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1. 发明授权

US4980042A Oxygen sensor and method of making it 失效
标题翻译：氧传感器及其制作方法
公开(公告)号：US4980042A
公开(公告)日：1990-12-25
申请号：US432444
申请日：1989-11-06
申请人： Haruhisa Shiomi , Toshihiko Aoyama , Yoshitake Kawachi , Ken Minoha
发明人： Haruhisa Shiomi , Toshihiko Aoyama , Yoshitake Kawachi , Ken Minoha
IPC分类号： G01N27/406 , G01N27/409
CPC分类号： G01N27/4067
摘要： An oxygen sensor comprising a hollow cylindrical member closed at one end but open at the other to admit a reference gas. There is at least one radial through-hole in the hollow cylindrical member. An oxygen-ion conductive solid electrolyte later has at least one pair of electrodes on its opposite sides. The electrolyte layer is wrapped around the hollow cylindrical member with the electrode on its inner side facing the through hole. In other embodiments, an oxygen sensor is provided which is very insensitive to the direction of flow of the gas to be analyzed. The electrodes of the sensor are spaced at substantially equal intervals on the circumference of a cylindrical solid electrolyte layer in registry with through-holes formed in a hollow tubular member surrounded by the electrolyte layer. A heating unit may be formed on either the inner or outer surface of the solid electrolyte layer.
摘要翻译：一种氧传感器，包括在一端封闭但在另一端封闭以容纳参考气体的中空圆柱形构件。中空圆柱形构件中至少有一个径向通孔。之后的氧离子导电固体电解质在其相对侧上具有至少一对电极。电解质层缠绕在中空圆柱形构件上，其电极在其内侧面向通孔。在其它实施例中，提供了对待分析气体的流动方向非常不敏感的氧传感器。传感器的电极在圆柱形固体电解质层的圆周上以基本上相等的间隔间隔开，与形成在由电解质层包围的中空管状构件中的通孔对齐。可以在固体电解质层的内表面或外表面上形成加热单元。

2. 发明授权

US5139829A Method for producing oxygen detection element 失效
标题翻译：氧检测元件生产方法
公开(公告)号：US5139829A
公开(公告)日：1992-08-18
申请号：US727361
申请日：1991-07-09
申请人： Ken Minoha , Haruhisa Shiomi , Yoshitake Kawachi
发明人： Ken Minoha , Haruhisa Shiomi , Yoshitake Kawachi
IPC分类号： C23C26/00 , G01N27/407 , G01N27/416
CPC分类号： G01N27/4075
摘要： A method for producing an oxygen detection element having uniform pores and an excellent durability against toxic matter contained in the measurement gas. The method includes a first step of applying a paste to be sintered to form a catalytic electrode layer onto at least a part of an oxygen-ion conductive solid-state electrolytic body, and sintering the paste to thereby form said catalytic electrode layer at a predetermined position on said surface of said solid-state electrolytic body after sintering, and a second step of forming an electrode protection layer for coating and protecting at least a part of the catalytic electrode layer either after or simultaneous with the first step. In a first embodiment, the paste contains mainly a noble metal powder acting as a catalyst and an organic metal compound, in a second embodiment mainly co-precipitated powder consisting of a noble metal and a metal hydroxide, and in a third embodiment mainly noble metal powder and a powder of a metal other than a noble metal.
摘要翻译：一种具有均匀孔的氧检测元件的制造方法和对测定气体中含有的有毒物质的耐久性。该方法包括：第一步骤，将待烧结的糊料施加到氧离子导电固态电解质体的至少一部分上形成催化剂电极层，并烧结该糊料，从而以预定的方式形成所述催化剂电极层烧结后所述固体电解质体的表面上的位置，以及在第一步骤之后或与第一步骤同时形成用于涂覆和保护至少一部分催化电极层的电极保护层的第二步骤。在第一实施方案中，糊料主要含有作为催化剂的贵金属粉末和有机金属化合物，在第二实施方案中主要是由贵金属和金属氢氧化物组成的共沉淀粉末，在第三实施方案中主要是贵金属粉末和除贵金属以外的金属的粉末。

3. 发明授权

US5753893A Alumina-based sintered material for ceramic heater 失效
标题翻译：氧化铝基陶瓷加热烧结材料
公开(公告)号：US5753893A
公开(公告)日：1998-05-19
申请号：US815586
申请日：1997-03-12
申请人： Yoshiro Noda , Yoshiro Suematsu , Toshihiko Aoyama , Yoshitake Kawachi
发明人： Yoshiro Noda , Yoshiro Suematsu , Toshihiko Aoyama , Yoshitake Kawachi
IPC分类号： C04B35/111 , H05B3/14 , H05B3/18 , H05B3/10 , H05B3/38
CPC分类号： H05B3/18 , C04B35/111 , H05B3/141
摘要： An alumina-based sintered material for ceramic heater having a resistance heater embedded in its ceramic material. With the total amount of Al.sub.2 O.sub.3, SiO.sub.2, MgO and CaO being 100 wt %, the sintered material contains 91 to 97 wt % of Al.sub.2 O.sub.3, 1 to 8 wt % of SiO.sub.2, 0.2 to 1.2 wt % of MgO and 0.2 to 1.2 wt % of CaO, the total amount of MgO and CaO being 0.4 to 1.8 wt %, whereas, for the total amount of Al.sub.2 O.sub.3, MgO and CaO of 100 wt %, 0.1 to 15 wt % of (a) at least one of rare earth elements and groups IVa excluding Ti, Va and VIa of the Periodic Table are contained in the sintered material. In place of (a), 0.2 wt % or less of other elements (Na, K, Fe, Ti etc.) may also be contained in an amount not more than 0.2 wt %, calculated in terms of oxides.
摘要翻译：一种用于陶瓷加热器的氧化铝基烧结材料，其具有嵌入其陶瓷材料中的电阻加热器。 Al2O3，SiO2，MgO，CaO的总量为100重量％时，烧结体的Al 2 O 3为91〜97重量％，SiO 2为1〜8重量％，MgO为0.2〜1.2重量％，MgO为0.2〜1.2重量％的CaO，MgO和CaO的总量为0.4〜1.8重量％，而对于Al 2 O 3，MgO和CaO的总量为100重量％，0.1〜15重量％的（a）稀土元素中的至少一种除了周期表中的Ti，Va和VIa之外的组IVa包含在烧结材料中。代替（a），根据氧化物计算，也可以含有0.2重量％以下的其他元素（Na，K，Fe，Ti等）的量不大于0.2重量％。

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