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1. 发明申请

US20050005645A1 Method for producing flat glass, glass cullet to be used in the method 审中-公开
标题翻译：方法生产平板玻璃，玻璃碎片用于该方法
公开(公告)号：US20050005645A1
公开(公告)日：2005-01-13
申请号：US10496704
申请日：2002-11-29
申请人： Kazuyuki Inoguchi , Toshifumi Tsujino , Hiromitsu Seto , Akihiro Koyama , Kazutaka Kamitani
发明人： Kazuyuki Inoguchi , Toshifumi Tsujino , Hiromitsu Seto , Akihiro Koyama , Kazutaka Kamitani
IPC分类号： B32B17/10 , C03B18/12 , C03C1/02 , C03C1/10 , C03C17/00 , C03B5/16
CPC分类号： C03C1/024 , B32B17/10036 , B32B17/10339 , B32B17/10761 , C03B18/12 , C03C1/02 , C03C1/10 , C03C17/007 , C03C2217/45 , C03C2217/475
摘要： The present invention provides a method for manufacturing a glass sheet in which a raw material containing glass cullets is melted to form the glass sheet, wherein the glass cullets include a colored film and this colored film contains an alkali metal oxide, a silicon oxide, and fine particles containing carbon as their main component. The glass cullets can be recycled as a part of the raw material for glass in spite of the colored film included therein since in the glass cullets, the fine particles containing carbon as their main component are contained as a colorant.
摘要翻译：本发明提供一种玻璃板的制造方法，其中含有玻璃碎片的原料熔化形成玻璃板，其中玻璃碎片包括着色膜，该着色膜含有碱金属氧化物，氧化硅和以碳为主要成分的微粒子。作为玻璃原料的一部分，玻璃碎片可以回收，尽管其中包含着色膜，由于在玻璃碎片中含有以碳为主要成分的微粒作为着色剂。

2. 发明申请

US20050003209A1 Glass substrate with colored film fine-particle-containing solution for forming colored film and method for producing glass substrate with colored film 审中-公开
标题翻译：具有用于形成着色膜的带有彩色膜微粒的溶液的玻璃基板和用彩色膜制造玻璃基板的方法
公开(公告)号：US20050003209A1
公开(公告)日：2005-01-06
申请号：US10496701
申请日：2002-11-29
申请人： Kazuyuki Inoguchi , Kazutaka Kamitani , Toshifumi Tsujino
发明人： Kazuyuki Inoguchi , Kazutaka Kamitani , Toshifumi Tsujino
IPC分类号： B32B17/10 , C03B18/12 , C03C1/02 , C03C1/10 , C03C17/00 , B32B17/06
CPC分类号： C03B18/12 , B32B17/10036 , B32B17/10339 , B32B17/10761 , C03C1/02 , C03C1/024 , C03C1/10 , C03C17/002 , C03C17/007 , C03C2217/452 , C03C2217/475 , Y10T428/25 , Y10T428/265 , Y10T428/31616
摘要： The present invention provides a glass sheet with a colored film that can be recycled as a cutlet raw material. The glass sheet includes a glass substrate and a colored film that coats at least part of the surface thereof. This colored film includes an alkali metal oxide, a silicon oxide, and fine particles containing carbon as their main component. The colored film functions as light-shielding films that reduce the visible light transmittance and ultraviolet transmittance.
摘要翻译：本发明提供一种具有可作为切片原料再循环的着色膜的玻璃板。玻璃板包括玻璃基板和涂覆其表面的至少一部分的着色膜。该着色膜包括碱金属氧化物，氧化硅和以碳为主要成分的微粒。着色膜用作减少可见光透射率和紫外线透射率的遮光膜。

3. 发明申请

US20060154048A1 Article having functional coating film thereon, method for manufacture thereof, and applying material for forming functional coating film 审中-公开
标题翻译：具有功能性涂膜的制品，其制造方法和施加用于形成功能性涂膜的材料
公开(公告)号：US20060154048A1
公开(公告)日：2006-07-13
申请号：US10538765
申请日：2003-12-10
申请人： Toyoyuki Teranishi , Toshifumi Tsujino , Kazutaka Kamitani
发明人： Toyoyuki Teranishi , Toshifumi Tsujino , Kazutaka Kamitani
IPC分类号： C09D5/20 , C09D4/00 , C04B41/50 , B32B5/16
CPC分类号： C09D5/28 , C08K3/36 , C09D1/00 , C09D7/61 , C09D7/67 , Y10T428/25 , Y10T428/26
摘要： An article coated with a functional coating film which has a base material, a primer layer coating the surface of the base material and having fine roughness and a functional layer coating the primer layer. The primer layer having fine roughness has portions formed by unevenly accumulating fine particles. The primer layer in the article contains silicon oxide as the main component, and the excellent transparency and the fine roughness are simultaneously exhibited.
摘要翻译：涂覆有功能性涂膜的制品，其具有基材，涂覆基材表面并具有细小粗糙度的底漆层和涂覆底漆层的功能层。具有细小粗糙度的底漆层具有通过不均匀地积聚微粒形成的部分。制品中的底漆层含有氧化硅作为主要成分，同时表现出优异的透明性和细小的粗糙度。

