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    • 8. 发明申请
    • PROCESS FOR CONVERSION OF LOW COST AND HIGH FFA OILS TO BIODIESEL
    • 将低成本和高FFA油转化生物柴油的方法
    • US20120255223A1
    • 2012-10-11
    • US13395871
    • 2010-03-19
    • Savita KaulNeeraj AtrayAjay Bhatnagar
    • Savita KaulNeeraj AtrayAjay Bhatnagar
    • C10L1/188
    • C11C3/003C10L1/026Y02E50/13
    • The present invention describes a process for converting high free fatty acid containing feed stocks (FFA 20-85%) like palm fatty acid distillate (PFAD), restaurant grease, waste cooking oil, Soya deodistillate, acid oil, jatropha curcas oil, mohua oil etc. to biodiesel, which involves esterification of FFA containing oil with lower alcohols like methanol, ethanol, propanol etc. in presence of macro reticular and gel type acidic heterogenous resin as catalyst to bring down acid value in the range of 1-2 mgKOH/g followed by transesterification in presence of homogeneous basic catalyst metal oxides, hydroxides and alkoxides like sodium hydroxide, potassium hydroxide, sodium methoxide, potassium methoxide etc. and separation of biodiesel and glycerine.
    • 本发明描述了一种将棕榈脂肪酸馏出物(PFAD),食用油脂,废食用油,大豆脱脂酸,酸性油,麻风树油,摩卡油(FFA 20-85%)的高游离脂肪酸 等等生物柴油,其中包括含有FFA的油与低级醇如甲醇,乙醇,丙醇等在大网状和凝胶型酸性异种树脂作为催化剂的存在下降解酸值在1-2mgKOH / 然后在均相碱性催化剂金属氧化物,氢氧化物和醇盐如氢氧化钠,氢氧化钾,甲醇钠,甲醇钾等存在下进行酯交换反应,并分离生物柴油和甘油。