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    • 2. 发明授权
    • Ultraviolet/infrared absorbent glass
    • 紫外/红外吸收玻璃
    • US06468934B2
    • 2002-10-22
    • US09785406
    • 2001-02-20
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • C03C3095
    • C03C4/085C03C3/095C03C4/082C03C17/007C03C17/008C03C2217/45C03C2217/479Y10T428/252Y10T428/256
    • An ultraviolet/infrared absorbent glass is formed of base glass, and colorants. The base glass includes 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % a total amount of MgO and CaO; 10 to 20 wt. % a total amount of Na2O and K2O; 0.05 to 0.3 wt. % SO3; and 0 to 5 wt. % B2O3. The colorants are formed of 0.35 to 0.55 wt. % the total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.08 to 0.15 wt. % FeO; 0.8 to 1.5 wt. % CeO2 and 0 to 1.5 wt. % TiO2. FeO expressed as Fe2O3 is equal to or more than 20 wt.% and less than 27 wt. % of T-Fe2O3. The glass has high visible light transmittance and light greensih color shade so that it is useful for a window of a vehicle and a building.
    • 紫外/红外吸收玻璃由基底玻璃和着色剂形成。 基础玻璃包括65至80wt。 %SiO2; 0至5wt。 %Al2O3; 0〜10重量% %MgO; 5至15wt。 %CaO; 10至18wt。 %Na2O; 0至5wt。 %K2O; 5至15wt。 MgO和CaO的总量%; 10〜20重量% Na2O和K2O的总量% 0.05〜0.3重量% %SO3; 和0-5重量% %B2O3。 着色剂由0.35〜0.55重量% 以Fe2O3表示的总氧化铁(T-Fe2O3)的百分比; 0.08〜0.15wt %FeO; 0.8〜1.5wt。 %CeO 2和0〜1.5重量% %TiO2。 以Fe 2 O 3表示的FeO等于或大于20重量%且小于27重量% %的T-Fe2O3。 玻璃具有高可见光透光率和浅绿色色调,因此它对于车辆和建筑物的窗户是有用的。
    • 3. 发明授权
    • Colored film-coated ultraviolet/infrared absorbent glass plate and window glass of vehicle
    • 彩色涂膜紫外线/红外线吸收玻璃板和车窗玻璃
    • US06340646B1
    • 2002-01-22
    • US09437229
    • 1999-11-10
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • C03C3095
    • C03C4/085C03C3/095C03C4/082C03C17/007C03C17/008C03C2217/45C03C2217/479Y10T428/252Y10T428/256
    • A colored film-coated ultraviolet/infrared absorbent glass plate is formed of base glass, colorants, and a colored film. The base glass includes 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % total amount of MgO and CaO; 10 to 20 wt. % total amount of Na2O and K2O; 0.05 to 0.3 wt. % of SO3; and 0 to 5 wt. % B2O3. The colorants includes 0.35 to 0.55 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.08 to 0.15 wt. % FeO; 0.8 to 1.5 wt. % CeO2; and 0 to 0.5 wt. % TiO2. FeO expressed as Fe2O3 is equal to or more than 20 wt. % and less than 27 wt. % of T-Fe2O3. The colored film has a red color shade with a thickness between 30 nm and 300 nm and includes fine particles of gold and silicon oxide of more than 50 wt. % and equal to or less than 95 wt. %. The colored film is applied onto a surface of the ultraviolet/infrared absorbent glass plate.
