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1. 发明授权

US07709435B2 Alkaline cleaning liquid comprising metallic ions for aluminum or aluminum alloys and method of cleaning 有权
标题翻译：包含用于铝或铝合金的金属离子的碱性清洗液和清洁方法
公开(公告)号：US07709435B2
公开(公告)日：2010-05-04
申请号：US10569495
申请日：2004-08-27
申请人： Kazuya Hino , Yasuo Iino , Ryoji Morita , Akio Shimizu , Kazuhisa Masuda , Shozo Ichinose , Shozo Sakurama
发明人： Kazuya Hino , Yasuo Iino , Ryoji Morita , Akio Shimizu , Kazuhisa Masuda , Shozo Ichinose , Shozo Sakurama
IPC分类号： C11D3/04 , C11D3/36 , C11D3/10
CPC分类号： C11D11/0029 , C11D3/361 , C11D7/06 , C11D7/12 , C11D7/14 , C11D7/36 , C23G1/22
摘要： There is provided an alkaline cleaning of aluminum alloy, in which the attained corrosion resistance is equal or superior to the acidic cleaning agent, and which mitigates the disadvantages of the acidic cleaning agent, such as corrosion of plant, processing of the waste liquid, and energy cost, and which attains improved productivity.The cleaning liquid from 0.5 to 40 g/L in total of one or more alkali builders selected from alkali metal hydroxide, alkali metal carbonate, inorganic alkali metal phosphate and alkali metal silicate, from 0.2 to 10 g/L of one or more of organic phosphonic acid and its salt (A), from 0.001 to 2 g/L of one or more metallic ions (B) selected from metallic ions having from 5.0 to 14.0 of stability constant with the organic phosphonic acid and its salt, and from 0.1 to 10 g/L of surfactant. Particularly, the weight ratio of (A):(B) is in a range of from 100:0.05˜20.
摘要翻译：提供铝合金的碱性清洗，其中所获得的耐腐蚀性等于或优于酸性清洁剂，并且减轻了酸性清洁剂的缺点，例如植物的腐蚀，废液的处理和能源成本，提高生产率。洗涤液总量为0.5〜40g / L，一种或多种选自碱金属氢氧化物，碱金属碳酸盐，无机碱金属磷酸盐和碱金属硅酸盐的碱助洗剂，0.2-10g / L的一种或多种有机物膦酸及其盐（A），0.001至2g / L的一种或多种金属离子（B），其选自与有机膦酸及其盐稳定常数的5.0至14.0的金属离子，并且从0.1至 10g / L表面活性剂。特别地，（A）:( B）的重量比在100:0.05〜20的范围内。

2. 发明申请

US20070184997A1 Alkaline cleaning liquid for aluminum or aluminum alloys and method of cleaning 有权
标题翻译：铝或铝合金碱性清洗液及清洗方法
公开(公告)号：US20070184997A1
公开(公告)日：2007-08-09
申请号：US10569495
申请日：2004-08-27
申请人： Kazuya Hino , Yasuo Iino , Ryoji Morita , Akio Shimizu , Kazuhisa Masuda , Shozo Ichinose , Shozo Sakurama
发明人： Kazuya Hino , Yasuo Iino , Ryoji Morita , Akio Shimizu , Kazuhisa Masuda , Shozo Ichinose , Shozo Sakurama
IPC分类号： C09D9/00
CPC分类号： C11D11/0029 , C11D3/361 , C11D7/06 , C11D7/12 , C11D7/14 , C11D7/36 , C23G1/22
摘要： [Problems] There is provided an alkaline cleaning of aluminum alloy, in which the attained corrosion resistance is equal or superior to the acidic cleaning agent, and which mitigates the disadvantages of the acidic cleaning agent, such as corrosion of plant, processing of the waste liquid, and energy cost, and which attains improved productivity. [Means for Solution] The cleaning liquid from 0.5 to 40 g/L in total of one or more alkali builders selected from alkali metal hydroxide, alkali metal carbonate, inorganic alkali metal phosphate and alkali metal silicate, from 0.2 to 10 g/L of one or more of organic phosphonic acid and its salt (A), from 0.001 to 2 g/L of one or more metallic ions (B) selected from metallic ions having from 5.0 to 14.0 of stability constant with the organic phosphonic acid and its salt, and from 0.1 to 10 g/L of surfactant. Particularly, the weight ratio of (A): (B) is in a range of from 100:0.05˜20.
摘要翻译： [问题]提供铝合金的碱性清洗，其中所获得的耐腐蚀性等于或优于酸性清洁剂，并且减轻了酸性清洁剂的缺点，例如植物的腐蚀，废物的处理液体和能源成本，并且提高了生产率。 [解决方案]将选自碱金属氢氧化物，碱金属碳酸盐，无机碱金属磷酸盐和碱金属硅酸盐的总量为0.5〜40g / L的清洗液，0.2〜10g / L的一种或多种有机膦酸及其盐（A），0.001至2g / L的一种或多种金属离子（B），其选自与有机膦酸及其盐稳定常数的5.0至14.0的金属离子，和0.1〜10g / L的表面活性剂。特别地，（A）：（B）的重量比在100:0.05〜20的范围内。

