounds having a very high voltage holding ratio, very little variation of these properties depending on temperature, high &Dgr;n, and good compatibility in the other liquid crystal materials particularly under a low temperature, liquid crystal compositions containing these crystalline compounds, and liquid crystal display devices constituted by using the liquid crystal compositions. The liquid crystalline compounds are represented by general formula (1): wherein R represents an alkyl, alkoxy or alkoxyalkyl group of 2-20 carbon atoms, and in each group, any 1-3 hydrogen atoms may be replaced by fluorine atoms; X shows an halogen atom or an alkyl group of 1-20 carbon atoms, any methylene groups (—CH2—) not adjacent each other in the alkyl group may be replaced by oxygen atoms, and any one or more hydrogen atoms in the alkyl group may be replaced by fluorine atoms; Z1, Z2 and Z3, each independently, represents —(CH2)2—, —(CH2)4—, —CH2O—, —OCH2—, —(CH2)3O—, —O(CH2)3— or a covalent bond; Y1-Y16 each independently represent hydrogen atoms or fluorine atoms, but at least two represent fluorine atoms; m represents 0 or 1, and any atom constituting the compound may be replaced by an isotope thereof.
    • 本发明提供了具有非常高的电压保持率的液晶化合物,这些性质随温度变化很小,DELTAn高,在其它液晶材料中特别是在低温下具有良好的相容性,含有这些结晶化合物的液晶组合物 ,以及使用液晶组合物构成的液晶显示装置。 液晶化合物由通式(1)表示:其中R表示2-20个碳原子的烷基,烷氧基或烷氧基烷基,并且在每一组中,任何1-3个氢原子可被氟原子取代; X表示卤素原子或1-20个碳原子的烷基,烷基中不相邻的任何亚甲基(-CH 2 - )可以被氧原子取代,并且烷基中的任何一个或多个氢原子 可以被氟原子取代; Z 2,Z 2和Z 3各自独立地表示 - (CH 2)2 - , - (CH 2)4 - , - CH 2 O - , - OCH 2 - , - (CH 2)3 O-,-O ; Y1-Y16各自独立地表示氢原子或氟原子,但至少两个表示氟原子; m表示0或1,构成化合物的任何原子可以被其同位素代替。