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    • 8. 发明授权
    • Method and a device for purifying combustion exhaust gas
    • 燃烧废气净化方法和装置
    • US5778667A
    • 1998-07-14
    • US876608
    • 1997-06-16
    • Yukio KinugasaTakaaki ItouNaoto Suzuki
    • Yukio KinugasaTakaaki ItouNaoto Suzuki
    • B01D53/94F01N3/08F01N3/20F01N3/24F01N9/00F01N13/02F01N13/04F02D41/14F01N3/36
    • F01N3/2073B01D53/9481B01D53/9495F01N13/009F01N13/011F01N3/0842F01N3/0871F01N3/2053F01N9/00B01D2251/2062B01D53/9418B01D53/945F01N2240/25F01N2250/12F01N2610/02Y02T10/22Y02T10/24Y02T10/47
    • In the present invention, the No. 1 cylinder of an engine is connected to a first exhaust passage and the No. 2 to No. 4 cylinders are connected to a second exhaust passage. A three-way catalyst and a NO.sub.X absorbent are disposed in the first and second exhaust passage, respectively. A denitrating catalyst is disposed in a common exhaust passage to which the first and second exhaust passage merge. The NO.sub.X absorbent absorbs NO.sub.X when the No. 2 to No. 4 cylinders are operated at a lean air-fuel ratio, and is regenerated, i.e., releases and reduces the absorbed NO.sub.X when the No. 2 to No. 4 cylinders are operated at a rich air-fuel ratio. However, NO.sub.X, without being reduced, is released from the NO.sub.X absorbent during a short period at the beginning of the regenerating operation. In the present invention, the No. 1 cylinder is operated at a rich air-fuel ratio during the short period at the beginning of the regenerating operation in order to produce NH.sub.3 at the three-way catalyst. Therefore, when NO.sub.X without being reduced is released from the NO.sub.X absorbent and flows into the denitrating catalyst on the common exhaust passage, NH.sub.3 produced at the three-way catalyst is also supplied to the denitrating catalyst. Thus, NO.sub.X released from the NO.sub.X absorbent at the beginning of the regenerating operation is reduced at the denitrating catalyst by NH.sub.3 produced at the three-way catalyst.
    • 在本发明中,发动机的1号缸与第一排气通路连接,第2〜4缸与第2排气通路连接。 分别在第一和第二排气通道中设置三元催化剂和NOX吸收剂。 脱气催化剂设置在第一和第二排气通道合流的公共排气通道中。 当2号至4号气缸以稀薄的空燃比运行时,NOX吸收剂吸收NOX,并且再生时,即当第2号至第4号气缸运行时释放并减少吸收的NOX 丰富的空燃比。 然而,在再生操作开始时的短时间内,NOX不被还原,从NOX吸收剂中释放出来。 在本发明中,为了在三元催化剂下生成NH 3,在再生运转开始的短时间内,1号气缸以浓空燃比运转。 因此,当没有还原的NO x从NOX吸收剂中释放并流入共用排气通道的脱硝催化剂时,在三元催化剂上生成的NH 3也被供给到脱硝催化剂。 因此,在再生操作开始时从NOX吸收剂释放的NOX在脱氮催化剂下通过在三元催化剂下产生的NH 3而降低。
    • 10. 发明授权
    • Exhaust gas purification device for an engine
    • 发动机废气净化装置
    • US5746052A
    • 1998-05-05
    • US525892
    • 1995-09-08
    • Yukio KinugasaKouhei IgarashiTakaaki ItouTakehisa YaegashiToshifumi Takaoka
    • Yukio KinugasaKouhei IgarashiTakaaki ItouTakehisa YaegashiToshifumi Takaoka
    • B01D53/94F01N3/20F01N3/22F01N3/24F01N13/02F01N13/04F02D41/04
    • B01D53/9454B01D53/9431B01D53/9477B01D53/9495F01N13/009F01N13/011F01N3/20F01N3/206F01N2240/25F01N2570/14F01N2610/02Y02T10/22
    • In the present invention, the exhaust gas from the engine is divided into a first and a second branch exhaust passages after it passes through a three-way reducing and oxidizing catalyst, and the two branch exhaust passages merge into an exhaust gas outlet passage. In the first branch exhaust passage, an oxidizing catalyst is disposed, and in the exhaust gas outlet passage, a denitrating and oxidizing catalyst is disposed. NO.sub.x in the exhaust gas from the engine is all converted to N.sub.2 and NH.sub.3 by the three-way reducing and oxidizing catalyst and a part of the NH.sub.3 generated by the three-way catalyst flows into the first branch exhaust passage and is converted to NO.sub.x again by the oxidizing catalyst. The amount of NO.sub.x produced by the oxidizing catalyst and the amount of NO.sub.x flowing through the second branch exhaust passage is determined by the flow distribution ratio of the first and the second branch exhaust passages. In this invention, the flow ratio is determined in such a manner that the amount of the NO.sub.x produced by the oxidizing catalyst and the amount of the NH.sub.3 passing through the second branch exhaust passage are stoichiometric to produce N.sub.2 and H.sub.2 O. Therefore, when these exhaust gases flow into the denitrating and oxidizing catalyst after they mix with each other in the exhaust gas outlet passage, all the NO.sub.x and the NH.sub.3 are converted to N.sub.2 and H.sub.2 O by the denitrating and oxidizing catalyst without producing any surplus NO.sub.x or NH.sub.3.
    • 在本发明中,来自发动机的废气在通过三通还原氧化催化剂后被分成第一和第二分支排气通道,两个分支排气通道合流到废气出口通道中。 在第一分支排气通道中设置氧化催化剂,并且在排气出口通道中设置脱硝和氧化催化剂。 来自发动机的废气中的NOx通过三元还原氧化催化剂全部转化为N 2和NH 3,并且由三元催化剂产生的一部分NH 3流入第一分支排气通道并再次转化为NOx 通过氧化催化剂。 由氧化催化剂产生的NOx的量和流过第二分支排气通道的NOx的量由第一和第二分支排气通道的流量分配比确定。 在本发明中,流量比以如下方式确定:氧化催化剂产生的NOx的量和通过第二分支排气通道的NH 3的量是化学计量的,以产生N 2和H 2 O. 因此,当这些废气在废气出口通道中彼此混合后流入脱硝和氧化催化剂时,所有的NOx和NH 3都被脱硝和氧化催化剂转化为N 2和H 2 O,而不产生任何剩余的NOx或 NH3。