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1. 发明授权

US4320232A Process for conjointly preparing methyl tert.-butyl ether and obtaining isobutene 失效
标题翻译：共同制备甲基叔丁基醚并获得异丁烯的方法
公开(公告)号：US4320232A
公开(公告)日：1982-03-16
申请号：US161041
申请日：1980-06-19
申请人： Klaus Volkamer , Alfred Lindner , Franz Merger , Ulrich Wagner , Erwin Brunner , Gerhard Sandrock , Max Strohmeyer
发明人： Klaus Volkamer , Alfred Lindner , Franz Merger , Ulrich Wagner , Erwin Brunner , Gerhard Sandrock , Max Strohmeyer
IPC分类号： C07C41/05 , C07C1/00 , C07C7/148 , C07C11/09 , C07C41/00 , C07C41/06 , C07C43/04 , C07C67/00
CPC分类号： C07C41/06 , C07C7/14891
摘要： A process for conjointly preparing methyl tert.-butyl ether and obtaining isobutene from an isobutene-containing C.sub.4 -hydrocarbon mixture. In the process the C.sub.4 -hydrocarbon mixture is reacted, in one or more etherification stages, with methanol and a primary C.sub.3 - or C.sub.4 -alcohol in the presence of an acid condensing agent, the resulting reaction mixture or mixtures are then separated into a fraction containing the unconverted hydrocarbons, the methyl tert.-butyl ether and a fraction containing the C.sub.3 - or C.sub.4 -alkyl tert.-butyl ether. Thereafter, the C.sub.3 - or C.sub.4 -alkyl tert.-butyl ether is decomposed at an elevated temperature, in the presence of an acid catalyst, into isobutene and primary C.sub.3 - or C.sub.4 -alcohol.
摘要翻译：一种联合制备甲基叔丁基醚并从含异丁烯的C4-烃混合物中获得异丁烯的方法。在该过程中，C4-烃混合物在一个或多个醚化阶段中，在酸缩合剂存在下与甲醇和伯C3或C4-醇反应，然后将所得反应混合物或混合物分离成馏分含有未转化的烃，甲基叔丁基醚和含有C3-或C4-烷基叔丁基醚的级分。此后，C3-或C4-烷基叔丁基醚在酸催化剂存在下在升高的温度下分解成异丁烯和伯C 3 - 或C 4 - 醇。

2. 发明授权

US4287379A Process for obtaining isobutene from C.sub.4 -hydrocarbon mixtures containing isobutene 失效
标题翻译：从含有异丁烯的C 4烃混合物中获得异丁烯的方法
公开(公告)号：US4287379A
公开(公告)日：1981-09-01
申请号：US137750
申请日：1980-04-07
申请人： Erwin Brunner , Eckart Schubert , Alfred Lindner , Franz Merger , Klaus Volkamer , Max Strohmeyer , Gerhard Sandrock
发明人： Erwin Brunner , Eckart Schubert , Alfred Lindner , Franz Merger , Klaus Volkamer , Max Strohmeyer , Gerhard Sandrock
IPC分类号： B01J31/00 , C07B61/00 , C07C1/00 , C07C7/148 , C07C11/09 , C07C41/42 , C07C67/00 , C07C7/00
CPC分类号： C07C41/42 , C07C11/09 , C07C41/06 , C07C7/14891
摘要： A process for obtaining isobutene from a C.sub.4 -hydrocarbon mixture containing isobutene, by reacting the mixture with a primary alcohol in the presence of an acid condensing agent and decomposing the resulting tertiary ether in the presence of an acid catalyst at an elevated temperature, wherein a primary C.sub.3 - or C.sub.4 -alcohol is used.
摘要翻译：通过在酸缩合剂存在下使该混合物与伯醇反应并在酸催化剂存在下在升高的温度下分解得到的叔乙醚，从含有异丁烯的C 4烃混合物中获得异丁烯的方法，其中a 使用初级C3-或C4-醇。

3. 发明授权

US4198531A Manufacture of p-alkylphenols 失效
标题翻译：对烷基苯酚的制造
公开(公告)号：US4198531A
公开(公告)日：1980-04-15
申请号：US842304
申请日：1977-10-14
申请人： Franz Merger , Max Strohmeyer , Gerhard Sandrock , Heinz Hohenschutz , Ludwig Schroff , Gerhard Nestler
发明人： Franz Merger , Max Strohmeyer , Gerhard Sandrock , Heinz Hohenschutz , Ludwig Schroff , Gerhard Nestler
IPC分类号： C07C37/14 , C07C39/06
CPC分类号： C07C37/14
摘要： p-alkylphenols are manufactured by continuous reaction of phenol with olefins in the presence of a pulverulent polystyrenesulfonic acid ion exchanger which is suspended in the reaction mixture.
摘要翻译：在烷基苯酚是通过苯酚与烯烃在悬浮在反应混合物中的粉状聚苯乙烯磺酸离子交换剂存在下的连续反应来制备的。

