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1. 发明专利

BRPI0616915A2 未知
公开(公告)号：BRPI0616915A2
公开(公告)日：2013-01-01
申请号：BRPI0616915
申请日：2006-10-04
申请人： MUSASHINO KAGAKU KENKYUSHO , MUTUAL CORP , YOSHIHARU KIMURA , TEIJIN LTD
发明人： SUZUKI HIROTAKA , TOYOHARA KIYOTSUNA , TO SHIN
IPC分类号： C08L67/04 , C08K3/00 , C08K5/00 , C08K5/51 , C08L101/16
摘要： A composition which comprises polylactide and has excellent heat stability, color and hydrolytic resistance. The composition comprises (i) polylactide, (ii) a metal catalyst and (iii) a hypophosphorous acid-based deactivator or a metaphosphoric acid-based deactivator.

2. 发明专利

JP2006307071A Preparing process of polylactic acid 有权
标题翻译：聚乳酸的制备方法
公开(公告)号：JP2006307071A
公开(公告)日：2006-11-09
申请号：JP2005133191
申请日：2005-04-28
申请人： Yoshiharu Kimura , Musashino Chemical Laboratory Ltd , Mutual:Kk , Teijin Ltd , 帝人株式会社 , 良晴木村 , 株式会社ミューチュアル , 株式会社武蔵野化学研究所
发明人： KIMURA YOSHIHARU , FUKUSHIMA KAZUKI , TO SHIN , TOYOHARA KIYOTSUNA
IPC分类号： C08G63/80
摘要： PROBLEM TO BE SOLVED: To provide a preparing process of a polylactic acid with a high molecular weight under mild solid phase polymerization conditions and to provide a preparing method of a polylactic acid with a high stereocomplex crystal content ratio and with a high molecular weight.
SOLUTION: The preparing method of the polylactic acid (I) comprises mixing poly-L-lactic acid (L composition) and poly-D-lactic acid (D composition) and preparing a polylactic acid blend of which the stereocomplex crystal content ratio (Fs) is 0.6 or less, and then conducting the solid phase polymerization of the polylactic acid blend. The preparing method of the polylactic acid includes a melting method of the polylactic acid after the solid phase polymerization.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：为了提供在温和的固相聚合条件下具有高分子量的聚乳酸的制备方法，并提供具有高立体络合物晶体含量比和高分子量的聚乳酸的制备方法重量。解决方案：聚乳酸（I）的制备方法包括将聚-L-乳酸（L组合物）和聚-D-乳酸（D组合物）混合并制备其中立体络合物晶体含量比率（Fs）为0.6以下，然后进行聚乳酸共混物的固相聚合。聚乳酸的制备方法包括固相聚合后的聚乳酸的熔融法。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2006036808A Stereocomplex polylactic acid and its manufacturing process 有权
标题翻译：立体聚酯多糖及其制造方法
公开(公告)号：JP2006036808A
公开(公告)日：2006-02-09
申请号：JP2004214496
申请日：2004-07-22
申请人： Yoshiharu Kimura , Musashino Chemical Laboratory Ltd , Mutual:Kk , Teijin Ltd , 帝人株式会社 , 良晴木村 , 株式会社ミューチュアル , 株式会社武蔵野化学研究所
发明人： NONOKAWA RYUJI , TOYOHARA KIYOTSUNA , MAEDA YASUTO , KOMAZAWA TOMOKA , KIMURA YOSHIHARU
IPC分类号： C08L67/04 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a stereocomplex polylactic acid which has a large molecular weight, an excellent moldability and a high melting point and is highly crystalline.
SOLUTION: The stereocomplex polylactic acid consists of (A) a polylactic acid unit A composed of a 90-99 mol% L-lactic acid unit and a 1-10 mol% D-lactic acid unit other than lactic acid and/or copolymer unit composed of lactic acid and (B) a polylactic acid unit B composed of a 90-99 mol% D-lactic acid unit and a 1-10 mol% L-lactic acid unit and/or a copolymer unit and has an average molecular weight of 100,000-500,000 and a ratio of the melting peak at ≥195°C of ≥80% in the melting peaks appearing in the course of rising temperature in differential scanning colorimetry (DSC).
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有大分子量，优异的成型性和高熔点并且高度结晶的立体络合物聚乳酸。解决方案：立体络合物聚乳酸由（A）由乳酸和/或乳酸组成的90-99mol％L-乳酸单元和1-10mol％D-乳酸单元组成的聚乳酸单元A和/ 或由乳酸组成的共聚物单元和（B）由90-99摩尔％D-乳酸单元和1-10摩尔％L-乳酸单元和/或共聚物单元组成的聚乳酸单元B，并且具有平均分子量为100,000-500,000，差示扫描比色法（DSC）中在温度升高过程中出现的熔融峰中，≥195℃下的熔融峰的比例为≥80％。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2003041751A Structure of floor securing air layer by incorporating netted sheet 审中-公开
标题翻译：通过并网安装地板安装空气层的结构
公开(公告)号：JP2003041751A
公开(公告)日：2003-02-13
申请号：JP2001260481
申请日：2001-07-26
申请人： Yoshiharu Kimura , 義晴木村
发明人： KIMURA YOSHIHARU
IPC分类号： E04F15/00 , E04F15/02 , E04F15/20
摘要： PROBLEM TO BE SOLVED: To respond to requirements for shielding daily life noises produced in an upper-floor dwelling house without affecting a lower-floor dwelling house in a floor structure of the dwelling house, especially in a multistoried dwelling house.
SOLUTION: An air layer is provided between a part of a finishing material constituting a floor and a backing plate and formed into non-contact therewith so as to prevent the transmission of the daily lift noises produced on the finishing material surface to other parts. However, this constitution cannot bear the live load and the dead weight of the floor so that a reticulate sheet made of a high-strength and high-durability resin fiber as a material is incorporated therein so as to compatibly secure both the air layer and the load resistance.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：为了满足在上层住宅中生产的日常生活噪音的要求，而不影响住宅楼层结构中的低层住宅，特别是在多层住宅中。解决方案：在构成地板的整理材料的一部分和背板之间设置空气层，并形成与其不接触的空气层，以防止在整理材料表面上产生的每日提升噪声传播到其它部分。然而，这种构造不能承受地板的活载荷和自重，使得由高强度和高耐久性树脂纤维制成的网状片材作为材料被并入其中，以便将空气层和负载电阻。

