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1. 发明授权

US5136004A Binder, process for its preparation and its use in clear or pigmented coating agents 失效
标题翻译： BINDER，其制备方法及其在清除或掺杂涂料中的用途
公开(公告)号：US5136004A
公开(公告)日：1992-08-04
申请号：US391541
申请日：1990-11-13
申请人： Klaus Bederke , Hermann Kerber , Manfred Krumme , Fritz Sadowski , Werner Stephan
发明人： Klaus Bederke , Hermann Kerber , Manfred Krumme , Fritz Sadowski , Werner Stephan
IPC分类号： C08F220/06 , C08F20/32 , C08F212/00 , C08F212/08 , C08F220/04 , C08F220/10 , C08F220/18 , C08F220/26 , C08F220/28 , C08F220/32 , C08G18/62 , C09D125/00 , C09D125/04 , C09D133/04 , C09D133/06 , C09D175/04
CPC分类号： C08F220/32 , C08F212/08
摘要： The invention concerns a binder suitable for clear or pigmented coating agents. Binders based on copolymers containing hydroxyl groups have hitherto a high solvent content. The solids content of the new binders is improved without affecting the viscosity; gloss, body, flow and processing properties of coatings containing the new binders are improved. The binders consist essentially of a copolymer containing hydroxyl groups, made from specific quantities of styrol, tertbutacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxypropyl methacrylate, butanediol-1, 4-monoacrylate, acrylic acid and glycidyl esters of .alpha.-alkylalkane monocarboxylic acids and/or .alpha.,.alpha.-dialkylalkane monocarboxylic acids.
摘要翻译： PCT No.PCT / EP88 / 01097 Sec。 371日期1990年11月13日 102（e）1990年11月13日日期PCT提交1988年12月2日PCT公布。第WO89 / 05314号公报日期：1989年6月15日。本发明涉及适用于透明或着色涂层剂的粘合剂。基于含有羟基的共聚物的粘合剂迄今为止具有高溶剂含量。新粘合剂的固体含量得到改善而不影响粘度; 提高了含有新粘合剂的涂料的光泽度，体积，流动性和加工性能。粘合剂基本上由含有羟基的共聚物组成，由特定量的苯乙烯，叔丁基丙烯酸酯，甲基丙烯酸异丁酯，甲基丙烯酸2-乙基己酯，甲基丙烯酸2-羟丙酯，丁二醇-1,4-单丙烯酸酯，丙烯酸和α-烷基烷基的缩水甘油酯一元羧酸和/或α，α-二烷基烷烃一元羧酸。

2. 发明授权

US5731382A Coating agents and their use in particular in the production of transparent and pigmented top coatings 失效
标题翻译：涂层剂及其用途，特别是生产透明和着色顶层涂料
公开(公告)号：US5731382A
公开(公告)日：1998-03-24
申请号：US718729
申请日：1996-09-24
申请人： Klaus Bederke , Gerhard Bremer , Hermann Kerber , Manfred Krumme , Fritz Sadowski , Werner Stephan , Olaf Ley
发明人： Klaus Bederke , Gerhard Bremer , Hermann Kerber , Manfred Krumme , Fritz Sadowski , Werner Stephan , Olaf Ley
IPC分类号： C09D125/04 , C08G18/62 , C09D125/00 , C09D133/00 , C09D133/04 , C09D175/04 , C08F8/30
CPC分类号： C08G18/6204 , C08G18/6254 , C09D175/04 , Y10T428/31551
摘要： Coating agents are described, that are suitable for the production of pigmented or transparent top coatings, based on hydroxy-functional (meth)acrylic copolymers, aliphatic and/or cycloaliphatic polyisocyanates, solvents, and customary lacquer additives and pigments. They are free from epoxy resins and nitrocellulose and contain as binder A) one or more (meth)acrylic copolymers, containing hydroxyl groups, from a1) 47-53 wt % of one or more aromatic vinyl compounds, a2) 28-33 wt % of one or more hydroxyalkyl methacrylates, a3) 14-19 wt % of one or more alkyl (meth)acrylates, and a4) 0.5-2 wt % acrylic acid and/or methacrylic acid, with a hydroxyl number of 120-160 mg KOH/g, an acid number of 5 to 15 mg KOH/g, a weight-average molecular weight of 10,000 to 20,000 and a glass transition temperature of +40.degree. C. to +60.degree. C., and B) an aliphatic and/or cycloaliphatic polyisocyanate or a mixture of such polyisocyanates in such an amount that 0.5 to 2.0 isocyanate groups are present for one hydroxyl group of component A).
摘要翻译：描述了适用于基于羟基官能（甲基）丙烯酸共聚物，脂族和/或脂环族多异氰酸酯，溶剂和常规漆添加剂和颜料的着色或透明顶涂层的生产的涂层剂。它们不含环氧树脂和硝化纤维素并含有作为粘合剂的一种或多种含有羟基的（甲基）丙烯酸共聚物，a1）47-53重量％的一种或多种芳族乙烯基化合物，a2）28-33重量％的一种或多种甲基丙烯酸羟烷基酯，a3）14-19重量％的一种或多种（甲基）丙烯酸烷基酯和a4）0.5-2重量％的丙烯酸和/或甲基丙烯酸，羟基数为120-160毫克KOH / g，酸值为5〜15mg KOH / g，重均分子量为10,000〜20,000，玻璃化转变温度为+ 40℃〜+ 60℃，B）脂肪族和/ 或环脂族多异氰酸酯或这种多异氰酸酯的混合物，其量为组分A）的一个羟基存在0.5-2.0个异氰酸酯基团。

