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    • 2. 发明申请
    • FLAME RETARDANT RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
    • 阻燃树脂组合物及其制品
    • US20110301266A1
    • 2011-12-08
    • US13201929
    • 2010-02-12
    • Katsuhiro YamanakaFumitaka Kondo
    • Katsuhiro YamanakaFumitaka Kondo
    • C08K5/5357C08L69/00C08L67/04C08L25/04
    • C09K21/12C07F9/657181C08K5/5357C08L25/12C08L51/04C08L55/02C08L67/04C08L69/00C08L2666/02
    • A flame retardant resin composition which has high flame retardancy, excellent heat resistance and physical properties and is obtained from a plant-derived raw material and a molded article thereof.The flame retardant resin composition comprises: (A) 100 parts by weight of a polylactic acid and/or a lactic acid copolymer (component A); (B) 1 to 100 parts by weight of a styrene-based resin and/or a polycarbonate resin (component B); and (C) 1 to 100 parts by weight of an organic phosphorus compound represented by the following formula (1) (component C). (wherein X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2)) ALAr)n  (2) (wherein AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group, naphthyl group or anthryl group all of which may have a substituent. n is an integer of 1 to 3, and Ar can be bonded to any carbon atom contained in AL.)
    • 一种阻燃树脂组合物,其具有高阻燃性,优异的耐热性和物理性能,并且由植物来源的原料及其模制品获得。 阻燃树脂组合物包含:(A)100重量份聚乳酸和/或乳酸共聚物(组分A); (B)1〜100重量份苯乙烯类树脂和/或聚碳酸酯树脂(B成分); 和(C)1〜100重量份由下式(1)表示的有机磷化合物(组分C)。 (其中X 1和X 2相同或不同,各自为下述式(2)表示的芳香族取代烷基)。(A)(2)(其中,AL为支链或直链脂肪族烃基, 5个碳原子,Ar为可以具有取代基的苯基,萘基或蒽基,n为1〜3的整数,Ar可以与AL所含的碳原子键合)
    • 3. 发明授权
    • Flame retardant resin composition and molded article thereof
    • 阻燃树脂组合物及其模塑制品
    • US08859655B2
    • 2014-10-14
    • US13201929
    • 2010-02-12
    • Katsuhiro YamanakaFumitaka Kondo
    • Katsuhiro YamanakaFumitaka Kondo
    • C08K5/5357C09K21/12C08L67/04C07F9/6571C08L51/04C08L25/12C08L55/02C08L69/00
    • C09K21/12C07F9/657181C08K5/5357C08L25/12C08L51/04C08L55/02C08L67/04C08L69/00C08L2666/02
    • A flame retardant resin composition which has high flame retardancy, excellent heat resistance and physical properties and is obtained from a plant-derived raw material and a molded article thereof.The flame retardant resin composition comprises: (A) 100 parts by weight of a polylactic acid and/or a lactic acid copolymer (component A); (B) 1 to 100 parts by weight of a styrene-based resin and/or a polycarbonate resin (component B); and (C) 1 to 100 parts by weight of an organic phosphorus compound represented by the following formula (1) (component C). (wherein X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2)) ALAr)n  (2) (wherein AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group, naphthyl group or anthryl group all of which may have a substituent. n is an integer of 1 to 3, and Ar can be bonded to any carbon atom contained in AL.).
    • 一种阻燃树脂组合物,其具有高阻燃性,优异的耐热性和物理性能,并且由植物来源的原料及其模制品获得。 阻燃树脂组合物包含:(A)100重量份聚乳酸和/或乳酸共聚物(组分A); (B)1〜100重量份苯乙烯类树脂和/或聚碳酸酯树脂(B成分); 和(C)1〜100重量份由下式(1)表示的有机磷化合物(组分C)。 (其中X1和X2相同或不同,并且每个由下式(2)表示的芳族取代烷基)ALAr)n(2)(其中AL是具有1至5个碳原子的支链或直链脂族烃基, Ar是可以具有取代基的苯基,萘基或蒽基,n是1〜3的整数,Ar可以与AL中的任何碳原子结合)。
    • 7. 发明申请
    • FLAME RETARDANT RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
    • 阻燃树脂组合物及其制品
    • US20110092623A1
    • 2011-04-21
    • US12994791
    • 2009-05-26
    • Katsuhiro YamanakaFumitaka KondoKiyotsuna Toyohara
    • Katsuhiro YamanakaFumitaka KondoKiyotsuna Toyohara
    • C08K5/5357
    • C08K5/5357C07F9/657181C08L67/04
    • A flame retardant resin composition which has high flame retardancy and excellent physical properties and comprises a resin obtained from a plant-derived raw material and a molded article thereof.The flame retardant resin composition comprises: (A) 100 parts by weight of a resin component (component A) which contains at least 50 wt % of a resin (component A-1) obtained from a plant-derived raw material; and (B) 1 to 100 parts by weight of an organic phosphorus compound (component B) represented by the following formula (1). (in the above formula, X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2): ALAr)n  (2) in the above formula, AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group which may have a substituent, naphthyl group which may have a substituent or anthryl group which may have a substituent, n is an integer of 1 to 3, and Ar may be bonded to any carbon atom contained in AL.)
