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    • 1. 发明授权
    • Flame retardant resin composition and molded articles thereof
    • 阻燃树脂组合物及其模塑制品
    • US07786197B2
    • 2010-08-31
    • US11152372
    • 2005-06-15
    • Katsuhiro YamanakaYutaka Taketani
    • Katsuhiro YamanakaYutaka Taketani
    • C08K5/529
    • C08K5/527C08K5/49C08K5/5357C08L67/02
    • A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 30 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight. According to the present invention, there can be obtained a flame retardant polyester resin composition which contains substantially no halogen and has UL-94 V-2 flame retardancy or V-0 flame retardancy under favorable conditions as well as a molded article thereof.
    • 一种阻燃树脂组合物,其基本上由以下组成:(A)100重量份的包含至少60重量%的芳族聚酯树脂的树脂组分(组分A)的总量; (B)由以下通式(1)表示并具有0.7mgKOH / g以下的酸值的有机磷化合物(B-1成分)或由以下通式表示的有机磷化合物(B-2成分) 公式(2); (C)0〜50重量份阻燃改善树脂(C成分); 和(D)0〜200重量份的填料(D成分)及其成型体。 其中,当有机磷化合物为组分B-1时,组分B-1的量为1至100重量份,当有机磷化合物为组分B-2时,组分B-2用于 与B组分(B-3)的组合,B-2成分为5〜30重量份,B-3成分为0.01〜5重量份。 根据本发明,可以获得在有利条件下基本上不含卤素并具有UL-94V-2阻燃性或V-0阻燃性的阻燃性聚酯树脂组合物及其成型体。
    • 2. 发明授权
    • Flame-resistant resin composition and article molded therefrom
    • 耐火树脂组合物和由其模制的制品
    • US07169837B2
    • 2007-01-30
    • US10736682
    • 2003-12-17
    • Katsuhiro YamanakaKazuhiko KoyaYutaka Taketani
    • Katsuhiro YamanakaKazuhiko KoyaYutaka Taketani
    • C08K3/02C08K5/5357
    • C08K5/527C08K5/51C08K5/5357C08L51/04
    • A flame retardant resin composition comprising: (A) 100 parts by weight of a resin component (component a) containing at least 50% by weight of a high impact polystyrene, and (B) 1 to 50 parts by weight of a phosphorous-containing compound (component b) represented by the following general formula (I): wherein A and A′ are the same or different and represent —OR or -Q wherein R and Q represent an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or an aryl group having 6 to 15 carbon atoms. According to the present invention, there are provided a polystyrene resin composition containing substantially no halogen and having heat resistance, particularly a high heat distortion temperature under load, and an article from the composition.
    • 一种阻燃树脂组合物,其包含:(A)100重量份含有至少50重量%的高抗冲聚苯乙烯的树脂组分(组分a),和(B)1至50重量份的含磷 由以下通式(I)表示的化合物(组分b):其中A和A'相同或不同,表示-OR或-Q,其中R和Q表示碳原子数1〜12的烷基,环烷基 碳原子数5〜10,碳原子数7〜20的芳烷基或碳原子数6〜15的芳基。 根据本发明,提供了基本上不含卤素并具有耐热性,特别是负载下的高热变形温度的聚苯乙烯树脂组合物和来自该组合物的制品。
    • 3. 发明申请
    • Flame-retardant styrene type resin composition and molded product therefrom
    • 阻燃型苯乙烯类树脂组合物及其成型品
    • US20070112108A1
    • 2007-05-17
    • US10582108
    • 2003-12-10
    • Katsuhiro YamanakaKoichi ImamuraSeiichi TanabeYutaka Taketani
    • Katsuhiro YamanakaKoichi ImamuraSeiichi TanabeYutaka Taketani
    • C08K5/49
    • C08L25/06C07F9/657181C08K5/5357C08L71/12C09K21/12C08L25/02C08L2666/22C08L2666/04
    • It is an object of the present invention to provide a styrene type resin composition excellent in thermal stability, hue, fluidity, and heat resistance, and also having the flame retardant performance, and a molded product excellent in outward appearance, formed therefrom. The present invention provides a flame retardant styrene type resin composition comprising (A) a styrene type resin (component A) in an amount of 100 parts by weight, (B) a polyphenylene ether type resin (component B) in an amount of 0 to 100 parts by weight, and (C) an organophosphorus compound (component C) represented by the following formula (1) in an amount of 1 to 100 parts by weight, characterized in that the organophosphorus compound (component C) satisfies: (i) the weight loss residue on heating at 500° C. is 10% or less; (ii) the HPLC purity is 90% or more, and (iii) the acid value is 0.5 mg KOH/g or less (where in the formula, Ar1 and Ar2 may be the same or different, and is a phenyl group which may have a substituent.)
