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1. 发明授权

US07186768B2 Silane-modified oxidic or siliceous filler, process for its production and its use 有权
标题翻译：硅烷改性的氧化或硅质填料，其生产和使用的过程
公开(公告)号：US07186768B2
公开(公告)日：2007-03-06
申请号：US10423901
申请日：2003-04-25
申请人： Karsten Korth , Kurt Eichenauer , Reimund Pieter , Oliver Klockmann , Jürgen Heidlas , Martin Ober , Rudolf Zobel
发明人： Karsten Korth , Kurt Eichenauer , Reimund Pieter , Oliver Klockmann , Jürgen Heidlas , Martin Ober , Rudolf Zobel
IPC分类号： C08K3/18
CPC分类号： C08K9/06 , A61K8/25 , A61K8/585 , A61K2800/412 , A61K2800/612 , A61Q11/00 , A61Q19/00 , C01P2004/54 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C08K3/013 , C08K3/22 , C08K3/34 , C09C1/3036 , C09C1/3081 , C09C1/3684 , C09C3/12 , C09D7/62 , C09D7/69 , C09D11/03 , C08L21/00
摘要： Silane-modified oxidic or siliceous filler with a bead fraction below 75 μm of less than 15 wt. % and a median particle size distribution between of 150 to 500 μm, which is produced by the reaction of at least one microbeaded or microgranular, oxidic or siliceous filler in a compressed gas with at least one silane. The silane-modified oxidic or siliceous fillers are used in rubber compounds.
摘要翻译：硅烷改性的氧化或硅质填料，珠粒分数低于75μm，小于15wt。％和通过至少一种微珠或微粒，氧化或硅质填料在压缩气体中与至少一种硅烷反应而产生的150至500μm之间的中值粒度分布。硅烷改性的氧化或硅质填料用于橡胶混合物中。

2. 发明授权

US07423165B2 Organosilicon compounds 有权
标题翻译：有机硅化合物
公开(公告)号：US07423165B2
公开(公告)日：2008-09-09
申请号：US10872177
申请日：2004-06-18
申请人： Karsten Korth , Philipp Albert , Reimund Pieter , Oliver Klockmann , Andre Hasse , Ulrich Deschler , Susann Witzsche , Inge Kiefer
发明人： Karsten Korth , Philipp Albert , Reimund Pieter , Oliver Klockmann , Andre Hasse , Ulrich Deschler , Susann Witzsche , Inge Kiefer
IPC分类号： C07F7/10 , C08G77/22
CPC分类号： C08K5/548 , C07F7/1804 , C08L21/00
摘要： Organosilicon compounds of the general formula I are produced by catalytically reacting silanes of the general formula II with alcohols of the general formula R′—OH, with the elimination of RIVOH, wherein the molar ratio of R—OH to RIVOH— groups is at least 1 and RIVOH is removed continuously or discontinuously from the reaction mixture. The organosilicon compounds may be used as coupling agents in filler-reinforced rubber mixtures.
摘要翻译：通式I的有机硅化合物是通过将通式II的硅烷与通式R'-OH的醇催化反应制备的，其中R≠OH的消除，其中R -OH至RⅣOH基团为至少1个，并且连续或不连续地从反应混合物中除去R 4 OH。有机硅化合物可用作填料增强橡胶混合物中的偶联剂。

3. 发明申请

US20060160935A1 Rubber mixtures 有权
标题翻译：橡胶混合物
公开(公告)号：US20060160935A1
公开(公告)日：2006-07-20
申请号：US11300374
申请日：2005-12-15
申请人： Andre Hasse , Philipp Albert , Oliver Klockmann , Karsten Korth , Reimund Pieter
发明人： Andre Hasse , Philipp Albert , Oliver Klockmann , Karsten Korth , Reimund Pieter
IPC分类号： C08K5/24
CPC分类号： C08K5/5419 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： The invention is directed to rubber mixtures comprising rubber, fillers, optionally further rubber auxiliaries and at least one organosilane of the general formula I: R1R2R3SiR4—SH (I) wherein: R1 is methyl or ethyl, R2 is methoxy, ethoxy or —O—(Y—O)m—X where Y=a branched or unbranched, saturated or unsaturated divalent hydrocarbon group, X is a C1- to C9-alkyl group and m=1-40, R3 is methyl, ethyl or R2, and R4 is a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C12 hydrocarbon group. The rubber mixtures according to the invention are prepared by mixing rubber, filler, optionally further rubber auxiliaries and at least one organosilane of the general formula I. The rubber mixtures can be used for the production of shaped articles.
摘要翻译：本发明涉及包含橡胶，填料，任选的其它橡胶助剂和至少一种通式I的有机硅烷的橡胶混合物：<？in-line-formula description =“In-Line Formulas”end =“lead”→> R S（1） S S S S < 其中：R 1是甲基或乙基，R 2是甲氧基，乙氧基或-O-（YO）

