会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 1. 发明授权
    • Cellulose sulfate salt having anti-coagulating action and process for
preparing same
    • 具有抗凝作用的硫酸纤维素盐及其制备方法
    • US4389523A
    • 1983-06-21
    • US324918
    • 1981-11-25
    • Kunihiko OkajimaKenji KamideToshihiko Matsui
    • Kunihiko OkajimaKenji KamideToshihiko Matsui
    • A61K31/715A61P7/02C08B5/14C08G18/10
    • C08B5/14
    • A cellulose sulfate salt having a heparinic action is provided, which satisfies requirements of 0.8.ltoreq. >.ltoreq.2.6, >.gtoreq. > and >.gtoreq. > wherein >, > and > stand for probability of substitution of atoms H in the OH groups bonded to the C.sub.2, C.sub.3 and C.sub.6 positions of the glucopyranose ring unit by sulfuric acid radicals, respectively, and > stands for the total substitution degree which is the sum of >, > and >. The cellulose sulfate salt is prepared by reacting a cellulose having a crystal form I with an SO.sub.3 /amine or SO.sub.3 /amide complex in an amount of 2 to 4 mole equivalents per glucose unit of the cellulose at -10.degree. C. to 40.degree. C. to form a gelatinous product; adding water to the gelatinous product in an amount 0.1 to 5 times the amount of the starting cellulose used for the reaction; treating the mixture at a high temperature to relatively reduce the values of > and > among the values of >, > and >; neutralizing, precipitating and drying the so obtained crude cellulose sulfate; dissolving the crude cellulose sulfate in water again; treating the solution with an adsorbent; and subjecting the treated cellulose sulfate to precipitation, drying, re-dissolution, dialysis, precipitation and then drying.
    • 提供了具有肝素作用的纤维素硫酸盐,其满足0.8 >> / = << f3 >>和<< f2 >>> / = << f6 >>其中“f2”,“f3”和“f6”代表与吡喃葡萄糖环单元的C2,C3和C6位置键合的OH基团中原子H的取代概率 分别为硫酸基,“F”代表总取代度,它是“f2”,“f3”和“f6”之和。 硫酸纤维素盐是通过在-10℃至40℃下使具有结晶形式I的纤维素与SO 3 /胺或SO 3 /酰胺络合物的量相对于纤维素的每葡萄糖单位为2至4摩尔当量 形成凝胶状产品; 向凝胶状产物中加入水,其量为用于反应的起始纤维素的量的0.1至5倍; 在“f2”,“F3”和“f6”的值之间,在高温下处理混合物以相对减小<< f6 >>和<< f3 >>的值。 中和,沉淀和干燥所得粗硫酸纤维素; 再次将粗硫酸纤维素溶解在水中; 用吸附剂处理溶液; 并将经处理的硫酸纤维素进行沉淀,干燥,再溶解,透析,沉淀,然后干燥。
    • 4. 发明授权
    • Cellulose derivative excellent in liquid absorbing property, process for
preparing same and structure containing same
    • 液体吸收性优异的纤维素衍生物,其制备方法和含有其的结构
    • US4579943A
    • 1986-04-01
    • US666445
    • 1984-10-30
    • Kenji KamideKunihiko Okajima
    • Kenji KamideKunihiko Okajima
    • A61L15/28C08B11/12C08B15/04
    • C08B11/12A61L15/28Y10T428/31971Y10T442/3976Y10T442/696
    • Disclosed is carboxymethyl cellulose or its salt derived from cellulose having a crystal form of cellulose II, wherein the total saturation degree > represented by the following formula: >= >+ >+ >wherein >, > and > represent the probabilities of substitution of substituent groups for OH groups located at the C.sub.2, C.sub.3 and C.sub.6 positions, respectively, of the glucose ring constituting the cellulose,is in the range of from 0.10 to 0.64. This carboxymethyl cellulose or its salt is excellent in liquid absorbing property and is prepared by treating cellulose having a crystal form of cellulose II with an alkali and then reacting the treated cellulose with monochloroacetic acid or sodium monochloroacetate. This carboxymethyl cellulose or its salt can be used in the form of a structure such as a sheet, a woven fabric or a nonwoven fabric.