3. 发明授权

US06306226B1 Process for surface-treating an aluminum-containing metal 有权
标题翻译：用于表面处理含铝金属的方法
公开(公告)号：US06306226B1
公开(公告)日：2001-10-23
申请号：US09177577
申请日：1998-10-23
申请人： Yasuo Iino , Hiroki Kojima , Tomohiro Ohsako , Hiroyoshi Sugawara , Kengo Kobayashi
发明人： Yasuo Iino , Hiroki Kojima , Tomohiro Ohsako , Hiroyoshi Sugawara , Kengo Kobayashi
IPC分类号： C23C2248
CPC分类号： F28F19/06 , B05D7/51 , C23C22/78 , C23C22/83 , C23F1/36 , C23G1/22 , F28D17/005 , F28F13/18 , F28F19/04 , F28F2245/02
摘要： An aluminum-containing metal material for, for example, a heat-exchanger for motorcars is surface-treated by chemically etching an Al-containing metal material surface, forming a first protective layer on the etched surface by a chemical conversion treatment with an aqueous solution of Zr phosphate or Ti phosphate, and coating the first protective layer with a second protective layer containing a hydrophilic resin including non-cross-linked hydrophilic functional groups and at least partially cross-linked reactive functional groups different from the hydrophilic functional groups, to impart high hydrophilicity and resistance to odor generation and corrosion to the aluminum-containing metal material surface.
摘要翻译：通过化学蚀刻含Al金属材料表面对例如用于摩托车的热交换器的含铝金属材料进行表面处理，通过用水溶液的化学转化处理在蚀刻表面上形成第一保护层的磷酸锌或磷酸钛，并且用包含非交联的亲水官能团的亲水性树脂和至少部分交联的与亲水官能团不同的反应性官能团的第二保护层涂覆第一保护层，以赋予含铝金属材料表面具有高亲水性和耐气味产生和腐蚀性。

4. 发明授权

US5336425A Acidic aluminum cleaner containing an oxidant and a nonionic surfactant stabilized by a glycol 失效
标题翻译：含有氧化剂和由二醇稳定的非离子表面活性剂的酸性铝清洁剂
公开(公告)号：US5336425A
公开(公告)日：1994-08-09
申请号：US971924
申请日：1992-12-21
申请人： Tomoyuki Aoki , Yasuo Iino , Yoji Ono , Shinichiro Asai
发明人： Tomoyuki Aoki , Yasuo Iino , Yoji Ono , Shinichiro Asai
IPC分类号： C11D10/02 , C23G1/12 , C11D1/72 , C23F1/20 , C23F1/22
CPC分类号： C23G1/125
摘要： The stability of an acidic liquid cleaner for aluminum comprising mineral acid, oxidant, polyvalent metal ions, and surfactant is substantially improved by the presence in the cleaner of from 0.05 to 5 g/L of a component selected from the group of glycols containing from 2 to 10 carbon atoms per molecule and mixtures of such glycols. The effectiveness of the cleaner for primary cleaning and de-smutting of aluminum and its alloys is not impaired and may even be improved by the addition of the glycol component.
摘要翻译： PCT No.PCT / US91 / 04263 Sec。 371日期：1993年12月21日 102（e）1993年12月21日的PCT日期1992年6月14日PCT。由含有无机酸，氧化剂，多价金属离子和表面活性剂的铝的酸性液体清洁剂的稳定性通过在 0.05至5g / L选自每分子含有2至10个碳原子的二醇的组分和这些二醇的混合物。用于铝及其合金的初步清洁和去除的清洁剂的有效性不受损害，甚至可以通过加入二醇组分来改善。

