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    • 4. 发明授权
    • Color photographic material comprising silver halide light-sensitive and
non light-sensitive layers
    • 彩色照相材料包含卤化银感光和非感光层
    • US4526863A
    • 1985-07-02
    • US592042
    • 1984-03-21
    • Keiji MihayashiShunji TakadaHidetoshi Kobayashi
    • Keiji MihayashiShunji TakadaHidetoshi Kobayashi
    • G03C1/06G03C1/46G03C1/95G03C7/305G03C1/76G03C7/00
    • G03C7/305G03C1/46G03C1/95Y10S430/156
    • A silver halide photographic light-sensitive material comprising a support having thereon at least two light-sensitive silver halide emulsion layers which are sensitive to light of substantially the same spectral region and a relatively light-insensitive layer containing silver halide, zinc oxide or titanium oxide positioned between the two light-sensitive silver halide emulsion layers and at least one of the two light-sensitive silver halide emulsion layers containing a compound represented by the following general formula (I):A--B (I)wherein A represents a residue of a compound capable of coupling with the oxidation product of an aromatic primary amine developing agent by removal of a hydrogen atom from the active position of the compound, and B represents a group which is released on coupling and exhibits a fogging function in a developing solution. The silver halide photographic light-sensitive material containing the compound represented by the general formula (I) has improved granularity as well as has high sensitivity.
    • 一种卤化银照相感光材料,其包括其上具有至少两个对基本上相同光谱区域的光敏感的感光卤化银乳剂层的支持体和含有卤化银,氧化锌或氧化钛的相对不透光层 位于两个感光卤化银乳剂层之间和两个感光卤化银乳剂层中的至少一个含有由以下通式(I)表示的化合物:AB(I)其中A表示化合物的残基 能够通过从化合物的活性位置除去氢原子而与芳族伯胺显影剂的氧化产物偶联,B表示在偶联时释放并在显影液中显示起雾功能的基团。 含有由通式(I)表示的化合物的卤化银摄影感光材料具有改善的粒度以及具有高灵敏度。
    • 8. 发明授权
    • Color photographic light-sensitive material and method of developing the
same
    • 彩色摄影感光材料及其开发方法
    • US4960689A
    • 1990-10-02
    • US201406
    • 1988-06-02
    • Toshihiro NishikawaShunji TakadaKazunori Hasebe
    • Toshihiro NishikawaShunji TakadaKazunori Hasebe
    • G03C7/26G03C1/035G03C1/06G03C7/30G03C7/392
    • G03C7/39236
    • A silver halide color photographic light-sensitive material includes a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer contains a silver halide emulsion which comprises silver halide grains consisting of at least 50 mol % of silver chloride and contains at least one of the compounds represented by formulas [I] to [III]: ##STR1## wherein Z represents alkyl (the number of carbon atoms is 1 to 18), aryl (the number of carbon atom is 6 to 18), or heterocyclic,Y represents an atom group required for forming heterocyclic or aryl (the number of carbon atoms of the aryl is 6 to 18),M represents metal cation, organic cation, or hydrogen atom, andn represents an integer from 2 to 10.A silver halide color photographic light-sensitve material includes a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer contains a silver halide emulsion which comprises silver grains consisting of at least 50 mol % of a chloride and chemically sensitized in the presence of at least one of the compounds represented by formulas [I] to [III].A method of developing a silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, characterized in that said emulsion layer contains a silver halide emulsion which comprises silver halide grains consisting of at least 50 mol % of silver chloride and contains at least one of the compounds represented by formulas [I] to [III], and that the method comprises the steps of: color-developing the silver halide color photographic light-sensitive material in the presence of a color coupler; and desilverizing the silver halide color photographic light-sensitive material.
    • 10. 发明授权
    • Highly-sensitive high-contrast photographic materials
    • 高度敏感的高对比度感光材料
    • US4241164A
    • 1980-12-23
    • US949480
    • 1978-10-10
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraNobuo Sakai
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraNobuo Sakai
    • C07C67/00C07C241/00C07C243/28C07C243/38C07C253/00C07C255/57G03C1/06G03C1/08G03C1/10G03C1/28G03C5/30
    • C07C243/00C07C243/38G03C1/061G03C1/28Y10S430/15
    • A silver halide photographic material providing very high contrast and negative image photographic characteristics comprising a support having thereon at least one silver halide photographic emulsion layer containing substantially surface latent image type mono-dispersed silver halide grains and providing a negative image, at least one hydrophilic colloid layer of the photographic material containing a compound represented by the general formula (I)R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group having 1 to 3 carbon atoms; and a compound represented by the general formula (II) or (III) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, an alkyl group which may be substituted, an aryl group which may be substituted, an amino group which may be substituted, a hydroxyl group, an alkoxy group, an alkylthio group, a carbamoyl group which may be substituted, a halogen atom, a cyano group, a carboxyl group, an alkoxycarbonyl group, or a heterocyclic group; wherein R.sup.3 and R.sup.4 or R.sup.4 and R.sup.5 may combine and form a 5-membered or 6-membered ring and at least one of R.sup.3 and R.sup.5 represents a hydroxyl group.
    • 提供非常高的对比度和负影像照相特征的卤化银照相材料,包括其上具有至少一个含有基本上表面潜影型单分散卤化银颗粒并提供负像的卤化银照相乳剂层的载体,至少一种亲水胶体 含有通式(I)R1NHNHCOR2(I)表示的化合物的照相材料层,其中R1表示芳基,R2表示氢原子,苯基或未取代的碳原子数1〜3的烷基; 和由通式(II)或(III)表示的化合物,其中可以相同或不同的R 3,R 4,R 5和R 6各自表示氢原子, 可以被取代的烷基,可以被取代的芳基,可以被取代的氨基,羟基,烷氧基,烷硫基,可被取代的氨基甲酰基,卤素原子,氰基 基团,羧基,烷氧基羰基或杂环基; 其中R3和R4或R4和R5可以组合并形成5元或6元环,并且R 3和R 5中的至少一个表示羟基。