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1. 发明授权

US09005857B2 Thermochromic color-memorization toner, cartridge including same housed therein, image formation apparatus, cartridge set, and image formation apparatus set 有权
标题翻译：热变色记忆调色剂，包含其中的相同的盒，图像形成装置，盒组和图像形成装置
公开(公告)号：US09005857B2
公开(公告)日：2015-04-14
申请号：US13509663
申请日：2009-11-13
申请人： Katsuyuki Fujita , Yoshiaki Ono , Yutaka Shibahashi
发明人： Katsuyuki Fujita , Yoshiaki Ono , Yutaka Shibahashi
IPC分类号： G03G9/00 , B43K29/00 , G03G9/08 , C09D11/17 , G03G9/09
CPC分类号： G03G9/0812 , C09D11/17 , G03G9/0821 , G03G9/0825 , G03G9/0926 , G03G9/0928
摘要： The present invention relates to a thermochromic color-memory toner containing: a microcapsule pigment encapsulating a thermochromic color-memory composition; and a binder resin, in which the microcapsule pigment shows a hysteresis characteristic that, in a temperature-rise process, decoloration starts when the temperature reaches t3 and the pigment completely reaches a decolored state in a temperature region of t4 or higher, and in a temperature-drop process, coloration starts when the temperature reaches t2 and the pigment completely reaches a colored state in a temperature region of ti or lower, and ti is in a range of from −50 to 0° C. and t4 is in a range of from 50 to 150° C.
摘要翻译：本发明涉及一种热致变色彩记忆调色剂，其含有：包封热变色色记忆组合物的微胶囊颜料; 和粘合剂树脂，其中微胶囊颜料显示出在温度升高过程中当温度达到t3时开始脱色并且颜料在t4或更高的温度区域完全达到脱色状态的滞后特性，并且在温度下降过程中，当温度达到t2时开始着色，并且颜料在ti或更低的温度区域中完全达到着色状态，并且t 1在-50至0℃的范围内，并且t 4在一定范围内为50〜150℃

2. 发明授权

US5879438A Method for improving light-fastness of reversible thermochromic compositions at the time of color extinguishment 失效
标题翻译：在熄灭时提高可逆热变色组合物的耐光性的方法
公开(公告)号：US5879438A
公开(公告)日：1999-03-09
申请号：US791420
申请日：1997-01-30
申请人： Katsuyuki Fujita , Yoshiaki Ono , Yutaka Shibahashi
发明人： Katsuyuki Fujita , Yoshiaki Ono , Yutaka Shibahashi
IPC分类号： C09K3/00 , B41M5/30 , B41M5/337 , B41M5/40 , B41M5/42 , C09B67/00 , C09B67/08 , C09B67/44 , C09K9/02 , C09D11/02
CPC分类号： B41M5/3375 , B41M5/305 , B41M5/42 , C09K9/02 , B41M5/423 , B41M5/426
摘要： A reversible thermochromic composition is formed by blending: (a) an electron donating compound; (b) an electron accepting compound; (c) a metachromatic temperature adjuster; (d) an electron accepting, light-fastness providing agent represented by Formula I based on 1.0 part by weight of the component-(a) electron donating compound: ##STR1## wherein n represents an integer of 5 to 17; X and Y each represent C.sub.1-4 or halogen; and p and m each represent an integer of 0 to 3.
摘要翻译：通过以下方式形成可逆热变色组合物：（a）给电子化合物; （b）电子接受性化合物; （c）异味温度调节器; （d）基于1.0重量份组分（a）给电子化合物的式I表示的电子接受耐光性提供剂：其中n表示5至17的整数; X和Y各自表示C1-4或卤素; p和m分别表示0〜3的整数。