4. 发明授权

US5149861A Recovery of trialkylamines and methyl formate from mixtures obtained in the preparation of trimethylolalkanes 失效
标题翻译：三氯甲烷制备中获得的混合物中的丙烯酰胺和甲基丙烯酸的回收
公开(公告)号：US5149861A
公开(公告)日：1992-09-22
申请号：US664463
申请日：1991-03-01
申请人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch , Heribert Deck , Heinz Auer , Erwin Brunner
发明人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch , Heribert Deck , Heinz Auer , Erwin Brunner
IPC分类号： C07C69/06 , C07C27/00 , C07C27/02 , C07C29/38 , C07C29/74 , C07C29/88 , C07C31/22 , C07C67/00 , C07C67/03 , C07C67/08 , C07C209/00 , C07C209/86 , C07C211/03 , C07C211/05
CPC分类号： C07C29/88 , C07C67/03
摘要： Trialkylamines and methyl formate are recovered from reaction mixtures obtained in the preparation of trimethylolalkanes by reaction of n-alkanals with from 2.2 to 4.5 moles of formaldehyde in aqueous solution in the presence of from 0.6 to 3 mole of trialkylamine, each quantity based on 1 mole of alkanal, and subsequent hydrogenation in a process wherein the crude reaction mixturea) is heated to from 100.degree. to 200.degree. C., the water present in the reaction mixture is substantially separated off by distillation, together with any excess free trialkylamine, the trialkylamine present in the form of a trialkylammonium formate is freed to form a trimethylolalkane formate, the trialkylamine is distilled off and the trimethylolalkane formate is transesterified with methanol to trimethylolalkane and methyl formate in the presence or absence of a catalytic amount of an alkali metal alkoxide or alkaline earth metal alkoxide, orb) is substantially dewatered, any excess free trialkylamine being removed at the same time, the trialkylamine present in the form of a trialkylammonium formate is separated off by admixing the remaining mixture with methanol and heating the admixture to from 100.degree. to 200.degree. C. to form methyl formate and trialkylamine.
摘要翻译：三烷基胺和甲酸甲酯从制备三羟甲基烷烃得到的反应混合物中回收，通过在0.6至3摩尔三烷基胺存在的情况下，正链烷与2.2至4.5摩尔甲醛在水溶液中的反应，每个量基于1摩尔然后在将粗反应混合物a）加热至100至200℃的过程中随后进行氢化，反应混合物中存在的水通过蒸馏与任何过量的游离三烷基胺基本上分离出来，以三烷基铵甲酸盐形式存在的三烷基胺可以形成甲酸三羟甲基烷烃，在存在或不存在催化量的碱金属醇盐的条件下，将三烷基胺蒸馏除去，甲醇三甲氧基链烷烃甲酯与甲醇酯交换为三羟甲基烷烃和甲酸甲酯，或碱土金属醇盐或b）基本脱水，任何过量游离的三烷基胺为同时除去以三烷基甲酸铵形式存在的三烷基胺，通过将剩余的混合物与甲醇混合并将混合物加热至100至200℃以分离，形成甲酸甲酯和三烷基胺。

5. 发明授权

US5689010A Preparation of higher aldehydes 失效
标题翻译：制备较高级的醛
公开(公告)号：US5689010A
公开(公告)日：1997-11-18
申请号：US638592
申请日：1996-04-29
申请人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
发明人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C45/49
CPC分类号： C07C45/50 , C07C45/62 , C07C45/74
摘要： Aldehydes with a higher number of carbon atoms and high selection are prepared by reacting olefins, in particular from petrochemical refinery products, by a hydroformylation with aldol condensation using a mixed catalyst of rhodium-carbonyl-phosphines and Mannich catalyst.
摘要翻译：通过使用铑 - 羰基膦和Mannich催化剂的混合催化剂通过使醛醇缩合的加氢甲酰化反应，使烯烃，特别是石油化学品炼油产物反应，制备具有较高碳原子数和高选择性的醛。

6. 发明授权

US5416240A Preparation of poloxy-alkylene glycols 失效
标题翻译：烷氧基 - 亚烷基二醇的制备
公开(公告)号：US5416240A
公开(公告)日：1995-05-16
申请号：US24903
申请日：1993-03-02
申请人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
发明人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
IPC分类号： C08G65/02 , C08G65/08 , C08G65/16 , C08G65/20 , C07C41/01 , C07C41/02
CPC分类号： C08G65/20
摘要： Polyoxyalkylene glycols are prepared by a process in which tetrahydrofuran is polymerized with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals in the absence of water and in the presence of a monohydric alcohol or of a monocarboxylic acid with the aid of an anhydrous heteropoly acid catalyst, and the polyoxyalkylene glycol is liberated from the resulting polyoxyalkylene glycol monoethers or polyoxyalkylene glycol monoesters by cleavage of the monoether or monoester bond.
摘要翻译：聚氧亚烷基二醇通过以下方法制备，其中四氢呋喃基于所用四氢呋喃的总量不超过95摩尔％，在不存在共聚单体的情况下聚合来自由环醚和缩醛组成的组中的一种或多种共聚单体水和一元醇或单羧酸存在下，借助于无水杂多酸催化剂，通过裂解单醚或单酯键，从所得聚氧亚烷基二醇单醚或聚氧亚烷基二醇单酯中释放出聚氧亚烷基二醇。