4. 发明授权

US08013178B2 Mercaptosilanes and derivatives thereof 有权
标题翻译：巯基硅烷及其衍生物
公开(公告)号：US08013178B2
公开(公告)日：2011-09-06
申请号：US11337205
申请日：2006-01-20
申请人： Oliver Klockmann , Philipp Albert , Andre Hasse , Karsten Korth , Reimund Pieter
发明人： Oliver Klockmann , Philipp Albert , Andre Hasse , Karsten Korth , Reimund Pieter
IPC分类号： C07F7/04 , C07F7/08
CPC分类号： C07F7/1804 , C08K5/548 , Y10T428/139 , C08L21/00
摘要： Mercaptosilanes are disclosed of the formula I wherein R1 is an alkyl polyether group —O—(R5—O)m—R6. They are prepared by a procedure in which a silane of the formula II is subjected to a catalyzed reaction with an alkyl polyether R1—H, R7—OH being split off, the molar ratio of the alkyl polyethers R1—H to the silane of the formula II is at least 0.5 and R7—OH is separated off from the reaction mixture continuously or discontinuously. They can be used in shaped articles.
摘要翻译：公开了通式I的巯基硅烷，其中R 1是烷基聚醚基-O-（R 5 -O）m -R 6。它们通过其中将式II的硅烷与烷基聚醚R1-H，R7-OH分离进行催化反应的方法制备，烷基聚醚R1-H与硅烷的摩尔比为式II至少为0.5，R7-OH连续或不连续地从反应混合物中分离出来。它们可用于成型制品。

5. 发明授权

US07384997B2 Rubber mixtures 有权
标题翻译：橡胶混合物
公开(公告)号：US07384997B2
公开(公告)日：2008-06-10
申请号：US11300374
申请日：2005-12-15
申请人： Andre Hasse , Philipp Albert , Oliver Klockmann , Karsten Korth , Reimund Pieter
发明人： Andre Hasse , Philipp Albert , Oliver Klockmann , Karsten Korth , Reimund Pieter
IPC分类号： C08K5/24
CPC分类号： C08K5/5419 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L21/00 , C08L2666/08
摘要： The invention is directed to rubber mixtures comprising rubber, fillers, optionally further rubber auxiliaries and at least one organosilane of the general formula I: R1R2R3SiR4—SH (I) wherein: R1 is methyl or ethyl, R2 is methoxy, ethoxy or —O—(Y—O)m—X where Y=a branched or unbranched, saturated or unsaturated divalent hydrocarbon group, X is a C1- to C9-alkyl group and m=1-40, R3 is methyl, ethyl or R2, and R4 is a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C12 hydrocarbon group. The rubber mixtures according to the invention are prepared by mixing rubber, filler, optionally further rubber auxiliaries and at least one organosilane of the general formula I. The rubber mixtures can be used for the production of shaped articles.
摘要翻译：本发明涉及包含橡胶，填料，任选的其它橡胶助剂和至少一种通式I的有机硅烷的橡胶混合物：<？in-line-formula description =“In-Line Formulas”end =“lead”→> R S（1） S S S S < 其中：R 1是甲基或乙基，R 2是甲氧基，乙氧基或-O-（YO）

6. 发明申请

US20060161015A1 Mercaptosilanes 有权
标题翻译：巯基吡咯烷酮
公开(公告)号：US20060161015A1
公开(公告)日：2006-07-20
申请号：US11337205
申请日：2006-01-20
申请人： Oliver Klockmann , Philipp Albert , Andre Hasse , Karsten Korth , Reimund Pieter
发明人： Oliver Klockmann , Philipp Albert , Andre Hasse , Karsten Korth , Reimund Pieter
IPC分类号： C07F7/04 , C07F7/08
CPC分类号： C07F7/1804 , C08K5/548 , Y10T428/139 , C08L21/00
摘要： Mercaptosilanes are disclosed of the formula I wherein R1 is an alkyl polyether group —O—(R5—O)m—R6. They are prepared by a procedure in which a silane of the formula II is subjected to a catalyzed reaction with an alkyl polyether R1—H, R7—OH being split off, the molar ratio of the alkyl polyethers R1—H to the silane of the formula II is at least 0.5 and R7—OH is separated off from the reaction mixture continuously or discontinuously. They can be used in shaped articles.
摘要翻译：公开了通式I的巯基硅烷，其中R 1是烷基聚醚基-O-（R 5 -O-O）m -R > 6 。它们通过其中使式II的硅烷与烷基聚醚R 1 -H，R 7 -OH被分解的催化反应的方法制备，烷基聚醚R 1 -H与式II的硅烷的摩尔比为至少0.5，并且从反应混合物中连续分离出R 7 -OH 或不连续地。它们可用于成型制品。