4. 发明授权

US06964815B2 Projecting film and manufacturing method thereof 失效
标题翻译：投影胶片及其制造方法
公开(公告)号：US06964815B2
公开(公告)日：2005-11-15
申请号：US10257735
申请日：2002-02-15
申请人： Tetsuya Yoshitake , Toshifumi Tsujino , Kazutaka Kamitani
发明人： Tetsuya Yoshitake , Toshifumi Tsujino , Kazutaka Kamitani
IPC分类号： C03C17/00 , C03C17/25 , C03C17/34 , G02F1/1335 , B32B9/04 , B32B15/00 , B05D5/02 , B05D3/02
CPC分类号： G02B1/10 , C03C17/009 , C03C17/25 , C03C17/3411 , C03C2217/77 , C03C2218/113 , G02F1/133502 , G02F1/133553 , Y10T428/24355 , Y10T428/24628 , Y10T428/26
摘要： A sol-form application liquid 3 is prepared by mixing together two solvents A and B and two film components C and D. The sol-form application liquid 3 thus prepared is applied onto a glass substrate 200, thus forming a mixed layer 401 on the glass substrate 200. The glass substrate 200 having the mixed layer 401 formed thereon is left at room temperature, whereupon the solvent A evaporates and phase separation of the mixed layer 401 into an upper layer 403 and a lower layer 402 occurs. The mixed layer 401 is then heated, thus evaporating the solvent B in the lower layer 402 and gelating the film component C in the upper layer 403 and the film component D in the lower layer 402, and hence forming an internal scattering layer 404.
摘要翻译：通过将两种溶剂A和B以及两种膜组分C和D混合在一起来制备溶胶形式的涂布液3.将如此制备的溶胶形式的涂布液3施加到玻璃基板200上，从而在在其上形成有混合层401的玻璃基板200在室温下放置，溶剂A蒸发，混合层401相分离成上层403和下层402。然后将混合层401加热，从而蒸发下层402中的溶剂B，并使上层402中的膜组分C和下层402中的膜组分D凝胶化，从而形成内部散射层404。

5. 发明申请

US20050003210A1 Substrate with film 审中-公开
标题翻译：基片与电影
公开(公告)号：US20050003210A1
公开(公告)日：2005-01-06
申请号：US10841680
申请日：2004-05-06
申请人： Kazuyuki Inoguchi , Mizuho Matsuda , Toshifumi Tsujino , Mamoru Yoshida
发明人： Kazuyuki Inoguchi , Mizuho Matsuda , Toshifumi Tsujino , Mamoru Yoshida
IPC分类号： C03C17/23 , C03C17/00 , B32B17/06
CPC分类号： C03C17/007 , C03C2217/45 , C03C2217/475 , C03C2217/476 , Y10T428/257
摘要： The invention provides a substrate with a film, in which functional particles are dispersed, and whose transparency is maintained even when heated. The film includes a matrix including an alkali metal oxide and a silicon oxide, and functional particles dispersed in the matrix is formed on a substrate. The alkali metal oxide includes at least sodium, and lithium and/or potassium. A mole ratio R2O/SiO2 of the alkali metal oxide to the silicon oxide included in the film is in a range of 17/100 to 22/100. The haze ratio of this substrate with a film stays low even when heated.
摘要翻译：本发明提供一种具有膜的基材，其中功能性颗粒被分散，并且即使在加热时其透明性也被保持。该膜包括包含碱金属氧化物和氧化硅的基质，分散在基质中的功能性粒子形成在基材上。碱金属氧化物至少包括钠和锂和/或钾。包括在膜中的碱金属氧化物与氧化硅的摩尔比R2O / SiO 2在17/100至22/100的范围内。即使加热，该基板与膜的雾度比也保持较低。