    • 本发明的目的是提供热稳定性,色调,流动性和耐热性优异并且具有阻燃性能的苯乙烯类树脂组合物,以及由其形成的外观优异的模塑制品。 本发明提供一种阻燃苯乙烯类树脂组合物,其包含(A)100重量份的苯乙烯类树脂(组分A),(B)聚苯醚型树脂(组分B),其量为0至 100重量份,和(C)由下式(1)表示的有机磷化合物(C成分)的量为1〜100重量份,其特征在于有机磷化合物(C成分)满足:(i) 在500℃下加热时的减重残渣为10%以下; (ii)HPLC纯度为90%以上,(iii)酸值为0.5mgKOH / g以下(式中,Ar 1,Ar 2, SUP>可以相同或不同,并且是可以具有取代基的苯基)。
    • 4. 发明授权
    • Flame-retardant resin composition and molded article therefrom
    • 阻燃性树脂组合物及其成型体
    • US07087667B2
    • 2006-08-08
    • US10476390
    • 2002-05-14
    • Katsuhiro YamanakaYutaka Taketani
    • Katsuhiro YamanakaYutaka Taketani
    • C08K5/526C08K5/5333
    • C08K5/527C08K5/49C08K5/5357C08L67/02
    • A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 3.0 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight. According to the present invention, there can be obtained a flame retardant polyester resin composition which contains substantially no halogen and has UL-94 V-2 flame retardancy or V-0 flame retardancy under favorable conditions as well as a molded article thereof.
    • 一种阻燃树脂组合物,其基本上由以下组成:(A)100重量份的包含至少60重量%的芳族聚酯树脂的树脂组分(组分A)的总量; (B)由以下通式(1)表示并具有0.7mgKOH / g以下的酸值的有机磷化合物(B-1成分)或由以下通式表示的有机磷化合物(B-2成分) 公式(2); (C)0〜50重量份阻燃改善树脂(C成分); 和(D)0〜200重量份的填料(D成分)及其成型体。 其中,当有机磷化合物为组分B-1时,组分B-1的量为1至100重量份,当有机磷化合物为组分B-2时,组分B-2用于 与B组分(B-3)的组合,B-2成分为5〜3.0重量份,B-3成分为0.01〜5重量份。 根据本发明,可以获得在有利条件下基本上不含卤素并具有UL-94V-2阻燃性或V-0阻燃性的阻燃性聚酯树脂组合物及其成型体。
    • 5. 发明申请
    • Flame retardant resin composition and molded articles thereof
    • 阻燃树脂组合物及其模塑制品
    • US20050256293A1
    • 2005-11-17
    • US11152372
    • 2005-06-15
    • Katsuhiro YamanakaYutaka Taketani
    • Katsuhiro YamanakaYutaka Taketani
    • C08K5/49C08K5/527C08L1/00
    • C08K5/527C08K5/49C08K5/5357C08L67/02
    • A flame retardant resin composition consisting essentially of: (A) 100 parts by weight of the total of resin components (components A) which include at least 60 wt % of an aromatic polyester resin; (B) an organic phosphorus compound (component B-1) represented by the following general formula (1) and having an acid value of 0.7 mgKOH/g or less or an organic phosphorus compound (component B-2) represented by the following general formula (2); (C) 0 to 50 parts by weight of a flame retardancy improving resin (component C); and (D) 0 to 200 parts by weight of a filler (component D), and a molded article thereof. Wherein, when the organic phosphorus compound is the component B-1, the amount of the component B-1 is 1 to 100 parts by weight and when the organic phosphorus compound is the component B-2, the component B-2 is used in combination with a biscumyl compound (component B-3), the amount of the component B-2 is 5 to 30 parts by weight, and the amount of the component B-3 is 0.01 to 5 parts by weight. According to the present invention, there can be obtained a flame retardant polyester resin composition which contains substantially no halogen and has UL-94 V-2 flame retardancy or V-0 flame retardancy under favorable conditions as well as a molded article thereof.
    • 一种阻燃树脂组合物,其基本上由以下组成:(A)100重量份的包含至少60重量%的芳族聚酯树脂的树脂组分(组分A)的总量; (B)由以下通式(1)表示并具有0.7mgKOH / g以下的酸值的有机磷化合物(B-1成分)或由以下通式表示的有机磷化合物(B-2成分) 公式(2); (C)0〜50重量份阻燃改善树脂(C成分); 和(D)0〜200重量份的填料(D成分)及其成型体。 其中,当有机磷化合物为组分B-1时,组分B-1的量为1至100重量份,当有机磷化合物为组分B-2时,组分B-2用于 与B组分(B-3)的组合,B-2成分为5〜30重量份,B-3成分为0.01〜5重量份。 根据本发明,可以获得在有利条件下基本上不含卤素并具有UL-94V-2阻燃性或V-0阻燃性的阻燃性聚酯树脂组合物及其成型体。