3. 发明授权

US6162886A Copolymers which contain hydroxyl groups and a method of producing them 失效
标题翻译：含羟基的共聚物及其制备方法
公开(公告)号：US6162886A
公开(公告)日：2000-12-19
申请号：US15852
申请日：1998-01-29
申请人： Gerhard Bremer , Hermann Kerber , Manfred Krumme , Olaf Ley , Werner Stephan , Jorg Wabbels
发明人： Gerhard Bremer , Hermann Kerber , Manfred Krumme , Olaf Ley , Werner Stephan , Jorg Wabbels
IPC分类号： C09D133/14 , C08F220/28 , C08F220/32 , C08G18/62 , C09D161/24 , C09D175/04 , C08F20/26 , C08F20/00 , C08F20/10 , C08F24/00 , C08F120/00
CPC分类号： C08F220/28 , C08F220/32 , C08G18/6258 , C09D175/04
摘要： This invention relates to copolymers which contain hydroxyl groups and which are based on vinyl esters of monocarboxylic acids, wherein the copolymers which contain hydroxyl groups have an OH number of 110-170 mg KOH/g, an acid number of 5-35 mg KOH/g and a number average molecular weight M.sub.n of 1500-8000 g/mole and are obtainable by the polymerisation of A) 5-20% by weight of one or more vinyl esters of saturated monocarboxylic acids, B) 10-30% by weight of one or more aromatic vinyl hydrocarbons, C) 41-55% by weight of hydroxy-functional, polymerisable, unsaturated monomers, and D) 0-40% by weight of further polymerisable, unsaturated monomers, wherein component C) contains C1) 40-70% by weight of one or more hydroxyalkyl esters of .alpha.,.beta.-unsaturated monocarboxylic acids, C2) 1-10% by weight of one or more lactones, and C3) 30-55% by weight of one or more reaction products of an .alpha.,.beta.-unsaturated monocarboxylic acid with a glycidyl ester of a saturated .alpha.,.alpha.-dialkylalkane-monocarboxylic acid or of a saturated .alpha.-alkylalkane-monocarboxylic acid, and the sum of components A) to D) and the sum of components C1) to C3) add up to 100% by weight in each case.
摘要翻译：本发明涉及含有羟基并基于一元羧酸的乙烯基酯的共聚物，其中含羟基的共聚物的OH值为110-170mg KOH / g，酸值为5-35mg KOH / g，数均分子量Mn为1500-8000g / mol，可通过A）5-20重量％的一种或多种饱和一元羧酸乙烯基酯的聚合获得，B）10-30重量％一种或多种芳族乙烯基烃，C）41-55％重量的羟基官能的可聚合的不饱和单体，和D）0-40％（重量）的其它可聚合的不饱和单体，其中组分C）含有C 1〜 70重量％的α，β-不饱和一元羧酸的一种或多种羟烷基酯，C2）1-10重量％的一种或多种内酯，和C3）30-55重量％的一种或多种反应产物 α，β-不饱和一元羧酸与饱和α，α-di的缩水甘油酯烷基烷烃 - 一元羧酸或饱和的α-烷基烷烃 - 一元羧酸，以及组分A）至D）和组分C1）至C3的总和）在每种情况下总计为100重量％。