    • 彩色薄膜紫外/红外线吸收玻璃板由基底玻璃,着色剂和着色膜形成。 基础玻璃包括65至80wt。 %SiO2; 0至5wt。 %Al2O3; 0〜10重量% %MgO; 5至15wt。 %CaO; 10至18wt。 %Na2O; 0至5wt。 %K2O; 5至15wt。 MgO和CaO的总量% 10〜20重量% Na2O和K2O的总量% 0.05〜0.3重量% SO3% 和0-5重量% %B2O3。 着色剂包括0.35至0.55wt。 以Fe2O3表示的总氧化铁(T-Fe2O3)%; 0.08〜0.15wt %FeO; 0.8〜1.5wt。 %CeO2; 和0〜0.5wt。 %TiO2。 以Fe2O3表示的FeO等于或大于20wt。 %且小于27wt。 %的T-Fe2O3。 着色膜具有厚度在30nm和300nm之间的红色色调,并且包括大于50重量%的金和氧化硅的细颗粒。 %且等于或小于95wt。 %。 将着色膜施加到紫外/红外线吸收玻璃板的表面上。
    • 9. 发明授权
    • Ultraviolet- and infrared-absorbing glass
    • 紫外线和红外线吸收玻璃
    • US5776846A
    • 1998-07-07
    • US782173
    • 1997-01-14
    • Koichi SakaguchiYukihito NagashimaIsamu KurodaShigekazu Yoshii
    • Koichi SakaguchiYukihito NagashimaIsamu KurodaShigekazu Yoshii
    • C03C3/095C03C4/02C03C4/08C03C3/087
    • C03C4/082C03C3/095C03C4/02C03C4/085
    • Ultraviolet- and infrared-absorbing glass comprising: as basic glass components, 65 to 80% by weight of SiO.sub.2, 0 to 5% by weight of Al.sub.2 O.sub.3, 0 to 10% by weight of MgO, 5 to 15% by weight of CaO, 10 to 18% by weight of Na.sub.2 O, 0 to 5% by weight of K.sub.2 O, 5 to 15% by weight in total of MgO and CaO, 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, and 0 to 5% by weight of B.sub.2 O.sub.3 ; and in the first embodiment, as coloring components, 0.25 to 0.45% by weight, in terms of Fe.sub.2 O.sub.3, of total iron oxide (T-Fe.sub.2 O.sub.3) having an FeO/T-Fe.sub.2 O.sub.3 ratio, in terms of Fe.sub.2 O.sub.3, of 15.5 to 25.0%, 0.8 to 2.0% by weight of CeO.sub.2, 0 to 1.0% by weight of TiO.sub.2, 0 to 0.005% by weight of CoO, and 0.0005 to 0.005% by weight of Se; or in the second embodiment, as coloring components, 0.25 to 0.5% by weight, in terms of Fe.sub.2 O.sub.3, of total iron oxide (T-Fe.sub.2 O.sub.3) having an FeO/T-Fe.sub.2 O.sub.3 ratio, in terms of Fe.sub.2 O.sub.3, of 5.0 to 20.0%, 1.4 to 2.0% by weight of CeO.sub.2, 0 to 0.4% by weight of TiO.sub.2, 0 to 0.002% by weight of CoO, and 0.0005 to 0.005% by weight of Se.
    • 紫外线和红外线吸收玻璃,其包含:作为碱性玻璃成分,65〜80重量%的SiO 2,0〜5重量%的Al 2 O 3,0〜10重量%的MgO,5〜15重量%的CaO, 10〜18重量%的Na 2 O,0〜5重量%的K 2 O,5〜15重量%的MgO和CaO,10〜20重量%的Na 2 O和K 2 O,0〜5重量% B2O3重量; 在第一实施方式中,作为着色成分,以Fe 2 O 3计,FeO / T-Fe 2 O 3比的总氧化铁(T-Fe 2 O 3)的Fe 2 O 3为0.25〜0.45重量%,以Fe 2 O 3计,为15.5〜25.0质量% ,CeO 2为0.8〜2.0重量%,TiO 2为0〜1.0重量%,CoO为0〜0.005重量%,Se为0.0005〜0.005重量% 或者在第二实施方案中,作为着色成分,以Fe2O3计,FeO / T-Fe 2 O 3比的Fe 2 O 3的总氧化铁(T-Fe 2 O 3)的Fe 2 O 3为0.25〜0.5重量%,以Fe 2 O 3计,为5.0〜20.0重量% ,CeO 2为1.4〜2.0重量%,TiO 2为0〜0.4重量%,CoO为0〜0.002重量%,Se为0.0005〜0.005重量%。