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    • 3. 发明授权
    • Ultrafine particles of amorphous metal and method for production thereof
    • 非晶态金属微粒及其制造方法
    • US5578108A
    • 1996-11-26
    • US313827
    • 1994-09-28
    • Tadashi YamaguchiKatsutoshi NosakiAkihisa InoueTsuyoshi Masumoto
    • Tadashi YamaguchiKatsutoshi NosakiAkihisa InoueTsuyoshi Masumoto
    • B22F9/14B22F1/00B22F9/12C22C1/00C22C45/00C22C45/02C22C45/10C23C14/00
    • B22F9/12C22C1/002C22C45/02C22C45/10B22F2999/00
    • Ultrafine amorphous metal particles which combine the properties of ultrafine particles with those of an amorphous alloy and a method for the production thereof are disclosed. The ultrafine amorphous metal particles are produced by a method which comprises discharging a plasma arc against a raw metal capable of forming a carbide in a reaction gas using an inert gas as a main component thereof and containing a hydrocarbon gas, and allowing the metal which has been consequently vaporized to contact the reaction gas which has been consequently converted into a plasma, thereby inducing formation of a solid solution of carbon atoms in the vaporized metal and quenching the solid solution in the reaction gas to confer an amorphous structure thereon. As the raw metal, at least one metal selected from the group consisting of Fe, Mo, Nb, Ta, Ti, Zr, Al, Si, and Cr is preferably used. By this method are obtained ultrafine amorphous metal particles which comprise the metal mentioned above, possess at least 50% by volume of an amorphous phase, and have particle diameters of not more than 500 nm.
    • 公开了将超细颗粒的性质与非晶合金的特性结合的超细无定形金属颗粒及其制造方法。 超细非晶态金属颗粒通过以下方法制造:使用惰性气体作为主要成分并含有烃气体的反应气体中能够形成碳化物的原料的等离子体电弧放电, 随后蒸发以接触已经转化成等离子体的反应气体,从而在蒸发的金属中引起碳原子的固溶体的形成,并淬灭反应气体中的固溶体以赋予其非晶结构。 作为原料金属,优选使用选自Fe,Mo,Nb,Ta,Ti,Zr,Al,Si和Cr中的至少一种金属。 通过该方法获得了包含上述金属的超细无定形金属颗粒,具有至少50体积%的非晶相,并且具有不大于500nm的粒径。