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    • 8. 发明授权
    • Method and a device for purifying combustion exhaust gas
    • 燃烧废气净化方法和装置
    • US5778667A
    • 1998-07-14
    • US876608
    • 1997-06-16
    • Yukio KinugasaTakaaki ItouNaoto Suzuki
    • Yukio KinugasaTakaaki ItouNaoto Suzuki
    • B01D53/94F01N3/08F01N3/20F01N3/24F01N9/00F01N13/02F01N13/04F02D41/14F01N3/36
    • F01N3/2073B01D53/9481B01D53/9495F01N13/009F01N13/011F01N3/0842F01N3/0871F01N3/2053F01N9/00B01D2251/2062B01D53/9418B01D53/945F01N2240/25F01N2250/12F01N2610/02Y02T10/22Y02T10/24Y02T10/47
    • In the present invention, the No. 1 cylinder of an engine is connected to a first exhaust passage and the No. 2 to No. 4 cylinders are connected to a second exhaust passage. A three-way catalyst and a NO.sub.X absorbent are disposed in the first and second exhaust passage, respectively. A denitrating catalyst is disposed in a common exhaust passage to which the first and second exhaust passage merge. The NO.sub.X absorbent absorbs NO.sub.X when the No. 2 to No. 4 cylinders are operated at a lean air-fuel ratio, and is regenerated, i.e., releases and reduces the absorbed NO.sub.X when the No. 2 to No. 4 cylinders are operated at a rich air-fuel ratio. However, NO.sub.X, without being reduced, is released from the NO.sub.X absorbent during a short period at the beginning of the regenerating operation. In the present invention, the No. 1 cylinder is operated at a rich air-fuel ratio during the short period at the beginning of the regenerating operation in order to produce NH.sub.3 at the three-way catalyst. Therefore, when NO.sub.X without being reduced is released from the NO.sub.X absorbent and flows into the denitrating catalyst on the common exhaust passage, NH.sub.3 produced at the three-way catalyst is also supplied to the denitrating catalyst. Thus, NO.sub.X released from the NO.sub.X absorbent at the beginning of the regenerating operation is reduced at the denitrating catalyst by NH.sub.3 produced at the three-way catalyst.
    • 在本发明中,发动机的1号缸与第一排气通路连接,第2〜4缸与第2排气通路连接。 分别在第一和第二排气通道中设置三元催化剂和NOX吸收剂。 脱气催化剂设置在第一和第二排气通道合流的公共排气通道中。 当2号至4号气缸以稀薄的空燃比运行时,NOX吸收剂吸收NOX,并且再生时,即当第2号至第4号气缸运行时释放并减少吸收的NOX 丰富的空燃比。 然而,在再生操作开始时的短时间内,NOX不被还原,从NOX吸收剂中释放出来。 在本发明中,为了在三元催化剂下生成NH 3,在再生运转开始的短时间内,1号气缸以浓空燃比运转。 因此,当没有还原的NO x从NOX吸收剂中释放并流入共用排气通道的脱硝催化剂时,在三元催化剂上生成的NH 3也被供给到脱硝催化剂。 因此,在再生操作开始时从NOX吸收剂释放的NOX在脱氮催化剂下通过在三元催化剂下产生的NH 3而降低。
    • 10. 发明授权
    • Exhaust gas purification device for an internal combustion engine
    • 内燃机用废气净化装置
    • US06336320B1
    • 2002-01-08
    • US09345406
    • 1999-07-01
    • Hiroshi TanakaToshio TanahashiNaoto Suzuki
    • Hiroshi TanakaToshio TanahashiNaoto Suzuki
    • F01N300
    • F01N3/0842F01N3/0814F01N9/00F01N13/009F01N13/011F01N2250/12F01N2570/16F02D41/0275F02D41/1462F02D41/1465F02D41/3011F02D41/3029F02D41/402F02D41/405F02D2200/0806F02D2200/0814F02D2200/0818Y02T10/44Y02T10/47
    • Start catalysts (SCs) having an O2 storage function are disposed in an exhaust gas passage of an internal combustion engine, and an NOx occluding and reducing catalyst is disposed in the exhaust gas passages downstream of the SCs. NOx in the exhaust gas is absorbed by the NOx occluding and reducing catalyst when the engine is in operation at a lean air-fuel ratio. When NOx is to be released, the engine is operated at a rich air-fuel ratio so that exhaust gas having a rich air-fuel ratio flows into the SCs and into the NOx occluding and reducing catalyst. An electronic control unit (ECU) executes the secondary fuel injection that does not contribute to the combustion in the expansion stroke or in the exhaust stroke of each cylinder by using a direct cylinder fuel injection valve at the time when the engine operating air-fuel ratio is to be changed from a lean air-fuel ratio operation to a rich air-fuel ratio, so that exhaust gas having a rich air-fuel ratio flows into the SC and that oxygen stored in the SC is released. At the time of changing over the air-fuel ratio, therefore, the air-fuel ratio is changed from the lean side to the rich side without delay, eliminating such an occurrence that NOx is released from the NOx occluding and reducing catalyst without being purified at the time of changing the air-fuel ratio.
    • 具有O 2储存功能的起始催化剂(SC)被设置在内燃机的排气通道中,并且NOx吸留还原催化剂设置在SC的下游的排气通道中。 当发动机以稀薄的空燃比运转时,废气中的NOx被NOx吸留和还原催化剂吸收。 当要释放NOx时,发动机以丰富的空燃比运转,使得具有浓空燃比的废气流入SC并进入NOx吸留和还原催化剂。 电子控制单元(ECU)通过在发动机工作空燃比(ECU)中使用直接气缸燃料喷射阀来执行对膨胀行程或每个气缸的排气冲程中的燃烧无贡献的二次燃料喷射 从稀空燃比操作变为浓空燃比,使得具有浓空燃比的废气流入SC,并且释放存储在SC中的氧。 因此,在空燃比变化的时候,空燃比从稀侧变为富侧无效,消除了NOx从NO X吸留还原催化剂释放而不被净化的情况 在改变空燃比的时候。