3. 发明申请

US20130029257A1 THERMOCHROMIC COLOR-MEMORIZATION TONER, CARTRIDGE INCLUDING SAME HOUSED THEREIN, IMAGE FORMATION APPARATUS, CARTRIDGE SET, AND IMAGE FORMATION APPARATUS SET 有权
标题翻译：热变色彩记忆墨粉盒，包括同类住房的图像，图像形成装置，墨盒和图像形成装置
公开(公告)号：US20130029257A1
公开(公告)日：2013-01-31
申请号：US13509663
申请日：2009-11-13
申请人： Katsuyuki Fujita , Yoshiaki Ono , Yutaka Shibahashi
发明人： Katsuyuki Fujita , Yoshiaki Ono , Yutaka Shibahashi
IPC分类号： G03G9/00 , G03G15/08
CPC分类号： G03G9/0812 , C09D11/17 , G03G9/0821 , G03G9/0825 , G03G9/0926 , G03G9/0928
摘要： The present invention relates to a thermochromic color-memory toner containing: a microcapsule pigment encapsulating a thermochromic color-memory composition; and a binder resin, in which the microcapsule pigment shows a hysteresis characteristic that, in a temperature-rise process, decoloration starts when the temperature reaches t3 and the pigment completely reaches a decolored state in a temperature region of t4 or higher, and in a temperature-drop process, coloration starts when the temperature reaches t2 and the pigment completely reaches a colored state in a temperature region of ti or lower, and ti is in a range of from −50 to 0° C. and t4 is in a range of from 50 to 150° C.
摘要翻译：本发明涉及一种热致变色彩记忆调色剂，其含有：包封热变色色记忆组合物的微胶囊颜料; 和粘合剂树脂，其中微胶囊颜料显示出在温度升高过程中当温度达到t3时开始脱色并且颜料在t4或更高的温度区域完全达到脱色状态的滞后特性，并且在温度下降过程中，当温度达到t2时开始着色，并且颜料在ti或更低的温度区域中完全达到着色状态，并且t 1在-50至0℃的范围内，并且t 4在一定范围内为50〜150℃

4. 发明授权

US5873932A Method for improving light-fastness of reversible thermochromic compositions at the time of color development 失效
标题翻译：在显色时提高可逆热变色组合物的耐光性的方法
公开(公告)号：US5873932A
公开(公告)日：1999-02-23
申请号：US760209
申请日：1996-12-04
申请人： Katsuyuki Fujita , Yutaka Shibahashi , Yoshiaki Ono
发明人： Katsuyuki Fujita , Yutaka Shibahashi , Yoshiaki Ono
IPC分类号： G01K11/16 , B41M5/30 , B41M5/333 , B41M5/337 , C08K5/00 , C08K5/02 , C08K5/03 , C08K5/13 , C08L101/00 , C09K3/00 , C09K9/02 , C09K15/08 , C09D11/02
CPC分类号： C09K9/02 , B41M5/305 , B41M5/3335 , B41M5/3375
摘要： A method of causing metachromatism by the use of a reversible thermochromic composition comprising (a) an electron donating compound, (b) an electron accepting compound and (c) a metachromatic temperature adjuster, wherein;(d) an electron accepting, light-fastness providing agent represented by Formula I: ##STR1## wherein n represents an integer of 5 to 17 to form a straight-chain or branched alkyl group; X and Y each represent a straight-chain or branched alkyl group having 1 to 4 carbon atoms, or a halogen atom; and p and m each represent an integer of 0 to 3;is brought into presence in an amount of 0.3 part by weight to 70 parts by weight based on 1.0 part by weight of the component-(a) electron donating compound.The light-fastness of the reversible thermochromic composition at the time of color development can be greatly improved.
摘要翻译：一种通过使用可逆热变色组合物引起变质反应的方法，其包含（a）给电子化合物，（b）电子接受化合物和（c）异色温度调节剂，其中：（d）由式I表示的电子接受耐光性提供剂：其中n表示5〜17的整数，形成直链或支链烷基; X和Y各自表示具有1〜4个碳原子的直链或支链烷基或卤素原子; p和m各自表示0〜3的整数，以（a）给电子化合物1.0重量份计，以0.3重量份〜70重量份的量存在。显色时可逆热变色组合物的耐光性可大大提高。

