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1. 发明授权

US4933406A Contact lens article made of silicon- and fluorine-containing resin 失效
标题翻译：由含硅和含氟树脂制成的隐形眼镜制品
公开(公告)号：US4933406A
公开(公告)日：1990-06-12
申请号：US403484
申请日：1989-09-06
申请人： Keizo Anan , Naoyuki Amaya , Yoshishige Murata , Takayuki Otsu , Hiroshi Kawashima , Satoshi Kubota , Masaru Egawa
发明人： Keizo Anan , Naoyuki Amaya , Yoshishige Murata , Takayuki Otsu , Hiroshi Kawashima , Satoshi Kubota , Masaru Egawa
IPC分类号： C08F230/08 , G02B1/04
CPC分类号： G02B1/043 , C08F230/08
摘要： A contact lens article comprises a resin obtained by copolymerizing starting monomer components containing a silicon-containing compound (A) represented by the formula ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group, X.sub.1 and X.sub.2 each represent a methyl group or ##STR2## l represents 0 or 1, m represents an integer of 1 to 3 and n and p each represent an integer of 0 to 3; a fluorine-containing compound (B) represented by the formula (II) of: ##STR3## wherein at least one of R.sub.2 and R.sub.3 represents a straight chain or branched chain fluoroalkyl group represented by --C.sub.h H.sub.k F.sub.2h+l-k in which h represents an integer of 2 to 18, k represents an integer of 1 to 2 multiplied by h and when one of R.sub.2 and R.sub.3 is --C.sub.h H.sub.k F.sub.2h+l-k, the other of R.sub.2 and R.sub.3 represents an alkyl group having 1 to 12 carbon atoms, an alkenyl group having 2 to 12 carbon atoms or a cycloalkyl group having 3 to 12 carbon atoms; and a radical polymerizable vinyl monomer.
摘要翻译：隐形眼镜制品包括通过共聚包含由式表示的含硅化合物（A）的起始单体成分得到的树脂，其中R 1表示氢原子或甲基，X 1和X 2各自表示甲基组或 l表示0或1，m表示1至3的整数，n和p各自表示0至3的整数; 由式（II）表示的含氟化合物（B）：其中R 2和R 3中的至少一个表示由-ChHkF 2h + lk表示的直链或支链氟烷基，其中h表示 2〜18，k表示1〜2的整数乘以h，当R2和R3之一为-ChHkF2h + lk时，R2和R3中的另一个为碳原子数1〜12的烷基，烯基为2 至12个碳原子或具有3至12个碳原子的环烷基; 和可自由基聚合的乙烯基单体。

2. 发明授权

US5209847A Ultrathin membrane of polymethacrylate or polycrotonate and device provided with ultrathin membrane 失效
标题翻译：聚甲基丙烯酸酯或聚氯乙烯的超薄膜和超声波膜提供的装置
公开(公告)号：US5209847A
公开(公告)日：1993-05-11
申请号：US590908
申请日：1990-10-01
申请人： Norihiro Kaiya , Naoyuki Amaya , Yoshishige Murata , Mikio Takagi , Kazuichi Tsuda , Kiyotaka Shigehara , Akira Yamada , Takayuki Otsu
发明人： Norihiro Kaiya , Naoyuki Amaya , Yoshishige Murata , Mikio Takagi , Kazuichi Tsuda , Kiyotaka Shigehara , Akira Yamada , Takayuki Otsu
IPC分类号： B05D1/20 , C09K19/56
CPC分类号： B05D1/202 , B82Y30/00 , B82Y40/00 , C09K19/56
摘要： An ultrathin polymeric membrane has a membrane thickness of 10 to 1,000 .ANG.. The membrane is constituted of polycarboxylate and obtained by the spin coating method or by the Langmuir-Blodgett method. The polycarboxylate contains recurrent units represented by the formula (I) ##STR1## wherein R.sub.1 and R.sub.2 represent different groups and each stands for a methyl group or a hydrogen atom, and R represents a hydrocarbon group selected from the group consisting of a branched alkyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a substituted alkyl group having 2 to 6 carbon atoms, a substituted cycloalkyl group having 3 to 10 carbon atoms and a siloxanic hydrocarbon group.