4. 发明授权

US5480936A Emulsifier-free coating agent, manufacture and use thereof 失效
标题翻译：无乳化剂涂层剂，其制造和使用
公开(公告)号：US5480936A
公开(公告)日：1996-01-02
申请号：US250449
申请日：1994-05-27
申请人： Volker Duecoffre , Carmen Flosbach , Walter Schubert , Manfred Krumme , Werner Stephan , Fritz Sadowski
发明人： Volker Duecoffre , Carmen Flosbach , Walter Schubert , Manfred Krumme , Werner Stephan , Fritz Sadowski
IPC分类号： C08G18/68 , C08G18/63 , C08G18/79 , C09D5/00 , C09D133/04 , C09D133/06 , C09D151/00 , C09D151/08 , C09D175/14 , C09D175/16 , C09D181/08 , C08L75/06 , C08F3/30 , C08F282/02
CPC分类号： C08G18/631 , C08G18/792 , C09D181/08
摘要： Oligoester acrylate resins having a high content of solids and comparatively low viscosity, and aqueous coating agents with a low content of organic solvents for obtaining coatings with high resistance to chemicals, more particularly high resistance to acids and oily soot, and very low tendency to yellowing.
摘要翻译：具有高固体含量和较低粘度的低聚酯丙烯酸酯树脂以及具有低含量有机溶剂的水性涂料，用于获得对化学品具有高抗性的涂层，更特别是耐酸性和油性烟灰的耐受性以及非常低的黄变倾向。

5. 发明授权

US5691417A Coating medium, the use thereof, and a process for multilayer coating 失效
标题翻译：涂布介质，其用途以及多层涂布方法
公开(公告)号：US5691417A
公开(公告)日：1997-11-25
申请号：US672131
申请日：1996-06-27
申请人： Gerhard Bremer , Hermann Kerber , Manfred Krumme , Olaf Ley , Werner Stephan
发明人： Gerhard Bremer , Hermann Kerber , Manfred Krumme , Olaf Ley , Werner Stephan
IPC分类号： B05D1/36 , B05D7/14 , C08F220/28 , C08G18/62 , C09D175/04
CPC分类号： C08G18/6254 , C08F220/28 , Y10T428/31551 , Y10T428/31605
摘要： A coating medium suitable for multilayer coatings, containing A) copolymers containing hydroxyl groups, comprising a1) 8-12% by weight of vinyl esters of alpha, alpha,dialkyl-substituted, branched, aliphatic saturated monocarboxylic acids, a2) 32-42% by weight of hydroxyalkyl esters of (meth)acrylic acid, a2) 25-40% by weight of alkyl esters of (meth)acrylic acid, a4) 12-24% by weight of cycloalkyl esters of (meth)acrylic acid, and a5) 2-4% by weight of (meth)acrylic acid with a hydroxyl number of 100-160 mg KOH/g, an acid number of 10-50 mg KOH/g, a number average molecular weight (Mn) of 1000 to 3000 g/mole and a glass transition temperature (Tg) of 30.degree.-80.degree. C., B) polyisocyanates in a quantitative proportion such that 0.5 to 2 isocyanate groups are allotted to one hydroxyl group of component A), and C) solvents and optionally one or more pigments, extenders and/or customary lacquer additives.
摘要翻译：包含A）包含羟基的共聚物的涂层介质，其包含a1）8-12重量％的α，α，二烷基取代的，支化的脂族饱和一元羧酸的乙烯基酯，a2）32-42％（甲基）丙烯酸的羟基烷基酯，a2）（甲基）丙烯酸的烷基酯的25-40重量％，（甲基）丙烯酸的12-24重量％的环烷基酯和）2-4重量％的羟基数为100-160mg KOH / g的（甲基）丙烯酸，酸值为10-50mg KOH / g，数均分子量（Mn）为1000-3000 g / mol，玻璃化转变温度（Tg）为30〜-80℃，B）多异氰酸酯的定量比例使得0.5〜2个异氰酸酯基团分配到组分A）的一个羟基，和C）溶剂和任选地一种或多种颜料，增量剂和/或常规漆添加剂。

6. 发明授权

US4613352A Displacement pick-up arrangement for the position detection of a pressing plunger 失效
标题翻译：用于按压柱塞的位置检测的位移拾取装置
公开(公告)号：US4613352A
公开(公告)日：1986-09-23
申请号：US690972
申请日：1985-01-11
申请人： Manfred Krumme , Gerhard Geisel
发明人： Manfred Krumme , Gerhard Geisel
IPC分类号： C03B9/193 , C03B9/41 , C03B11/16
CPC分类号： C03B9/1936 , C03B9/41
摘要： A displacement pick-up arrangement for the position detection of a plunger is a component of a pressing station of a section of an I.S. glass-forming machine in which a plunger is inserted into a mold recess of a parison mold holding a glass gob at this time, and includes a ring-shaped core which is carried by a piston rod mounted to said plunger. The core forms an actuating element for changing the inductivity of a coil which is arranged in a ring-shaped frame between a cylinder and a guiding cylinder for the plunger.
摘要翻译：用于柱塞的位置检测的位移拾取装置是I.S.的一部分的按压站的部件。玻璃成形机，其中柱塞插入到此时保持玻璃料滴的型坯模具的模具凹槽中，并且包括由安装到所述柱塞的活塞杆承载的环形芯。芯形成用于改变线圈的电感的致动元件，该线圈布置在圆筒和用于柱塞的引导筒之间的环形框架中。

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