5. 发明授权

US5858914A Thermochromic coloring color-memory footwear 失效
标题翻译：热变色着色色记忆鞋
公开(公告)号：US5858914A
公开(公告)日：1999-01-12
申请号：US668818
申请日：1996-06-24
申请人： Yutaka Shibahashi , Katsuyuki Fujita , Akio Nakashima
发明人： Yutaka Shibahashi , Katsuyuki Fujita , Akio Nakashima
IPC分类号： A43B23/24 , A63F3/06 , B44F1/10 , B41M5/34
CPC分类号： A43B3/24 , A43B1/0036 , A43B23/24 , A43B3/0078 , B44F1/10 , A63F3/0685
摘要： A footwear has a thermochromic coloring color-memory layer having a large hysteresis on a color-density-to-temperature curve so as to show interchangeability between a first color phase and a second color phase different from the first color phase, and a coloring tool for forming a desired image on the footwear.
摘要翻译：一种鞋类具有在色密度 - 温度曲线上具有大的迟滞的热致变色着色色记忆层，以便显示第一色相和不同于第一色相的第二色相之间的互换性，以及着色工具用于在鞋上形成期望的图像。

6. 发明授权

US5688592A Thermochromic laminate comprising light intercepting pigment and light stabilizer 失效
标题翻译：包含遮光颜料和光稳定剂的热变色层压板
公开(公告)号：US5688592A
公开(公告)日：1997-11-18
申请号：US425788
申请日：1995-04-20
申请人： Yutaka Shibahashi , Katsuyuki Fujita
发明人： Yutaka Shibahashi , Katsuyuki Fujita
IPC分类号： B41M5/337 , B32B27/18 , B44F1/08 , B32B5/16
CPC分类号： B32B27/18 , B41M5/30 , B41M5/42 , B44F1/08 , B41M2205/04 , B41M2205/40 , B41M5/305 , B41M5/423 , B41M5/426 , Y10S428/913 , Y10S428/914 , Y10T428/25 , Y10T428/251 , Y10T428/256 , Y10T428/2991
摘要： A thermochromic laminate is provided which comprises a thermochromic layer, and a coating layer or layers laminated thereon containing a light-intercepting pigment and a light stabilizer; the coating layer or layers containing the light-intercepting pigment and the light stabilizer dispersed and fixed in a first film-forming material, and the thermochromic layer constituted of a homogeneous solid composed of an electron-donating coloring organic compound, an electron-accepting compound, and an organic compound medium for adjusting color reaction temperature dispersed and fixed in a second film forming material; the light-intercepting pigment being one or more pigments selected from metallic luster pigments, transparent titanium dioxide, transparent iron oxide, transparent cesium oxide, and transparent zinc oxide; and the light stabilizer being one or more chemicals selected from ultraviolet absorbers, antioxidants, singlet oxygen quenchers, superoxide anion quenchers, ozone quenchers, visible light absorbers, and infrared absorbers. The thermochromic laminate has remarkably improved light-fastness.
摘要翻译：提供了一种热致变色层压板，其包括热变色层，以及层压在其上的包含遮光颜料和光稳定剂的涂层; 包含遮光颜料的涂层或分散固定在第一成膜材料中的光稳定剂的层，以及由供电子着色有机化合物，电子接受性化合物和用于调节分散固定在第二成膜材料中的显色反应温度的有机化合物介质; 遮光颜料是选自金属光泽颜料，透明二氧化钛，透明氧化铁，透明氧化铯和透明氧化锌中的一种或多种颜料; 光稳定剂是选自紫外线吸收剂，抗氧化剂，单线态氧猝灭剂，超氧化物阴离子猝灭剂，臭氧猝灭剂，可见光吸收剂和红外线吸收剂中的一种或多种化学物质。热变色层压板具有显着提高的耐光性。