    • 公开了由具有纤维素II的结晶形式的纤维素衍生的羧甲基纤维素或其盐,其中由下式表示的总饱和度“F”:<< F >> = << f2 >> + << f3> > + << f6 >>其中“f2”,“f3”和“f6”分别代表位于C2,C3和C6位置的OH基团的取代基取代的概率 构成纤维素的葡萄糖环的范围为0.10〜0.64。 该羧甲基纤维素或其盐具有优异的液体吸收性能,并且通过用碱处理具有纤维素II结晶形式的纤维素,然后使处理的纤维素与一氯乙酸或一氯乙酸钠反应来制备。 该羧甲基纤维素或其盐可以以片状,机织织物或无纺布等结构的形式使用。
    • 5. 发明授权
    • Cellulose dope, process for preparation and method for application
thereof
    • 纤维素涂料,制备方法及其应用方法
    • US4634470A
    • 1987-01-06
    • US675762
    • 1984-11-28
    • Kenji KamideKunihiko Okajima
    • Kenji KamideKunihiko Okajima
    • D06M15/05C08B1/00C08B16/00C08L1/02D06M101/00D06M101/02D06M101/06D06M101/08D06M101/16D06M101/18D06M101/30D06M101/32D06M101/34C08L1/00
    • C08L1/02C08B1/00C08B16/00
    • Described is a cellulose dope which is an aqueous alkali solution containing substantially at least 3% by weight of cellulose having a degree of polymerization of at least 100, wherein in the .sup.13 C-NMR spectrum of the cellulose, the C.sub.4 -position carbon peak is found at a magnetic field higher by at least 7 ppm than the magnetic field of the C.sub.4 -position carbon peak of solid cellulose attributed to the strong intramolecular hydrogen bond. This dope is prepared by maintaining a mixture comprising 100 weight parts of cellulose, which may have any crystal form, and 10 to 1000 weight parts of a hydrogen bond-cleaving solution at 100.degree. C. to 350.degree. C. under a pressure of 10 to 250 atmospheres, promptly exposing the mixture to the ambient atmosphere, mixing the resulting cellulose with an aqueous alkali solution maintained at a temperature not higher than 50.degree. C., and then stirring the mixture at a temperature not higher than 10.degree. C. to dissolve the cellulose in the aqueous alkali solution. The dope may be used for the manufacture of a shaped article or for coating.
    • 描述了一种纤维素涂料,其是基本上含有至少3重量%的聚合度至少为100的纤维素的碱性水溶液,其中在纤维素的13 C-NMR光谱中发现了C4位碳峰 在比由强分子内氢键归因于固体纤维素的C4位碳峰的磁场高至少7ppm的磁场。 通过在100℃至350℃的压力下保持包含100重量份可以具有任何结晶形式的纤维素和10-1000重量份氢键解链溶液的混合物来制备该涂料, 至250个大气压,迅速将混合物暴露于环境气氛下,将得到的纤维素与维持在不高于50℃的碱性水溶液混合,然后在不高于10℃的温度下搅拌混合物至 将纤维素溶解在碱性水溶液中。 涂料可用于制造成型制品或用于涂覆。
    • 6. 发明授权
    • Edible body and process for preparation thereof
    • 食用体及其制备方法
    • US4994285A
    • 1991-02-19
    • US243306
    • 1988-08-08
    • Jinpei HisanoAkihiro GotoKunihiko Okajima
    • Jinpei HisanoAkihiro GotoKunihiko Okajima
    • A23L1/308C08L1/06
    • C08L1/06A23L33/24Y10S426/802Y10S426/803
    • An edible body composed of a cellulose having a crystal form of cellulose II, which is regenerated from an aqueous solution of an alkali metal hydroxide, and at least one guest component selected from polypeptides and edible polysaccharides. The cellulose II or a homogeneous mixture of the cellulose II and polysaccharide is present in the form of a sea component or a continuous phase in an amount of at least 10% based on the edible body. The edible body is made by adding at least one guest component selected from polypeptides, polysaccharides and living body constituents composed mainly thereof to an alkali solution in which up to 50 parts by weight of an undissolved cellulose is swollen and dispersed per 100 parts by weight of a dissolved cellulose, directly or after dissolution in an aqueous solution of an alkali, to form a dope in which at least 50% by weight of the total guest component is dissolved, extruding the dope through an extruder, coagulating the extrudate, and neutralizing, water-washing and, if necessary, drying the extrudate.
