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    • 4. 发明授权
    • Organic EL element and method of producing the same
    • 有机EL元件及其制造方法
    • US06187457B1
    • 2001-02-13
    • US09117043
    • 1998-10-21
    • Michio AraiKenji NakayaOsamu OnitsukaMasami Mori
    • Michio AraiKenji NakayaOsamu OnitsukaMasami Mori
    • H05B3314
    • H05B33/26H01L51/5231
    • The invention provides an organic electroluminescent light emitting device comprising essentially comprising a substrate, a hole injecting electrode formed on at least said substrate, a light emitting layer and an electron injecting electrode containing a constituting material having a work function of up to 4 eV. The electron injecting electrode has a sealing film on a side thereof not opposite to the substrate. This sealing film contains one or two or more of an oxide, a nitride and a carbide of the constituting material for the electron injecting electrode, and so can be relatively easily formed continuously from the electron injecting electrode without any dedicated equipment for sealing films, while maintaining a high sealing effect. The invention also provides a process of producing such an organic electroluminescent light emitting device.
    • 本发明提供了一种有机电致发光发光器件,其包括基本上包括至少形成在所述衬底上的空穴注入电极,发光层和含有功函数高达4eV的构成材料的电子注入电极。 电子注入电极在其与基板不相对的一侧上具有密封膜。 该密封膜含有电子注入电极的构成材料的氧化物,氮化物和碳化物中的一种或两种以上,并且可以相对容易地从电子注入电极连续地形成,而不需要任何用于密封膜的专用设备,同时 保持高密封效果。 本发明还提供了制造这种有机电致发光发光器件的方法。
    • 8. 发明授权
    • Organic electroluminescent device
    • 有机电致发光器件
    • US06340537B1
    • 2002-01-22
    • US09239963
    • 1999-01-29
    • Michio AraiIsamu KoboriEtsuo Mitsuhashi
    • Michio AraiIsamu KoboriEtsuo Mitsuhashi
    • B62B3300
    • H01L51/5092H01L51/5088
    • The organic EL device of the present invention fulfills the object of realizing an organic EL device which exhibits an excellent hole injecting efficiency and an improved light emitting efficiency and which can be operated at a low drive voltage and manufactured at a reduced cost. In order to attain such object, the organic EL device comprises a hole injecting electrode, a negative electrode, and one or more organic layers between the electrodes wherein at least one of said organic layers has a light emitting function. A high resistivity inorganic hole injecting layer is provided between said hole injecting electrode and the organic layer. This layer has conduction paths for electron blockage and hole transportation. An inorganic insulative electron injecting and transporting layer is provided between the light emitting layer and the negative electrode. This layer contains at least one oxide selected from strontium oxide, magnesium oxide, calcium oxide, lithium oxide, rubidium oxide, potassium oxide, sodium oxide and cesium oxide as its main component.
    • 本发明的有机EL器件的目的在于实现具有优异的空穴注入效率和提高的发光效率的有机EL器件,并且可以以低的驱动电压进行操作并以低成本制造。 为了达到这个目的,有机EL器件包括空穴注入电极,负电极和电极之间的一个或多个有机层,其中至少一个所述有机层具有发光功能。 在所述空穴注入电极和有机层之间设置有高电阻率的无机空穴注入层。 该层具有电子阻塞和空穴传输的传导路径。 在发光层和负极之间设置无机绝缘性电子注入输送层。 该层含有选自氧化锶,氧化镁,氧化钙,氧化锂,氧化铷,氧化钾,氧化钠,氧化铯为主要成分的至少一种氧化物。
    • 9. 发明授权
    • Organic electroluminescent device
    • 有机电致发光器件
    • US06303239B1
    • 2001-10-16
    • US09241284
    • 1999-02-01
    • Michio AraiIsamu KoboriEtsuo Mitsuhashi
    • Michio AraiIsamu KoboriEtsuo Mitsuhashi
    • H01L3300
    • H01L51/5092H01L51/5221
    • An object of the invention is to achieve an organic EL device which has an extended life, weather resistance, high stability, and high efficiency, and is inexpensive as well. This object is accomplished by the provision of an organic EL device comprising a substrate, a pair of a hole injecting electrode and a cathode formed on the substrate, and an organic layer located between these electrodes and taking part in at least a light emission function, wherein between the organic layer and the cathode there is provided an inorganic insulating electron injecting and transporting layer comprising a first component comprising at least one oxide selected from the group consisting of lithium oxide, rubidium oxide, potassium oxide, sodium oxide and cesium oxide, a second component comprising at least one oxide selected from the group consisting of strontium oxide, magnesium oxide and calcium oxide, and a third component comprising silicon oxide and/or germanium oxide.
    • 本发明的目的在于实现具有延长使用寿命,耐候性,高稳定性和高效率的有机EL器件,并且也便宜。 该目的通过提供一种包括基板,一对空穴注入电极和形成在基板上的阴极的有机EL器件和位于这些电极之间的有机层并且至少参与发光功能来实现, 其中在有机层和阴极之间提供无机绝缘电子注入和传输层,其包含第一组分,该第一组分包含选自氧化锂,氧化铷,氧化钾,氧化钠和氧化铯中的至少一种氧化物, 第二组分包含选自氧化锶,氧化镁和氧化钙中的至少一种氧化物,以及包含氧化硅和/或氧化锗的第三组分。
    • 10. 发明授权
    • Organic electroluminescent device with silicone oxide and/or germanium oxide insulative layer
    • 有机电致发光器件
    • US06208076B1
    • 2001-03-27
    • US09229569
    • 1999-01-13
    • Michio AraiIsamu KoboriEtsuo Mitsuhashi
    • Michio AraiIsamu KoboriEtsuo Mitsuhashi
    • H01L3300
    • H01L51/5088
    • The invention provides an organic EL device comprising a hole injecting electrode, a negative electrode, at least one organic layer between the electrodes, the organic layer including a light emitting layer having a light emitting function, and a hole injecting and transporting layer containing a hole transporting organic material and an inorganic insulative hole injecting and transporting layer formed of an inorganic material between the hole injecting electrode and the light emitting layer. The inorganic insulative hole injecting and transporting layer contains silicon oxide and/or germanium oxide as a main component, the main component having an average composition represented by the formula: (Si1−xGex)Oy wherein 0≦x≦1 and 1
    • 本发明提供了一种有机EL器件,其包括空穴注入电极,负极,电极之间的至少一个有机层,有机层包括具有发光功能的发光层,以及含有孔的空穴注入传输层 在空穴注入电极和发光层之间传输有机材料和由无机材料形成的无机绝缘空穴注入和传输层。 无机绝缘性空穴注入输送层含有氧化硅和/或氧化锗作为主要成分,主成分的平均成分由下式(Si1-xGex)Oy表示,其中0 <= x <= 1, y <= 2。 这种结构使得能够使用有机材料具有空穴注入和输送层,寿命长,耐候性,高稳定性,高效率和低成本的现有技术的器件具有更好的性能。