5. 发明专利

JPS59204620A Production of high-molecular weight organoaluminum polymer 失效
标题翻译：生产高分子量有机铝聚合物
公开(公告)号：JPS59204620A
公开(公告)日：1984-11-20
申请号：JP7983783
申请日：1983-05-07
申请人： Toshiaki Ichimura , Yoshiharu Kimura , Isoji Taniguchi
发明人： TANIGUCHI ISOJI , KIMURA YOSHIHARU , ICHIMURA TOSHIAKI
IPC分类号： C08G79/00 , C08G79/10
摘要： PURPOSE: To obtain the titled polymer easily with a efficiency, by adding specific amounts of water and an organic acid to a specific organoaluminum compound before or after the reaction thereof with water, and suitable for molding fibers, etc.
CONSTITUTION: After an organoaluminum compound of the formula (X and Y are H, alkyl or alkoxyl; R is organic group), e.g. diethylaluminum 3-ethoxypropionate, is reacted with water or before water is added thereto, water in a molar amount of 1.0W3.5 times of that of the above-mentioned organoaluminum compound and an organic acid, e.g. 3-ethoxypropionic acid, in a molar amount of 0.2W10 times of that of the above-mentioned organoaluminum compound are added and reacted therewith to give the aimed polymer.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了有效地获得标题的聚合物，可以通过在与水反应之前或之后向特定的有机铝化合物加入特定量的水和有机酸，并适合于模制纤维等。构成：在有机铝化合物的式（X和Y是H，烷基或烷氧基; R是有机基团），例如二乙基铝3-乙氧基丙酸酯与水反应或加入水之前，摩尔量为上述有机铝化合物的1.0-3.5倍的水和有机酸，例如，加入摩尔量为上述有机铝化合物的0.2-10倍的3-乙氧基丙酸并与其反应，得到目标聚合物。