    • PCT No.PCT / JP86 / 00535 Sec。 371日期1988年8月8日第 102(e)日期1988年8月8日PCT提交1986年10月22日PCT公布。 出版物WO88 / 02991 日期:1988年5月5日。一种由碱金属氢氧化物水溶液再生的具有纤维素II结晶形式的纤维素的组合物和至少一种选自多肽和食用多糖的客体成分。 纤维素II或纤维素II和多糖的均匀混合物以海成分或连续相的形式存在,其量相对于食用体为至少10%。 通过将至少一种选自多肽,多糖和主要成分的生物体成分的客体成分添加至碱溶液中,至少含有50重量份的未溶解的纤维素溶胀并分散,每100重量份的 溶解的纤维素,直接或溶解在碱的水溶液中,形成其中溶解总客体成分的至少50重量%的涂料,通过挤出机挤出纺丝液,使挤出物凝结,中和, 水洗,如果需要,干燥挤出物。
    • 8. 发明授权
    • Cellulose dope and method for producing the same
    • 纤维素涂料及其制造方法
    • US07108907B1
    • 2006-09-19
    • US09546665
    • 2000-10-25
    • Chihiro YamaneKunihiko OkajimaSeiji Shimizu
    • Chihiro YamaneKunihiko OkajimaSeiji Shimizu
    • D04H1/00D04H3/00B32B23/00
    • C08B1/003D01F2/02Y10T428/249924Y10T428/2913Y10T428/2965
    • A cellulose dope comprising an aqueous sodium hydroxide solution and cellulose dissolved in the solution, wherein the cellulose dope has a sodium hydroxide concentration (CNa) of from 6.5 to 11% by weight, a cellulose content (Cc) of from 5 to 10% by weight, a viscosity average degree of polymerization (DPc) of the cellulose of from 350 to 1,200 and a cellulose dissolution ratio (Sc) of 99.0% by weight or more, and wherein the zero-shear viscosity (η0) and the cellulose content (Cc) of the cellulose dope and the viscosity average degree of polymerization (DPc) of the cellulose in the cellulose dope satisfy the following formula (1): η0=kCcm×DPcp   (1) wherein: η0 represents the zero-shear viscosity (mPa·s) of the cellulose dope, Cc represents the cellulose content (% by weight) of the cellulose dope, DPc represents the viscosity average degree of polymerization of the cellulose in the cellulose dope, k=3.9×10−11, m is a number of from 5 to 7, and p is a number of from 3 to 4.
    • 一种含有氢氧化钠水溶液和溶于该溶液中的纤维素的纤维素原液,其中纤维素掺杂物的氢氧化钠浓度为6.5-11%(重量),纤维素含量(Cc )为5〜10重量%,纤维素的粘度平均聚合度(DPc)为350〜1200,纤维素溶解率(Sc)为99.0重量%以上,其中零剪切粘度 纤维素掺杂物的纤维素含量(Cc)和纤维素掺杂物中的纤维素的粘度平均聚合度(DPc)满足下式(1):&lt;&lt;&lt; 0&gt; -line-formula description =“In-line Formulas”end =“lead”?> eta = kCc xDPc

      (1) <?in-line-formula description =“In-line Formulas”end =“tail”?>其中:eta 0表示纤维素原料的零剪切粘度(mPa.s),Cc 表示纤维素的纤维素含量(重量%) 糊剂,DPc表示纤维素原液中纤维素的粘度平均聚合度,k = 3.9×10 -6,m为5〜7的数,p为3 到4。