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    • 4. 发明授权
    • Production method of polyhydroxyimide
    • 聚羟基酰亚胺的生产方法
    • US08871894B2
    • 2014-10-28
    • US13264917
    • 2010-04-22
    • Kazuya Ebara
    • Kazuya Ebara
    • C08G69/10G03F7/023C08G73/10C09D179/08G03F7/004
    • C09D179/08C08G73/1028C08G73/1032C08G73/1039C08G73/1042C08G73/1046C08G73/106C08G73/1064C08G73/1075G03F7/0045G03F7/0233
    • There is provided a simple production method of a polyhydroxyimide. A production method of a polyhydroxyimide, characterized by comprising adding to a polyhydroxyimide precursor containing a repeating structure of Formula (1): in which X is a tetravalent aliphatic group or aromatic group, Y is an organic group containing an aromatic group substituted with at least one OH group, and n is an integer of 1 or more, at least a compound of Formula (2) or Formula (3): in which R1 to R4 or R5 to R8 are independently a hydrogen atom or a monovalent organic group, and m is a natural number, and heating the resultant reaction mixture at a temperature of 50° C. or more to obtain a polyimide having a weight average molecular weight measured by gel permeation chromatography (GPC) in terms of polystyrene of 5,000 to 100,000.
    • 提供了一种简单的多羟基酰亚胺生产方法。 一种聚羟基酰亚胺的制造方法,其特征在于,向含有式(1)的重复结构的聚羟基酰亚胺前体中加入其中X为四价脂肪族基团或芳香族基团,Y为含有至少被取代的芳香族基团的有机基团 一个OH基,n为1以上的整数,至少为式(2)或式(3)的化合物:其中,R 1至R 4或R 5至R 8独立地为氢原子或一价有机基团,和 m为自然数,在50℃以上的温度下加热得到的反应混合物,得到聚苯乙烯换算通过凝胶渗透色谱法(GPC)测定的重均分子量为5,000〜100,000的聚酰亚胺。
    • 8. 发明申请
    • FILM-FORMING MATERIAL
    • 成膜材料
    • US20130284261A1
    • 2013-10-31
    • US13990896
    • 2011-12-01
    • Kazuya Ebara
    • Kazuya Ebara
    • H01L31/0216
    • H01L31/02167C08F12/02C08F212/32C08F220/06C08F2810/20C08G73/0644H01L31/02168Y02E10/50Y02E10/52
    • There is provided a novel material used for solar cells that can contribute to the improvement in maximum output of solar cells without using the conventional MPPT system. A film-forming material for forming a light-collecting film on a transparent electrode of a solar cell, including an aromatic group-containing organic polymer compound (A) and a cross-linker (B), wherein the film-forming material exhibits an index of refraction of 1.5 to 2.0 at a wavelength of 633 nm and a transmittance of 95% or more with respect to light having a wavelength of 400 nm, and a solar cell obtained by coating a cured film made from the film-forming material on a surface of a transparent electrode.
    • 提供了用于太阳能电池的新型材料,其可以有助于在不使用常规MPPT系统的情况下改善太阳能电池的最大输出。 一种用于在太阳能电池的透明电极上形成聚光膜的成膜材料,其包含含芳基的有机聚合物化合物(A)和交联剂(B),其中所述成膜材料显示出 折射率为1.5〜2.0,波长为633nm,透射率为波长400nm的光的透射率为95%以上,通过将由成膜材料制成的固化膜涂布在 透明电极的表面。
    • 9. 发明申请
    • PRODUCTION METHOD OF POLYHYDROXYIMIDE
    • 聚羟基酰亚胺的生产方法
    • US20120094232A1
    • 2012-04-19
    • US13264917
    • 2010-04-22
    • Kazuya Ebara
    • Kazuya Ebara
    • G03F7/039C07D209/02C07D209/48C07D213/69C08G73/10C09D179/08
    • C09D179/08C08G73/1028C08G73/1032C08G73/1039C08G73/1042C08G73/1046C08G73/106C08G73/1064C08G73/1075G03F7/0045G03F7/0233
    • There is provided a simple production method of a polyhydroxyimide. A production method of a polyhydroxyimide, characterized by comprising adding to a polyhydroxyimide precursor containing a repeating structure of Formula (1): in which X is a tetravalent aliphatic group or aromatic group, Y is an organic group containing an aromatic group substituted with at least one OH group, and n is an integer of 1 or more, at least a compound of Formula (2) or Formula (3): in which R1 to R4 or R5 to R8 are independently a hydrogen atom or a monovalent organic group, and m is a natural number, and heating the resultant reaction mixture at a temperature of 50° C. or more to obtain a polyimide having a weight average molecular weight measured by gel permeation chromatography (GPC) in terms of polystyrene of 5,000 to 100,000.
    • 提供了一种简单的聚羟基酰亚胺生产方法。 一种聚羟基酰亚胺的制造方法,其特征在于,向含有式(1)的重复结构的聚羟基酰亚胺前体中加入其中X为四价脂肪族基团或芳香族基团,Y为含有至少被取代的芳香族基团的有机基团 一个OH基,n为1以上的整数,至少为式(2)或式(3)的化合物:其中,R 1至R 4或R 5至R 8独立地为氢原子或一价有机基团,和 m为自然数,在50℃以上的温度下加热得到的反应混合物,得到聚苯乙烯换算通过凝胶渗透色谱法(GPC)测定的重均分子量为5,000〜100,000的聚酰亚胺。
    • 10. 发明申请
    • POSITIVE PHOTOSENSITIVE RESIN COMPOSITION AND DPOLYHYDROXYAMIDE RESIN
    • 阳性光敏树脂组合物和DPOLYHYDROXYAMIDE树脂
    • US20100119969A1
    • 2010-05-13
    • US12451906
    • 2008-05-27
    • Kazuya EbaraHideo SuzukiTakayuki Tamura
    • Kazuya EbaraHideo SuzukiTakayuki Tamura
    • G03F7/004C08G63/00
    • C08G69/28C08G69/26C08G69/265C08G69/40C08G69/42G03F7/0045G03F7/0233G03F7/0387G03F7/0757G03F7/40
    • There is provided a positive photosensitive resin composition that is excellent in electric insulating properties, heat resistance, mechanical strength and electrical characteristics, and capable of forming a high-resolution circuit pattern. The positive photosensitive resin composition comprises at least one type of a polyhydroxyamide resin containing a repeating unit represented by Formula (1) and having a weight average molecular weight of 3,000 to 100,000, and a compound generating an acid by light irradiation. (where X represents a tetravalent aliphatic group or an aromatic group; R1 and R2 independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atom(s); Ar1 and Ar2 independently represent an aromatic group; Y represents an organic group containing an aromatic group substituted with at least one OH group; n represents an integer of 1 or more; and l and m independently represent an integer of 0 or 1 or more and satisfy l+m≦2).
    • 提供了具有优异的电绝缘性,耐热性,机械强度和电特性并且能够形成高分辨率电路图案的正型感光性树脂组合物。 正型感光性树脂组合物包含至少一种含有式(1)表示的重均单元,重均分子量为3,000〜100,000的聚羟基酰胺树脂和通过光照射产生酸的化合物。 (其中X表示四价脂肪族基团或芳香族基团; R 1和R 2分别表示氢原子或碳原子数1〜10的烷基,Ar 1和Ar 2独立地表示芳香族基,Y表示含有 被至少一个OH基团取代的芳基; n表示1以上的整数,l和m分别表示0或1以上的整数,满足l + m< 1lE; 2)。