7. 发明授权

US5268499A Preparation of mixtures of 3-aminopropionitrile and ethylene cyanohydrin 失效
标题翻译：制备3-氨基丙腈和乙烯氰醇的混合物
公开(公告)号：US5268499A
公开(公告)日：1993-12-07
申请号：US47303
申请日：1993-04-19
申请人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
发明人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
IPC分类号： C07C253/30
CPC分类号： C07C253/30
摘要： A process for preparing mixtures of 3-aminopropionitrile of the formula IH.sub.2 N--CH.sub.2 --CH.sub.2 --CN (I)and ethylene cyanohydrin of the formula IIHO--CH.sub.2 --CH.sub.2 --CN (II)comprises reacting bis(2-cyanoethyl) ether of the formula IIINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN (III)with ammonia at from 50 to 170.degree. C. and under from 1 to 500 bar thermally or in the presence of a heterogeneous catalyst.
摘要翻译：制备式I H 2 N-CH 2 -CH 2 -N（I）的3-氨基丙腈和式II HO-CH2-CH2-CN（Ⅱ）的乙烯氰醇的混合物的方法包括使双（2-氰乙基）醚式III NC-CH2-CH2-O-CH2-CH2-CN（III）与氨在50至170℃下和在1至500巴下加热或在多相催化剂存在下反应。

8. 发明授权

US5256813A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲酰基丙酸酯，其制备及其用于制备3-取代的3-甲酰基丙烯酸酯的用途
公开(公告)号：US5256813A
公开(公告)日：1993-10-26
申请号：US883342
申请日：1992-05-15
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： C07C69/675 , C07C69/732
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy-3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the fomrula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic eater of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：其中R1是低级烷基，R2是具有1-10个碳原子的直链或支链烷基的式Ⅰ的3-取代的2-羟基-3-甲酰基丙酸酯是通过将烷基的II型和式III（III）的烷基乙醛酸盐同时与由仲胺和羧酸的盐或混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃。式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

9. 发明授权

US5202461A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲基丙烯酸酯，其制备方法及其用于制备3-取代的3-甲基丙烯酸酯的用途
公开(公告)号：US5202461A
公开(公告)日：1993-04-13
申请号：US593891
申请日：1990-10-05
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： B01J31/02 , B01J31/04 , C07B61/00 , C07C67/343 , C07C67/44 , C07C69/67 , C07C69/675
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the formula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic ester of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：通过加入式I的3-取代的2-羟基-3-甲酰基丙酸酯，其中R 1是低级烷基，R 2是1-10个碳原子的直链或支链烷基，式II（II）和式III（III）的烷基乙醛酸盐同时加入由盐或仲胺和羧酸的混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃ 式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

10. 发明授权

US5166447A Preparation of cyclopentanones 失效
标题翻译：环戊酮的制备
公开(公告)号：US5166447A
公开(公告)日：1992-11-24
申请号：US776688
申请日：1991-10-15
申请人： Franz Merger , Tom Witzel
发明人： Franz Merger , Tom Witzel
IPC分类号： C07C45/60 , C07C49/395 , C07C49/523
CPC分类号： C07C49/395 , C07C45/60 , C07C49/523 , Y02P20/582
摘要： Cyclopentanones of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each an organic radical or R.sup.1 or R.sup.2 may be hydrogen and R.sup.3 is hydrogen or formyl, are prepared by a process in which a 2-formyl-3,4-dihydropyran of the general formula II ##STR2## where R.sup.1 and R.sup.2 have the abovementioned meanings, a) where R.sup.3 is formyl, is converted in the presence of an acidic heterogeneous catalyst at from 50.degree. to 500.degree. C., andb) where R.sup.3 is hydrogen,b.sub.1) is reacted with water or an alcohol in the presence of an acidic heterogeneous catalyst at from 100.degree. to 500.degree. C. in the gas phase orb.sub.2) a compound II or an acrolein of the general formula III ##STR3## is reacted with water or with water in the presence of an acid or with an alcohol in the presence of an acid at from 150.degree. to 400.degree. C. in the liquid phase. Novel 2-formylcyclopentanones are obtained.
摘要翻译：其中R 1和R 2各自为有机基团或R 1或R 2可以是氢并且R 3为氢或甲酰基的通式I（I）的环戊烷酮通过其中2-甲酰基-3,4 - 二氢吡喃，其中R 1和R 2具有上述含义，a）其中R 3是甲酰基，在酸性多相催化剂存在下在50-500℃下转化，和 b）其中R3是氢，b1）在酸性非均相催化剂存在下，在气相中在100-500℃下与水或醇反应，或b2）化合物II或通式为的丙烯醛在酸的存在下，在酸的存在下，在液相中，在150℃至400℃的条件下，将III（III）化合物与水或水在酸或醇的存在下反应。得到新的2-甲酰基环戊烷酮。

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