6. 发明授权

US06921578B2 Low-reflection glass article 有权
标题翻译：低反射玻璃制品
公开(公告)号：US06921578B2
公开(公告)日：2005-07-26
申请号：US09928836
申请日：2001-08-11
申请人： Toshifumi Tsujino , Hideki Okamoto , Tetsuro Kawahara
发明人： Toshifumi Tsujino , Hideki Okamoto , Tetsuro Kawahara
IPC分类号： G02B1/11 , C03C1/00 , C03C17/00 , C03C17/25 , C03C17/42 , C03C19/00 , F24J2/50 , G01Q30/14 , G01Q60/00 , G02B1/111 , G02B1/12 , H01L31/0216 , H01L31/04 , B32B9/00
CPC分类号： H01L31/02168 , C03C1/008 , C03C17/007 , C03C17/42 , C03C19/00 , C03C2217/213 , C03C2217/42 , C03C2217/478 , C03C2218/113 , C03C2218/116 , F24S80/52 , G02B1/11 , G02B1/12 , Y02E10/40 , Y02E10/50 , Y10T428/25 , Y10T428/26 , Y10T428/2993
摘要： A low reflection film comprising silica fine particles and a binder in a weight ratio proportion of 60:40 to 95:5 is obtained by mixing starting fine particles comprising at least non-aggregated silica fine particles with a mean particle size of 40-1000 nm and/or linear (chain-like) aggregated silica fine particles with a mean primary particle size of 10-100 nm, a hydrolyzable metal compound, water, and a solvent, hydrolyzing the hydrolyzable metal compound in the presence of the starting fine particles, and then coating the prepared coating solution onto a glass base substrate and subjecting it to heat treatment.The obtained low reflection film is a single-layer low reflection film with low reflectivity, excellent abrasion resistance, high film strength and excellent contamination removal property, and coating of the low reflection film onto glass base substrates can give low reflection glass articles.
摘要翻译：通过混合至少包含平均粒度为40-1000nm的非聚集的二氧化硅细颗粒的起始细颗粒，得到重量比为60:40至95:5的二氧化硅微粒和粘合剂的低反射膜和/或平均一次粒径为10-100nm的线性（链状）聚集的二氧化硅细颗粒，水解性金属化合物，水和溶剂，在起始微粒存在下水解可水解的金属化合物，然后将制备的涂布溶液涂布在玻璃基材上并对其进行热处理。获得的低反射膜是具有低反射率，优异的耐磨性，高膜强度和优异的污染除去性能的单层低反射膜，并且低反射膜在玻璃基底上的涂布可以产生低反射玻璃制品。

7. 发明申请

US20050019528A1 Method of forming projecting film 审中-公开
标题翻译：形成投影膜的方法
公开(公告)号：US20050019528A1
公开(公告)日：2005-01-27
申请号：US10868261
申请日：2004-06-14
申请人： Tetsuya Yoshitake , Toshifumi Tsujino
发明人： Tetsuya Yoshitake , Toshifumi Tsujino
IPC分类号： C03C17/25 , C03C17/34 , C03C17/36 , G02B5/02 , G02B5/08 , G02B5/09 , G02F1/1335 , G02F1/13357 , B32B1/00 , D06N7/04
CPC分类号： G02B1/10 , C03C17/25 , C03C17/3417 , C03C17/36 , C03C2217/212 , C03C2217/213 , C03C2217/734 , C03C2218/113 , G02B5/0221 , G02B5/0268 , G02B5/0284 , Y10T428/24355
摘要： By establishing a projecting part control method that enables the same application liquid to be used for a plurality of different scattering property requirements, there is provided a method of forming a projecting film according to which an increase in the number of times of preparing an application liquid and the frequency of replacing the application liquid can be suppressed, and hence the uptime ratio of coating equipment can be prevented from dropping, and thus the manufacturing cost can be reduced. The method of forming a projecting film comprises a formation step of applying a sol-form application liquid comprising at least one film component and at least two solvents onto a glass substrate 20 to form an applied layer 41, a phase separation step of drying the applied layer 41 to selectively remove at least one of the solvents that acted effectively to homogenize the applied layer 41, thus carrying out phase separation between at least one of the solvents that acts effectively to cause phase separation and at least one of the film components, or between a plurality of the film components, by utilizing a difference in surface tension between at least one of the solvents that acts effectively to cause phase separation and at least one of the film components, or between a plurality of the film components, and a gelation step of removing the solvents to gelate the film components. The drying temperature in the drying of the applied layer 41 is controlled within a range of 200 to 500° C., and the drying time is controlled within a range of 1 minute to 24 hours.
摘要翻译：通过建立使得相同的涂布液能够用于多种不同散射特性要求的突出部分控制方法，提供了一种形成突起膜的方法，根据该方法，制备涂布液的次数增加能够抑制更换涂布液的频率，能够防止涂布装置的正常运转时间的下降，能够降低制造成本。形成突出膜的方法包括：将包含至少一种膜成分和至少两种溶剂的溶胶型涂布液施加到玻璃基板20上以形成涂布层41的形成步骤，层41以选择性地除去至少一种有效地作用以使施加的层41均匀化的溶剂，从而在有效地引起相分离的至少一种溶剂之间进行相分离，并且至少一种膜组分，或在多个膜组分之间，通过利用有效地引起相分离的至少一种溶剂与至少一种膜组分之间或多个膜组分之间的表面张力差和凝胶化去除溶剂以使膜组分胶凝的步骤。施加层41的干燥中的干燥温度控制在200〜500℃的范围内，干燥时间控制在1分钟〜24小时的范围内。