7. 发明授权

US06444313B1 Thermochromic acrylic synthetic fiber, its processed article, and process for producing thermochromic acrylic synthetic fiber 有权
标题翻译：热变色丙烯酸合成纤维，其加工制品，以及生产热变色丙烯酸合成纤维的方法
公开(公告)号：US06444313B1
公开(公告)日：2002-09-03
申请号：US09754309
申请日：2001-01-05
申请人： Yoshiaki Ono , Naoya Ishimura , Yutaka Shibahashi
发明人： Yoshiaki Ono , Naoya Ishimura , Yutaka Shibahashi
IPC分类号： D01F600
CPC分类号： D01F6/18 , D01F1/04 , D04H1/43 , D04H1/4382 , D04H3/00 , Y10S428/913 , Y10T428/2915 , Y10T428/2927 , Y10T428/2933 , Y10T428/2984
摘要： A thermochromic acrylic synthetic fiber comprising an acrylonitrile polymer in which a thermochromic pigment composition with an average particle diameter of from 0.5 &mgr;m to 30 &mgr;m is dispersedly contained in an amount of from 0.5% by weight to 40% by weight based on the weight of the polymer, and being made into fibers; the pigment composition containing (a) an electron-donating color-developing organic compound, (b) an electron-accepting compound and (c) a reaction medium that determines the temperature at which the color-developing reaction of the both compounds takes place. Also disclosed are a processed article of the above thermochromic acrylic synthetic fiber, and a process for producing the thermochromic acrylic synthetic fiber.
摘要翻译：包含丙烯腈聚合物的热致变色丙烯酸类合成纤维，其中平均粒径为0.5〜30μm的热变色颜料组合物以0.5重量％〜40重量％的量分散包含，聚合物，并制成纤维; 所述颜料组合物含有（a）给电子显色有机化合物，（b）电子接受性化合物和（c）确定发生两种化合物的显色反应的温度的反应介质。还公开了上述热变色丙烯酸类合成纤维的加工品，以及制造热变色丙烯酸类合成纤维的方法。

8. 发明授权

US09937434B2 Photochromic toy 有权
公开(公告)号：US09937434B2
公开(公告)日：2018-04-10
申请号：US14131610
申请日：2012-07-13
申请人： Michiyuki Yasuda , Yutaka Shibahashi , Yoshie Kamiya
发明人： Michiyuki Yasuda , Yutaka Shibahashi , Yoshie Kamiya
IPC分类号： A63H33/22 , C09K9/02 , C09K11/08 , C09K11/77
CPC分类号： A63H33/22 , C09K9/02 , C09K11/0883 , C09K11/7731 , C09K11/7734 , C09K11/7774
摘要： The present invention relates to a photochromic toy containing a light irradiator equipped with a light source and a toy main body containing a photochromic compound, in which the light source has a peak wavelength in the range of from 400 nm to 495 nm and the photochromic compound satisfies the following expression (1) between the integrated value of absorbance (x) in the range of from a wavelength showing a maximum absorbance in less than 400 nm to a wavelength of 400 nm and the integrated value of absorbance (y) in the wavelength range of from 400 nm to 700 nm. y/x≥0.02 (1)

9. 发明申请

US20070082977A1 Ink composition for color-memorizing photochromic writing instrument and writing instrument using the same 审中-公开
标题翻译：用于记忆光致变色书写工具和书写工具的墨水组合物
公开(公告)号：US20070082977A1
公开(公告)日：2007-04-12
申请号：US11245167
申请日：2005-10-07
申请人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
发明人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
IPC分类号： C09D11/00
CPC分类号： C09D11/17 , C09D11/50
摘要： An ink composition for a color-memorizing photochromic writing instrument, which comprises a photochromic agent containing a diarylethene photochromic compound dissolved, dispersed or suspended in a vehicle containing at least a solvent and a binder.
摘要翻译：一种用于记忆光致变色书写工具的油墨组合物，其包含溶解，分散或悬浮在至少含有溶剂和粘合剂的载体中的二烯丙基光致变色化合物的光致变色剂。

10. 发明申请

US20060053975A1 Color-memorizing photochromic writing instrument, color-memorizing photochromic writing instrument set using the same and method for alternately expressing color-memorizing photochromic function of writing image 有权
公开(公告)号：US20060053975A1
公开(公告)日：2006-03-16
申请号：US11226291
申请日：2005-09-15
申请人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
发明人： Yutaka Shibahashi , Michiyuki Yasuda , Masahiro Irie
IPC分类号： B41B1/00 , G02B5/23
CPC分类号： B43K5/02 , B43K7/02 , B43K8/03 , B43K23/12 , C09D11/17 , C09D11/18
摘要： A color-memorizing photochromic writing instrument, which comprises a writing tip portion connected to a light-shielding tubular member or refill; and a color-memorizing photochromic ink, wherein the ink is prepared by dissolving, dispersing or suspending a diarylethene photochromic compound in a vehicle containing at least a solvent and a binder, wherein the diarylethene photochromic compound is in a coloring state, and a color-memorizing photochromic writing instrument set comprising the writing instrument and a color-changing means.

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