6. 发明专利

JPS59193926A Preparation of organo-aluminum polymer having high molecular weight 失效
标题翻译：具有高分子量的有机铝聚合物的制备
公开(公告)号：JPS59193926A
公开(公告)日：1984-11-02
申请号：JP6756483
申请日：1983-04-16
申请人： Yoshiharu Kimura , Isoji Taniguchi
发明人： TANIGUCHI ISOJI , KIMURA YOSHIHARU
IPC分类号： C08G79/00 , C08G79/10
摘要： PURPOSE: To prepare an organoaluminum compound having high molecular weigt and suitable for the forming of fibers, etc., easily and in high efficiency, by carrying out the polycondensation reaction of an organo-Al compound with water using specific amounts of water and an organic acid and adding the organic acid to the reaction system at a specific reaction stage.
CONSTITUTION: In the polycondensation reaction of water and an organo-Al compound of formula (X, Y and Z are H, alkyl or alkoxy), 1.0W3.5mol of water and 1.1W1.0mol of an organic acid (e.g. aliphatic monocarboxylic acid excluding formic acid, alicyclic carboxylic acid, aromatic mono- or dicarboxylic acid, hydroxycarboxylic acid, etc.) are used per 1mol of the organo-Al compound, and the organic acid is added to the reaction system in the reaction of the organo-Al compound with water.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过使用特定量的水和有机物进行有机铝化合物与水的缩聚反应，容易且高效地制备具有高分子量并适于形成纤维等的有机铝化合物酸，并在特定反应阶段将有机酸加入到反应体系中。构成：在水和式（X，Y和Z的有机铝化合物）为H，烷基或烷氧基的缩合反应中，1.0-3.5mol水和1.1-1.0mol有机酸（例如脂肪族单羧酸除了甲酸，脂环族羧酸，芳族单羧酸或二羧酸，羟基羧酸等）每1mol有机铝化合物使用，有机酸在有机铝的反应中加入到反应体系中与水混合。

7. 发明专利

JPS59179526A Preparation of organo-aluminum polymer having high molecular weight 失效
标题翻译：具有高分子量的有机铝聚合物的制备
公开(公告)号：JPS59179526A
公开(公告)日：1984-10-12
申请号：JP5626683
申请日：1983-03-30
申请人： Toshiaki Ichimura , Yoshiharu Kimura , Isoji Taniguchi
发明人： TANIGUCHI ISOJI , KIMURA YOSHIHARU , ICHIMURA TOSHIAKI
IPC分类号： C08G79/00 , C08G79/10 , D01F6/76
摘要： PURPOSE: To prepare an organo-aluminum polymer having high molecular weight and suitable for the forming of fiber, etc., easily and efficiently, by reacting an organo-aluminum compound with a specific amount of water in the presence of a specific amount of an organic acid.
CONSTITUTION: The objective polymer is prepared by reacting the organo- aluminum compound of formula [X and Y are H, alkyl or alkoxy); R is organic residue (e.g., CH
3 , cyclohexyl, vinyl, phenyl, etc.)] with water. The reaction is carried out in the presence of 0.2W10mol of an organic acid (e.g. lauric acid, hexanoic acid, butyric acid, valeric acid, etc.) using 1.0W3.5mol of water based on 1mol of the organo-aluminum compound, preferably at 0W60°C.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过使有机铝化合物与特定量的水反应，在特定量的水溶液存在下，通过使有机铝化合物与特定量的水反应来制备具有高分子量且适于形成纤维等的有机铝聚合物有机酸。构成：通过使式[X和Y的有机铝化合物是H，烷基或烷氧基）反应制备目标聚合物; R是有机残基（例如，CH3，环己基，乙烯基，苯基等）]与水。该反应在使用1.0-3.5摩尔水（基于1摩尔有机铝化合物）的0.2-10摩尔有机酸（例如月桂酸，己酸，丁酸，戊酸等）存在下进行，优选在0-60℃。