5. 发明授权

US5370909A Liquid composition and process for treating aluminum or tin cans to impart corrosion resistance and mobility thereto 失效
标题翻译：用于处理铝罐或锡罐的液体组合物和方法以赋予其耐腐蚀性和迁移性
公开(公告)号：US5370909A
公开(公告)日：1994-12-06
申请号：US949258
申请日：1992-12-18
申请人： Shigeo Tanaka , Tomoyuki Aoki , Masayuki Yoshida , Yasuo Iino , Shinichiro Asai
发明人： Shigeo Tanaka , Tomoyuki Aoki , Masayuki Yoshida , Yasuo Iino , Shinichiro Asai
IPC分类号： C23C22/23 , C23C22/68 , B05D1/02 , C23F11/00
CPC分类号： C23C22/23 , C23C22/68
摘要： A corrosion resistant film with a low coefficient of friction that facilitates automatic conveying can be formed on the surface of tin-plated steel or of aluminum, particularly DI cans of one of these types of metal, by contacting the aluminum or the tin plated steel with an aqueous liquid composition having a pH in the range from 2.0 to 6.5 and containing:(A) from 1 to 30 g/L of phosphate ions,(B) from 0.1 to 10 g/L of condensed phosphate ions, and(C) from 0.1 to 20 g/L as solids of water-soluble polymers of N-vinylphenol substituted on the phenolic rings with dialkylaminomethyl groups.
摘要翻译： PCT No.PCT / US91 / 04250 Sec。 371日期1992年12月18日 102（e）日期1992年12月18日PCT 1991年6月13日PCT。可以在镀锡钢或铝，特别是DI罐的表面上形成便于自动输送的具有低摩擦系数的耐腐蚀膜的这些金属之一，通过使铝或镀锡钢与pH为2.0-6.5的含水液体组合物接触，并含有：（A）1至30g / L的磷酸根离子（ B）0.1〜10g / L的缩合磷酸根离子，（C）0.1〜20g / L作为在具有二烷基氨基甲基的酚醛环上取代的N-乙烯基苯酚的水溶性聚合物的固体。

6. 发明授权

US4980076A Fluoride and chromium free acid etchant rinse for aluminum 失效
标题翻译：氟化物和无铬铬酸蚀刻剂冲洗铝
公开(公告)号：US4980076A
公开(公告)日：1990-12-25
申请号：US403625
申请日：1989-09-06
申请人： Shigeo Tanaka , Tomoyuki Aoki , Yasuo Iino , Yoji Ono
发明人： Shigeo Tanaka , Tomoyuki Aoki , Yasuo Iino , Yoji Ono
IPC分类号： C23G1/12
CPC分类号： C23G1/125
摘要： Problems with previously known aqueous acidic rinsing solutions for aluminum after shaping while using surface lubricants are avoided by use of a solution which contains water and (A) orthophosphoric acid in an amount to give a stoichiometric equivalent of 3.0 to 50 g/L as PO.sub.4.sup.-3, (B) an aluminum ion sequestrant component in an amount of 0.01 to 10.0 g/L; and (C) 20 to 170 ppm of ferric ion. The ferric ions act to inhibit corrosion of the stainless steel process equipment. Preferably the solution also contains 0.1 to 1.0 g/L of H.sub.2 O.sub.2, NO.sub.2.sup.-1 ions, or a mixture thereof to reoxidize ferrous ions formed by reduction of ferric ions during use of the solution and thus maintain the concentration of ferric ions above 20 ppm at all times. The solution may also contain surfactant and up to 10 g/L of dissolved aluminum ions.
摘要翻译：使用含有水的溶液和（A）正磷酸的量，通过使用表面润滑剂成型后的铝的先前已知的水性酸性漂洗溶液的问题可以避免，其量为化学计量当量为3.0〜50g / L，PO4- 3，（B）0.01〜10.0g / L的铝离子螯合剂成分; 和（C）20〜170ppm的铁离子。铁离子用于抑制不锈钢工艺设备的腐蚀。优选地，溶液还含有0.1至1.0g / L的H 2 O 2，NO 2 -1离子或其混合物，以在溶液的使用期间再氧化由铁离子还原形成的亚铁离子，并且因此将铁离子的浓度保持在20ppm以上一直。该溶液还可以含有表面活性剂和高达10g / L的溶解的铝离子。