8. 发明授权

US06607832B1 Ultraviolet/infrared absorbent glass, an ultraviolet/infrared absorbent glass plate, a colored film-coated ultraviolet/infrared absorbent glass plate and a window glass of a vehicle 失效
标题翻译：紫外/红外线吸收玻璃，紫外/红外线吸收玻璃板，彩色薄膜包衣紫外/红外吸收玻璃板和车窗玻璃
公开(公告)号：US06607832B1
公开(公告)日：2003-08-19
申请号：US09363043
申请日：1999-07-29
申请人： Yukihito Nagashima , Isamu Kuroda , Mitsuhiro Kawazu , Toshifumi Tsujino
发明人： Yukihito Nagashima , Isamu Kuroda , Mitsuhiro Kawazu , Toshifumi Tsujino
IPC分类号： B32B1706
CPC分类号： B32B17/10761 , B32B17/10339 , C03C3/095 , C03C4/02 , C03C4/082 , C03C4/085 , C03C8/18 , C03C17/007 , C03C17/008 , C03C2217/45 , C03C2217/479 , Y10T428/24909 , Y10T428/24917
摘要： An ultraviolet/infrared absorbent glass plate includes base glass including 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % a total amount of MgO and CaO; 10 to 20 wt. % a total amount of Na2O and K2O; 0.05 to 0.3 wt. % SO3; 0 to 5 wt. % B2O3; 0 to 1 wt. % SnO2; and 0 to 350 ppm MnO; and colorants including 0.2 to 0.45 wt. % total iron oxide (T—Fe2O3) expressed as Fe2O3; 0.01 to 0.03 wt. % (excluding 0.03 wt. %) FeO; 0.8 to 2 wt. % CeO2; 0 to 0.003 wt. % CoO; and 0 to 1.5 wt. % TiO2. FeO expressed as Fe2O3 is 5 to 10 wt. % (excluding 10 wt. %) of T—Fe2O3, and the glass at any thickness in a range of 3.25 mm to 6.25 mm has visible light transmittance of equal to or more than 80% when measured by using CIE illuminant A.
摘要翻译：紫外线/红外线吸收剂玻璃板包括含有65〜80重量％％SiO2; 0至5wt。％Al2O3; 0〜10重量％％MgO; 5至15wt。％CaO; 10至18wt。％Na2O; 0至5wt。％K2O; 5至15wt。 MgO和CaO的总量％; 10〜20重量％ Na2O和K2O的总量％ 0.05〜0.3重量％％SO3; 0至5wt。％B2O3; 0〜1重量％％SnO2; 和0至350ppm MnO; 和着色剂，包括0.2至0.45wt。以Fe2O3表示的总氧化铁（T-Fe2O3）％; 0.01〜0.03重量％％（不含0.03重量％）FeO; 0.8〜2重量％％CeO2; 0〜0.003重量％％CoO; 和0至1.5wt。％TiO2。以Fe2O3表示的FeO为5〜10重量％。％（不包括10重量％）的T-Fe 2 O 3，并且在3.25mm至6.25mm的范围内的任何厚度的玻璃在通过使用CIE光源A测量时具有等于或大于80％的可见光透射率。