8. 发明专利

JP2006070102A Stereocomplex polylactic acid and manufacturing method of the same 有权
标题翻译：立体聚酯多糖及其制造方法
公开(公告)号：JP2006070102A
公开(公告)日：2006-03-16
申请号：JP2004252804
申请日：2004-08-31
申请人： Yoshiharu Kimura , Musashino Chemical Laboratory Ltd , Mutual:Kk , Teijin Ltd , 帝人株式会社 , 良晴木村 , 株式会社ミューチュアル , 株式会社武蔵野化学研究所
发明人： KIMURA YOSHIHARU , FUKUSHIMA KAZUKI , TAKADA MASAYUKI , TO SHIN , TOYOHARA KIYOTSUNA
IPC分类号： C08G63/06 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a stereocomplex polylactic acid having a high molecular weight, high crystallinity and a high melting point, and its manufacturing method.
SOLUTION: The stereocomplex polylactic acid is provided, which has the following characteristics: (1) it consists of a polylactic acid block copolymer constituted by L-lactic acid blocks and D-lactic acid blocks; (2) the average chain length of each block is 5-40; (3) the proportion of L-lactic acid units (L component) and D-lactic acid units (D component) is 20/80-80/20 (D component/L component, by weight ratio); (4) its weight average mol. wt. is 80,000-300,000; and (5) the content of the stereocomplex crystal is 80-100%.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有高分子量，高结晶度和高熔点的立体络合物聚乳酸及其制造方法。解决方案：提供立体络合物聚乳酸，其具有以下特征：（1）它由由L-乳酸嵌段和D-乳酸嵌段构成的聚乳酸嵌段共聚物组成; （2）每个块的平均链长为5-40; （3）L-乳酸单元（L成分）和D-乳酸单元（D成分）的比例为20/80〜80/20（D成分/ L成分，重量比）。（4）其重均分子量。重量。是80,000-300,000; 和（5）立构复合晶体的含量为80-100％。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2005187626A Manufacturing process of polylactic acid stereo complex body 审中-公开
标题翻译：多酸立体复合体的制备工艺
公开(公告)号：JP2005187626A
公开(公告)日：2005-07-14
申请号：JP2003430393
申请日：2003-12-25
申请人： Yoshiharu Kimura , Musashino Chemical Laboratory Ltd , Mutual:Kk , 良晴木村 , 株式会社ミューチュアル , 株式会社武蔵野化学研究所
发明人： KIMURA YOSHIHARU , FUKUSHIMA KAZUKI , MIURA SHIGENOBU , TAKADA MASAYUKI , SOGO KAZUAKI
IPC分类号： C08L101/16 , C08G63/08
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing process of a polylactic acid stereo complex body excellent in heat resistance and heat stability.
SOLUTION: The manufacturing process of the polylactic acid stereo complex body comprises a step in which a polylactic acid stereo block copolymer containing an L-lactic segment and a D-lactic segment, a poly-L-lactic acid and a poly-D-lactic acid and a step in which the mixture obtained forms the stereo complex. The polylactic acid stereo complex body is excellent in transparency, heat resistance and heat stability.
COPYRIGHT: (C)2005,JPO&NCIPI

10. 发明专利

JPS6147735A Preparation of organic boron nitride polymer 失效
标题翻译：有机硼酸盐聚合物的制备
公开(公告)号：JPS6147735A
公开(公告)日：1986-03-08
申请号：JP16845484
申请日：1984-08-11
申请人： Yoshiharu Kimura , Isoji Taniguchi , Kenji Yamamoto
发明人： TANIGUCHI ISOJI , KIMURA YOSHIHARU , YAMAMOTO KENJI
IPC分类号： C08G79/00 , C01B21/064 , C04B35/583 , C04B35/622 , C08G79/08 , C08K3/38
CPC分类号： C08G79/08 , C01B21/064 , C01P2002/82 , C04B35/583 , C04B35/62227 , C08K3/38 , C08L85/04
摘要： PURPOSE: To obtain an excellent polymer for molding, having low cross-linked polymer content, easily in high efficiency, by polymerizing an organic boron nitride in the presence of a specific amine compound.
CONSTITUTION: An organic boron nitride compound of formula (XBNR)
3 (R is H, saturated or unsaturated alkyl or aryl; X is primary W tertiary amino or silylamino) having a cyclic structure is polymerized in the presence of 0.3W30mol% amine compound of formula R
1 NH
2 or R
1 NHR
2 (R
1 and R
2 are alkyl, aryl or silyl) or their mixture.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过在特定的胺化合物的存在下使有机氮化硼聚合，得到极好的交联聚合物，易于高效率地成型。构成：具有环状结构的式（XBNR）3（R为H，饱和或不饱和的烷基或芳基; X为伯 - 叔氨基或甲硅烷基氨基）的有机氮化硼化合物在0.3-30mol％胺化合物存在下聚合式R 1 NH 2或R 1 NHR 2（R 1和R 2）是烷基，芳基或甲硅烷基）或它们的混合物。

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