7. 发明授权

US4301297A Process for preparing dimethylaminoethyl methacrylate 失效
标题翻译：制备甲基丙烯酸二甲氨基乙酯的方法
公开(公告)号：US4301297A
公开(公告)日：1981-11-17
申请号：US848523
申请日：1977-11-04
申请人： Yoshiya Kametani , Yasuo Iino
发明人： Yoshiya Kametani , Yasuo Iino
IPC分类号： C07B61/00 , B01J23/14 , B01J31/00 , B01J31/12 , C07C67/00 , C07C67/03 , C07C213/00 , C07C213/06 , C07C219/08
CPC分类号： C07C67/03
摘要： Dimethylaminoethyl methacrylate, which is a useful monomer for the production of polymers useful as flocculants, antistatic agents, soil improving agents, etc., having a high purity can be prepared in a high yield by subjecting methyl methacrylate and dimethylaminoethanol to transesterification in the presence of di-n-octyltin oxide as a catalyst.
摘要翻译：作为生产可用作絮凝剂的聚合物，抗静电剂，土壤改良剂等的有用单体的甲基丙烯酸二甲基氨基乙酯可以通过使甲基丙烯酸甲酯和二甲基氨基乙醇在存在下进行酯交换而以高产率制备，二正辛基锡氧化物作为催化剂。

8. 发明授权

US4281175A Process for producing dimethylaminoethyl methacrylate 失效
标题翻译：甲基丙烯酸二甲氨基乙酯的制备方法
公开(公告)号：US4281175A
公开(公告)日：1981-07-28
申请号：US160367
申请日：1980-06-17
申请人： Yoshiya Kametani , Yasuo Iino
发明人： Yoshiya Kametani , Yasuo Iino
IPC分类号： C07B61/00 , B01J31/00 , B01J31/12 , C07C67/00 , C07C213/00 , C07C213/06 , C07C219/08 , C07C67/02
CPC分类号： C07C213/06 , B01J31/122
摘要： Methyl methacrylate is transesterified with dimethylaminoethanol using alkyltin compounds as catalysts. Typical alkyltin compounds used are tetrabutyltin, trioctyltin ethoxide, dibutyltin dimethoxide, dibutyltin dihydride, dibutyltin dilaurate, dibutyltin maleate, bis(tributyltin) oxide and bis(dibutylmethoxytin) oxide.
摘要翻译：使用烷基锡化合物作为催化剂，甲基丙烯酸甲酯与二甲基氨基乙醇酯交换。所用的典型烷基锡化合物是四丁基锡，乙氧基三辛基锡，二甲氧基二丁基锡，二氢化二丁基锡，二月桂酸二丁基锡，马来酸二丁基锡，氧化双（三丁基锡）氧化物和双（二丁基甲氧基锡）氧化物。