3. 发明授权

US4855374A Optical resin from diallyl esters 失效
标题翻译：来自二烯丙酯的光学树脂
公开(公告)号：US4855374A
公开(公告)日：1989-08-08
申请号：US211166
申请日：1988-06-22
申请人： Yoshishige Murata , Yasumi Koinuma , Naoyuki Amaya , Takayuki Otsu , Masafumi Nisimura
发明人： Yoshishige Murata , Yasumi Koinuma , Naoyuki Amaya , Takayuki Otsu , Masafumi Nisimura
IPC分类号： C08F22/10 , G02B1/04
CPC分类号： C08F22/10 , G02B1/04
摘要： According to the invention, there are provided an optical resin and a process for preparing such a resin. The optical resin is obtained by polymerizing a feed monomer comprising at least a diester of dicarboxylic acid represented by the general formula (1) of: ##STR1## wherein R.sub.1 and R.sub.2 each represent the same or different groups and stand for an alkyl or alkenyl group having 1 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms or an ester residue having at least one aromatic ring.
摘要翻译：根据本发明，提供了一种光学树脂及其制备方法。光学树脂通过聚合至少包含由以下通式（1）表示的二羧酸的二酯的进料单体获得：其中R 1和R 2各自表示相同或不同的基团，并且代表烷基或具有1至12个碳原子的烯基，具有3至12个碳原子的环烷基或具有至少一个芳族环的酯残基。

4. 发明授权

US4670520A Method for modifying polyfumaric acid diester 失效
标题翻译：聚富马酸二酯改性方法
公开(公告)号：US4670520A
公开(公告)日：1987-06-02
申请号：US823225
申请日：1986-01-28
申请人： Takayuki Otsu , Yoshishige Murata , Naoyuki Amaya
发明人： Takayuki Otsu , Yoshishige Murata , Naoyuki Amaya
IPC分类号： C07C67/47 , C07C67/475 , C07C69/33 , C07C69/52 , C08F8/00 , C08F8/12 , C08F22/00 , C08F22/10 , C08F122/00 , C08F122/12
CPC分类号： C08F8/00 , C08F8/12
摘要： According to the invention, a method for modifying a polyfumaric acid diester is provided. The method comprises subjecting the polyfumaric acid diester to thermal treatment to thereby obtain a polyfumarate having carboxyl groups. The polyfumaric acid diester is obtained by polymerizing a fumaric acid diester represented by the following general formula of: ##STR1## wherein R represents an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms or an organic residue having at least one aromatic ring.
摘要翻译：根据本发明，提供了一种改性聚富马酸二酯的方法。该方法包括使聚富马酸二酯进行热处理，从而得到具有羧基的聚富马酸盐。聚富马酸二酯是通过聚合由以下通式表示的富马酸二酯得到的：其中R表示碳原子数1〜12的烷基，碳原子数3〜12的环烷基或具有碳原子数3〜12的有机残基，至少一个芳香环。

5. 发明授权

US5314962A ABA type block copolymers 失效
标题翻译： ABA型嵌段共聚物
公开(公告)号：US5314962A
公开(公告)日：1994-05-24
申请号：US83326
申请日：1993-06-29
申请人： Takayuki Otsu , Shunichi Himori , Takashi Kiriyama
发明人： Takayuki Otsu , Shunichi Himori , Takashi Kiriyama
IPC分类号： C08F2/48 , C08F293/00 , C08F297/00
CPC分类号： C08F293/00
摘要： An acrylate is polymerized by the photo-decomposition of ##STR1## to make a polymeric intermediate containing dithiocarbamate groups at both its ends, and a hard polymer-forming monomer is polymerized by the photo-decomposition of this dithiocarbamate group-containing polymeric intermediate to form blocks of a polymer of said hard polymer-forming monomer on both sides of said polymeric intermediate, thereby forming an ABA type block copolymer.
摘要翻译：通过的光分解使丙烯酸酯聚合以制备在其两端含有二硫代氨基甲酸酯基团的聚合物中间体，并且形成硬聚合物的单体通过该含二硫代氨基甲酸酯基团的聚合物中间体的光分解聚合以形成在所述聚合物中间体的两侧上形成所述硬聚合物形成单体的聚合物嵌段，由此形成ABA型嵌段共聚物。