9. 发明申请

US20060121190A1 Low-reflection glass article and method for manufacturing 审中-公开
标题翻译：低反射玻璃制品及其制造方法
公开(公告)号：US20060121190A1
公开(公告)日：2006-06-08
申请号：US11143141
申请日：2005-06-01
申请人： Toshifumi Tsujino , Hideki Okamoto , Tetsuro Kawahara
发明人： Toshifumi Tsujino , Hideki Okamoto , Tetsuro Kawahara
IPC分类号： B05D3/02
CPC分类号： H01L31/02168 , C03C1/008 , C03C17/007 , C03C17/42 , C03C19/00 , C03C2217/213 , C03C2217/42 , C03C2217/478 , C03C2218/113 , C03C2218/116 , F24S80/52 , G02B1/11 , G02B1/12 , Y02E10/40 , Y02E10/50 , Y10T428/25 , Y10T428/26 , Y10T428/2993
摘要： A low reflection film comprising silica fine particles and a binder in a weight ratio proportion of 60:40 to 95:5 is obtained by mixing starting fine particles comprising at least non-aggregated silica fine particles with a mean particle size of 40-1000 nm and/or linear (chain-like) aggregated silica fine particles with a mean primary particle size of 10-100 nm, a hydrolyzable metal compound, water, and a solvent, hydrolyzing the hydrolyzable metal compound in the presence of the starting fine particles, and then coating the prepared coating solution onto a glass base substrate and subjecting it to heat treatment. The obtained low reflection film is a single-layer low reflection film with low reflectivity, excellent abrasion resistance, high film strength and excellent contamination removal property, and coating of the low reflection film onto glass base substrates can give low reflection glass articles.
摘要翻译：通过混合至少包含平均粒度为40-1000nm的非聚集的二氧化硅细颗粒的起始细颗粒，得到重量比为60:40至95:5的二氧化硅微粒和粘合剂的低反射膜和/或平均一次粒径为10-100nm的线性（链状）聚集的二氧化硅细颗粒，水解性金属化合物，水和溶剂，在起始微粒存在下水解可水解的金属化合物，然后将制备的涂布溶液涂布在玻璃基材上并对其进行热处理。获得的低反射膜是具有低反射率，优异的耐磨性，高膜强度和优异的污染除去性能的单层低反射膜，并且低反射膜在玻璃基底上的涂布可以产生低反射玻璃制品。

10. 发明授权

US06379803B1 Low-reflectance glass article and process for preparing the same 失效
标题翻译：低反射玻璃制品及其制备方法
公开(公告)号：US06379803B1
公开(公告)日：2002-04-30
申请号：US09230901
申请日：1999-02-03
申请人： Koichiro Nakamura , Toshifumi Tsujino , Koji Yokoi
发明人： Koichiro Nakamura , Toshifumi Tsujino , Koji Yokoi
IPC分类号： C03C1734
CPC分类号： C03C17/3417 , G02B1/115 , Y10T428/24942 , Y10T428/24975
摘要： The present invention is a low reflection glass article which is prepared by laminating a first layer which has a middle refractive index (n1) from 1.60 to 1.95 and has a film thickness of (60 to 130 nm)/n1, a second layer which has a high refractive index (n2) which is in a range from 1.91 to 2.60 and higher than the refractive index of said first layer by at least 0.20 and has a film thickness of (140 to 230 nm)/n2, and a third layer which has a low refractive index (n3) which is in a range from 1.35 to 1.59 and lower than the refractive index of said first layer by at least 0.20 and has a film thickness of (110 to 150 nm)/n3 in this order on a transparent glass substrate having a refractive index from 1.47 to 1.53, wherein said second layer contains titanium oxide and other metal oxides in an amount of 70 mol % or more in total, said third layer contains a silicon oxide in an amount from 50 to 100 mol % and said metal oxides in an amount from 0 to 10 mol % in total, and said first layer contains a silicon oxide in an amount from 15 to 80 mol % and said metal oxides in an amount from 20 to 70 mol % in total. According to the present invention, there can be provided a low reflection glass article coated with an optical multi-layer film which can reduce the reflectivity in wide visible light range.
摘要翻译：本发明是一种低反射玻璃制品，其通过层压具有1.60至1.95的中折射率（n1）从而具有（60-130nm）/ n1的膜厚度的第一层，其具有高折射率（n2）在1.91至2.60的范围内并且高于所述第一层的折射率至少为0.20并具有（140至230nm）/ n2的膜厚度，以及第三层，具有低折射率（n3），其在1.35至1.59的范围内，并且低于所述第一层的折射率至少0.20，并且具有（110至150nm）/ n3的膜厚度折射率为1.47〜1.53的透明玻璃基板，其中所述第二层含有氧化钛和总共为70摩尔％以上的其它金属氧化物，所述第三层含有50〜100摩尔的氧化硅％，所述金属氧化物的总量为0〜10摩尔％，前述1 ayer含有15至80摩尔％的氧化硅和所述金属氧化物的总量为20至70摩尔％。根据本发明，可以提供一种涂覆有光学多层的低反射玻璃制品可以在宽的可见光范围内降低反射率。

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