9. 发明授权

US4212040A Tape recorder with single control activating member 失效
标题翻译：磁带录音机，带单控制激活器
公开(公告)号：US4212040A
公开(公告)日：1980-07-08
申请号：US923196
申请日：1978-07-10
申请人： Masashi Yoshida , Yasuo Iino
发明人： Masashi Yoshida , Yasuo Iino
IPC分类号： G11B15/10 , G11B15/18 , G11B15/22 , G11B5/54 , G11B21/22
CPC分类号： G11B15/10 , G11B15/18
摘要： A tape recorder is disclosed in which the movement of the pinch roller toward and away from the capstan, the movement of the take-up roller toward and away from the take-up reel mount and the movement of the brake plate toward and away from the take-up and supply reel mounts are performed by a single control board having three control sections. The movement of the control board is associated with that of the head base plate carrying a magnetic head and movable between a stop position and a playback position. When the head base plate moves to the playback position, the control board moves together with the head base plate by the elasticity of the spring member tensioned therebetween, whereby the three types of movements make possible the desired playback state. In response to an external operation for a pause, the control board alone is moved to the stop position, thus turning the three types of movements into a pause mode.
摘要翻译：公开了一种磁带记录器，其中夹送辊朝向和远离主导轴的移动，卷取辊朝向和远离收紧卷轴安装件的运动以及制动板朝向和远离卷取卷轴安装件的运动卷取和卷取装置由具有三个控制部分的单个控制板执行。控制板的运动与携带磁头的头基板的运动相关联，并可在停止位置和重放位置之间移动。当头基板移动到播放位置时，控制板通过在其之间张紧的弹簧构件的弹性与头基板一起移动，由此三种类型的移动使得期望的重放状态成为可能。响应于暂停的外部操作，单独的控制板被移动到停止位置，从而将三种类型的运动转变成暂停模式。

10. 发明授权

US4131922A Operation device of tape recorder 失效
标题翻译：录音机操作装置
公开(公告)号：US4131922A
公开(公告)日：1978-12-26
申请号：US864263
申请日：1977-12-27
申请人： Masashi Yoshida , Yasuo Iino , Katsuya Sato
发明人： Masashi Yoshida , Yasuo Iino , Katsuya Sato
IPC分类号： G11B15/10 , G11B15/26 , G11B15/32
CPC分类号： G11B15/106
摘要： An operation device of a tape recorder adapted to bring mechanisms such as a pinch roller, magnetic heads and so on into constant-speed tape feeding condition, making use of a part of torque of a member such as a capstan which is driven by a motor. The device has a manual operation system and an automatic actuating system. The manual operation system includes a manually operable constant-speed tape feed operation member and first locking means adapted to lock the manual operation member at an operation position to which the same has been displaced. The automatic actuating system includes a first rotary body adapted to be rotated in relation with the rotation of the shaft of the motor, a second rotary body having an engageable portion capable of performing a torque-transmitting engagement with the first rotary body and a non-engageable portion which cannot engage the first rotary body, an actuating plate adapted to be displaced by the rotation of the second rotary body and to control the position of the mechanisms, and second locking means to lock the mechanisms at a position to which they have been displaced. As the operation member is operated, it is locked at the operation position by the first locking means. A part of power for displacing the operation member to the operation position is transmitted to the second rotary body, which has confronted the first rotary body at its non-engageable portion, is slightly rotated to bring its engageable portion into engagement with the first rotary body, so as to be continuously driven by the latter. As the second rotary body is driven, it displaces the mechanisms through the actuating plate, and the mechanisms are held at the position to which they have been moved.
摘要翻译：一种磁带记录器的操作装置，其适用于将诸如压带辊，磁头等的机构带入恒速送带状态，利用由马达驱动的绞盘等部件的转矩的一部分。该设备具有手动操作系统和自动启动系统。手动操作系统包括手动操作的恒速送带操作构件和适于将手动操作构件锁定在其移动位置的操作位置的第一锁定装置。所述自动致动系统包括：第一旋转体，其适于相对于所述马达的轴的旋转而旋转;第二旋转体，具有能够与所述第一旋转体进行扭矩传递接合的可接合部; 不能接合第一旋转体的可接合部分，适于通过第二旋转体的旋转而移位并且控制机构的位置的致动板，以及第二锁定装置，以将机构锁定在它们已经被存在的位置流离失所当操作构件被操作时，其通过第一锁定装置锁定在操作位置。用于将操作构件移动到操作位置的动力的一部分被传递到在其不可接合部分处面对第一旋转体的第二旋转体稍微旋转以使其可接合部分与第一旋转体，以便由后者继续驱动。当第二旋转体被驱动时，其通过致动板移动机构，并且机构保持在它们已经移动到的位置。

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