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    • 3. 发明授权
    • Amphoteric ion-permeable composite membrane
    • 两性离子渗透复合膜
    • US4360434A
    • 1982-11-23
    • US225324
    • 1981-01-15
    • Takeyuki KawaguchiHiroyoshi MinematsuYuzuru HayashiShigeyoshi HaraFumio Ueda
    • Takeyuki KawaguchiHiroyoshi MinematsuYuzuru HayashiShigeyoshi HaraFumio Ueda
    • B01D67/00B01D69/12B01D71/60C08J5/22G01N27/40B05D3/10B05D5/00
    • B01D67/0093B01D69/125B01D71/60G01N27/40B01D2323/30Y10T428/249978Y10T428/249981
    • An amphoteric ion-permeable composite membrane composed of a microporous substrate, and supported on the substrate, a thin amphoteric ion-exchange film formed of an active amino group-containing polymer which has been interfacially crosslinked at least at the surface portion of the thin film, said membrane being produced by forming a thin layer comprising an active amino group-containing polymer containing 1.0 to 23 milliequivalents/g, as amino equivalent, of an active amino group selected from primary and secondary amino groups and 0 to 18 milliequivalents/g, as amino equivalent, of a tertiary amino group and/or an ammonium salt group per molecule with the total amino content thereof being in the range of 2.0 to 23 milliequivalents/g on the microporous substrate and then contacting the thin layer on the substrate interfacially with a polyfunctional aromatic compound containing at least two functional groups selected from carbonyl halide groups, sulfonyl halide groups, carboxylic acid anhydride groups, sulfonic acid anhydride groups and derivative groups of carboxylic acids and sulfonic acids having equivalent reactivity to the aforesaid halide and anhydride groups.
    • 由微孔基材构成并负载在基板上的两性离子透过性复合膜由至少在薄膜的表面部分进行了界面交联的含活性氨基聚合物形成的薄的两性离子交换膜 所述膜通过形成包含含有选自伯氨基和仲氨基的活性氨基和0至18毫当量/克的作为氨基当量的1.0至23毫当量/克的含有活性氨基的聚合物的薄层, 作为氨基当量的每个分子的叔氨基和/或铵盐基团,其总氨基含量在微孔基材上在2.0至23毫当量/ g的范围内,然后使基底上的薄层与 含有至少两个选自羰基卤基,磺酰卤基,羧酸的官能团的多官能芳族化合物 酸酐基团,磺酸酐基团和与上述卤化物和酸酐基团具有等同反应性的羧酸和磺酸的衍生基团。
    • 5. 发明授权
    • Process for preparation of improved semipermeable composite membranes
    • 改良半透膜复合膜的制备方法
    • US4388189A
    • 1983-06-14
    • US220081
    • 1980-12-24
    • Takeyuki KawaguchiHiroyoshi MinematsuYuzuru HayashiShigeyoshi Hara
    • Takeyuki KawaguchiHiroyoshi MinematsuYuzuru HayashiShigeyoshi Hara
    • B01D71/28B01D69/12B01D71/38B01D71/48B01D71/52B01D71/60B01D71/66B01D71/82B01D31/00
    • B01D69/125B01D71/60
    • In a process for producing a semipermeable composite membrane which comprises forming on a microporous substrate a thin layer of a polymeric material comprising a polyamino polymer containing at least 1 milliequivalent, per gram of the polymer in the dry state, of active amino groups selected from primary amino groups and secondary amino groups, and thereafter interfacially crosslinking a surface portion of said thin layer with a crosslinking agent having at least two functional groups (a) capable of easily reacting with either the primary or secondary amino groups or both in said polymer; the improvement wherein(1) said polymeric material contains dispersed therein a polyfunctional compound having at least two functional groups (b) substantially incapable of reacting with the primary or secondary amino groups in said polymer at a temperature at which the interfacial crosslinking is carried out, but capable of reacting easily with either the primary or secondary amino groups or both in said polymer at a temperature at least 30.degree. C. higher than said crosslinking temperature, and(2) the interfacially crosslinked thin layer is heated to a temperature at which said polyfunctional compound reacts with the primary or secondary amino groups or both in said polymer.
    • 在一种制备半透膜复合膜的方法中,该方法包括在微孔基材上形成包含聚氨基聚合物的聚合物材料的薄层,所述聚合物材料含有至少1毫当量的每克干燥状态的聚合物,选自主要 氨基和仲氨基,然后用具有至少两个能够容易地与所述聚合物中的伯或仲氨基反应的二官能团(a)的交联剂与所述薄层的表面部分进行界面交联; 改进之处在于(1)所述聚合材料含有分散有至少两个官能团的多官能化合物(b)在进行界面交联的温度下基本上不能与所述聚合物中的伯或仲氨基发生反应, 但能够在高于所述交联温度的至少30℃的温度下容易地与所述聚合物中的伯或仲氨基或两者反应,和(2)将界面交联的薄层加热至所述 多官能化合物与所述聚合物中的伯或仲氨基或两者反应。