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    • 9. 发明申请
    • METHOD FOR PRODUCING MTW-TYPE ZEOLITE
    • 生产MTW型沸石的方法
    • US20130343986A1
    • 2013-12-26
    • US13980765
    • 2012-01-17
    • Keiji ItabashiYoshihiro KamimuraTatsuya Okubo
    • Keiji ItabashiYoshihiro KamimuraTatsuya Okubo
    • C01B39/46
    • C01B39/46C01B39/42
    • Provided is a method for producing an MTW-type zeolite. The reaction mixture contains a silica source, an alumina source, an alkali source, and water is reacted with a seed crystal of a zeolite to produce an MTW-type zeolite. The reaction mixture has a composition, which makes a synthesized zeolite contain an MFI-type zeolite when the zeolite is synthesized solely from the reaction mixture, is used. As the seed crystal, a beta-type zeolite which has a ratio of SiO2/Al2O3 of 8 to 50 and does not contain a structure direction agent is used. The seed crystal is added to the reaction mixture, in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture. The reaction mixture to which the seed crystal has been added is heated at 100° C. to 200° C. in a sealed state.
    • 提供了一种MTW型沸石的制造方法。 反应混合物含有二氧化硅源,氧化铝源,碱源,水与沸石晶种反应生成MTW型沸石。 反应混合物具有组合物,当使用沸石仅由反应混合物合成时,其使合成的沸石含有MFI型沸石。 作为晶种,使用SiO 2 / Al 2 O 3的比例为8〜50,不含结构方向试剂的β型沸石。 相对于反应混合物中的二氧化硅成分,将该晶种以0.1质量%〜20质量%的比例添加到反应混合物中。 已加入晶种的反应混合物在密封状态下在100℃加热至200℃。
    • 10. 发明授权
    • Method for producing MTW-type zeolite
    • 生产MTW型沸石的方法
    • US08834836B2
    • 2014-09-16
    • US13980765
    • 2012-01-17
    • Keiji ItabashiYoshihiro KamimuraTatsuya Okubo
    • Keiji ItabashiYoshihiro KamimuraTatsuya Okubo
    • C01B33/36C01B39/00C01B39/42C01B39/46
    • C01B39/46C01B39/42
    • Provided is a method for producing an MTW-type zeolite. The reaction mixture contains a silica source, an alumina source, an alkali source, and water is reacted with a seed crystal of a zeolite to produce an MTW-type zeolite. The reaction mixture has a composition, which makes a synthesized zeolite contain an MFI-type zeolite when the zeolite is synthesized solely from the reaction mixture, is used. As the seed crystal, a beta-type zeolite which has a ratio of SiO2/Al2O3 of 8 to 50 and does not contain a structure direction agent is used. The seed crystal is added to the reaction mixture, in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture. The reaction mixture to which the seed crystal has been added is heated at 100° C. to 200° C. in a sealed state.
    • 提供了一种MTW型沸石的制造方法。 反应混合物含有二氧化硅源,氧化铝源,碱源,水与沸石晶种反应生成MTW型沸石。 反应混合物具有组合物,当使用仅由反应混合物合成沸石时,使合成的沸石含有MFI型沸石。 作为晶种,使用SiO 2 / Al 2 O 3的比例为8〜50,不含结构方向试剂的β型沸石。 相对于反应混合物中的二氧化硅成分,将该晶种以0.1质量%〜20质量%的比例添加到反应混合物中。 已加入晶种的反应混合物在密封状态下在100℃加热至200℃。