6. 发明授权

US4477599A Method of preparing a low density, nonflammable polyvinyl foam composition 失效
标题翻译：制备低密度，不可燃聚乙烯泡沫组合物的方法
公开(公告)号：US4477599A
公开(公告)日：1984-10-16
申请号：US439981
申请日：1982-11-08
申请人： Takayuki Otsu , Hirosuke Kojima
发明人： Takayuki Otsu , Hirosuke Kojima
IPC分类号： C04B38/02 , C08J9/00 , C08J9/02 , C08L27/04
CPC分类号： C08J9/0066 , C08J9/0028 , C08J9/0033 , C08K3/00 , C08K5/23 , C08K5/39 , C08K5/40 , C08K5/47 , C08J2357/08
摘要： A method of preparing a foamable polyvinyl system resin composition which renders a non-flammable, high strength to weight ratio foam product comprises, reacting at least 0.05 parts by weight of an organic radical initiator per 1 part by weight of polyvinyl system resin with the components consisting essentially of (a) at least one polyvinyl system resin (b) 2-100 parts by weight of at least one inorganic filler per 1 part by weight of polyvinyl system resin (c) an effective amount of at least one blowing agent.
摘要翻译：一种制备可发泡聚乙烯系树脂组合物的方法，其使得不燃的高强度重量比的泡沫产品包括：使每1重量份聚乙烯基系树脂与至少0.05重量份的有机自由基引发剂与组分基本上由（a）至少一种聚乙烯基系树脂（b）每1重量份聚乙烯基系树脂（c）2-100重量份的至少一种无机填料，有效量的至少一种发泡剂。

7. 发明授权

US5104428A Separation membrane 失效
标题翻译：分离膜
公开(公告)号：US5104428A
公开(公告)日：1992-04-14
申请号：US722471
申请日：1991-07-02
申请人： Toru Doi , Tomohiro Ishikawa , Takayuki Otsu , Akikazu Matsumoto
发明人： Toru Doi , Tomohiro Ishikawa , Takayuki Otsu , Akikazu Matsumoto
IPC分类号： B01D71/32 , B01D71/40 , B01D71/62 , B01D71/70
CPC分类号： B01D71/40
摘要： A separation membrane comprising a resin being constituted of the repeating unit represented by the general formula (I) and having a number average molecular weight of not less than 1.times.10.sup.3 in polystyrene equivalent: ##STR1## wherein R.sub.1 denotes an alkyl group of 1-20 carbons, a fluoroalkyl group of 1-20 carbons, or a group represented by the general formula: --(--X--).sub.m --(SiR.sub.2 R.sub.3 --).sub.n --R.sub.4, or --(--X--).sub.m --(--SiR.sub.2 R.sub.3 O--).sub.n --SiR.sub.4 R.sub.5 R.sub.6 (wherein X is an alkylene group of 1-8 carbons or a phenylene group of 6-12 carbons; m is 0 or 1; n is an integer of 1-20; R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are respectively a group, having 1-8 carbons, selected from an alkyl group, a cycloalkyl group, a phenyl group, an alkoxyl group, and a fluoroalkyl group, and may be the same with or different from each other).

8. 发明授权

US5102957A Novel block copolymer of styrene and ethylene 失效
标题翻译：苯乙烯和乙烯的新型嵌段共聚物
公开(公告)号：US5102957A
公开(公告)日：1992-04-07
申请号：US511467
申请日：1990-04-20
申请人： Kiyoshi Endo , Takayuki Otsu
发明人： Kiyoshi Endo , Takayuki Otsu
IPC分类号： C08F297/02
CPC分类号： C08F297/02
摘要： A novel method is proposed for the preparation of a block copolymer of styrene and ethylene having a very narrow molecular weight distribution and controlled molar ratio of the styrene moiety to ethylene moiety in a high efficiency. The method comprises the steps of: (a) living-polymerizing styrene by using an organic lithium compound as a polymerization initiator; (b) admixing the polymerization mixture containing the living polymer of styrene with a tertiary diamine compound, such as N,N,N',N'-tetramethyl ethylene diamine; and (c) introducing ethylene monomer into the polymerization mixture to effect polymerization of ethylene on to the living polymer molecules of polystyrene.
摘要翻译：提出了一种制备苯乙烯和乙烯的嵌段共聚物的新方法，该嵌段共聚物具有非常窄的分子量分布和高度效率的苯乙烯部分与乙烯部分的受控摩尔比。该方法包括以下步骤：（a）通过使用有机锂化合物作为聚合引发剂使苯乙烯活性聚合; （b）将包含苯乙烯的活性聚合物的聚合混合物与N，N，N'，N'-四甲基乙二胺等叔胺化合物混合; 和（c）将乙烯单体引入到聚合混合物中以使乙烯聚合到聚苯乙烯的活性聚合物分子上。

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