    • 阻燃性树脂组合物,其具有高阻燃性和优异的物理性质,并且含有由植物来源的原料得到的树脂及其成型体。 阻燃树脂组合物包含:(A)100重量份含有至少50重量%由植物来源的原料得到的树脂(A-1成分)的树脂成分(A成分) 和(B)1〜100重量份由下式(1)表示的有机磷化合物(B成分)。 (在上式中,X1和X2相同或不同,并且每个由下式(2)表示的芳族取代的烷基:上式中的n(2)中,AL是支链或 具有1至5个碳原子的直链脂族烃基,Ar是可以具有取代基的苯基,可以具有取代基的萘基或可以具有取代基的蒽基,n是1〜3的整数,Ar可以 结合到AL中包含的任何碳原子上。)
    • 8. 发明授权
    • Flame retardant resin composition and molded articles thereof
    • 阻燃树脂组合物及其模塑制品
    • US07786197B2
    • 2010-08-31
    • US11152372
    • 2005-06-15
    • Katsuhiro YamanakaYutaka Taketani
    • Katsuhiro YamanakaYutaka Taketani
    • C08K5/529
    • C08K5/527C08K5/49C08K5/5357C08L67/02
    • A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 30 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight. According to the present invention, there can be obtained a flame retardant polyester resin composition which contains substantially no halogen and has UL-94 V-2 flame retardancy or V-0 flame retardancy under favorable conditions as well as a molded article thereof.
    • 一种阻燃树脂组合物,其基本上由以下组成:(A)100重量份的包含至少60重量%的芳族聚酯树脂的树脂组分(组分A)的总量; (B)由以下通式(1)表示并具有0.7mgKOH / g以下的酸值的有机磷化合物(B-1成分)或由以下通式表示的有机磷化合物(B-2成分) 公式(2); (C)0〜50重量份阻燃改善树脂(C成分); 和(D)0〜200重量份的填料(D成分)及其成型体。 其中,当有机磷化合物为组分B-1时,组分B-1的量为1至100重量份,当有机磷化合物为组分B-2时,组分B-2用于 与B组分(B-3)的组合,B-2成分为5〜30重量份,B-3成分为0.01〜5重量份。 根据本发明,可以获得在有利条件下基本上不含卤素并具有UL-94V-2阻燃性或V-0阻燃性的阻燃性聚酯树脂组合物及其成型体。
    • 9. 发明授权
    • Flame-resistant resin composition and article molded therefrom
    • 耐火树脂组合物和由其模制的制品
    • US07169837B2
    • 2007-01-30
    • US10736682
    • 2003-12-17
    • Katsuhiro YamanakaKazuhiko KoyaYutaka Taketani
    • Katsuhiro YamanakaKazuhiko KoyaYutaka Taketani
    • C08K3/02C08K5/5357
    • C08K5/527C08K5/51C08K5/5357C08L51/04
    • A flame retardant resin composition comprising: (A) 100 parts by weight of a resin component (component a) containing at least 50% by weight of a high impact polystyrene, and (B) 1 to 50 parts by weight of a phosphorous-containing compound (component b) represented by the following general formula (I): wherein A and A′ are the same or different and represent —OR or -Q wherein R and Q represent an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or an aryl group having 6 to 15 carbon atoms. According to the present invention, there are provided a polystyrene resin composition containing substantially no halogen and having heat resistance, particularly a high heat distortion temperature under load, and an article from the composition.
    • 一种阻燃树脂组合物,其包含:(A)100重量份含有至少50重量%的高抗冲聚苯乙烯的树脂组分(组分a),和(B)1至50重量份的含磷 由以下通式(I)表示的化合物(组分b):其中A和A'相同或不同,表示-OR或-Q,其中R和Q表示碳原子数1〜12的烷基,环烷基 碳原子数5〜10,碳原子数7〜20的芳烷基或碳原子数6〜15的芳基。 根据本发明,提供了基本上不含卤素并具有耐热性,特别是负载下的高热变形温度的聚苯乙烯树脂组合物和来自该组合物的制品。