7. 发明授权

US07462221B2 Process and device for the extraction of substances from silane-modified fillers 有权
标题翻译：从硅烷改性填料中提取物质的方法和装置
公开(公告)号：US07462221B2
公开(公告)日：2008-12-09
申请号：US11157919
申请日：2005-06-22
申请人： Karsten Korth , Jürgen Heidlas , Kurt Stork , Rudolf Zobel
发明人： Karsten Korth , Jürgen Heidlas , Kurt Stork , Rudolf Zobel
IPC分类号： B01D53/02
CPC分类号： B01D11/0203 , B01D11/0219 , B01D11/0288 , B01D11/0292
摘要： Process for the extraction of substances from at least one silane-modified oxidic or silicatic filler, wherein at least one gas compressed by means of pressure and/or temperature is employed as the extraction agent and the compressed gas is led in the radial direction through the filler in the pressure container and/or the substances extracted from the silane-modified filler are removed from the compressed gas with a suitable sorbent. A device for carrying out the process is furthermore described, wherein this comprises at least one pressure container having at least one internal container, sieve or insert for accommodation of the fillers which is permeable to gas and at least one gas feed and gas removal in the bulk bed of filler, and has a radially designed gas feed or gas removal from the bulk bed of filler.
摘要翻译：用于从至少一种硅烷改性的氧化或硅填料中提取物质的方法，其中使用至少一种通过压力和/或温度压缩的气体作为萃取剂，压缩气体沿径向被引导通过用合适的吸附剂从压缩气体中除去压力容器中的填料和/或从硅烷改性填料中提取的物质。进一步描述了用于执行该方法的装置，其中包括至少一个压力容器，其具有至少一个内部容器，筛子或插入件，用于容纳可渗透气体的填料和至少一种气体进料和气体去除填料填充床，并且具有径向设计的气体进料或从填料填料床排出气体。

8. 发明申请

US20130012691A1 Process for Preparing Silicon-Containing Azodicarbamides 有权
标题翻译：制备含硅偶氮二酰胺的方法
公开(公告)号：US20130012691A1
公开(公告)日：2013-01-10
申请号：US13580780
申请日：2011-03-15
申请人： Karsten Korth , Julia Keck , Susann Witzsche , Oliver Klockmann , Jaroslaw Monkiewicz , Christian Springer
发明人： Karsten Korth , Julia Keck , Susann Witzsche , Oliver Klockmann , Jaroslaw Monkiewicz , Christian Springer
IPC分类号： C07F7/18
CPC分类号： C07F7/1892
摘要： The invention relates to a process for preparing silicon-containing azodicarbamides of the general formula (I) (R1)3-a(R2)aSi—RI—NH—C(O)—N═N—C(O)—NH—RI—Si(R1)3-a(R2)a (I), by reaction of azobiscarboxy compounds of the general formula II R3—X1—C(O)—N═N—C(O)—X1—R4 (II) with aminosilanes of the general formula III (R1)3-a(R2)aSi—RI—NH2 (III).
摘要翻译：本发明涉及制备通式（I）（R1）3-a（R2）aSi-RI-NH-C（O）-N = N-C（O）-NH-的硅氧偶氮二酰胺的方法，通过使通式II的R 3 -X 1 -C（O）-N = N-C（O）-X 1 -R 4（II）的偶氮二羧基化合物反应，得到RI-Si（R 1）3-a（R 2）a ）与通式III（R1）3-a（R2）aSi-RI-NH2（III）的氨基硅烷反应。

9. 发明授权

US07777063B2 Organosilicon compounds their preparation and their use 有权
标题翻译：有机硅化合物的制备及其用途
公开(公告)号：US07777063B2
公开(公告)日：2010-08-17
申请号：US11503932
申请日：2006-08-15
申请人： Karsten Korth , Andre Hasse , Susann Witzsche , Oliver Klockmann , Philipp Albert
发明人： Karsten Korth , Andre Hasse , Susann Witzsche , Oliver Klockmann , Philipp Albert
IPC分类号： C07F7/00 , C07F9/02
CPC分类号： C08K5/549 , C07F7/1804 , C08K5/548 , C08K9/06 , C08K9/12 , C08L21/00
摘要： The invention relates to organosilicon compounds, and to the ways in which they can be made and used.
摘要翻译：本发明涉及有机硅化合物，以及它们可以制备和使用的方式。

10. 发明授权

US07705076B2 Rubber mixtures 失效
标题翻译：橡胶混合物
公开(公告)号：US07705076B2
公开(公告)日：2010-04-27
申请号：US12308047
申请日：2007-05-10
申请人： Karsten Korth , Andre Hasse , Dirk Laur , Ingo Kiefer , Oliver Klockmann , Philipp Albert , Manuel Friedel
发明人： Karsten Korth , Andre Hasse , Dirk Laur , Ingo Kiefer , Oliver Klockmann , Philipp Albert , Manuel Friedel
IPC分类号： C08K5/54
CPC分类号： B60C1/0016 , C08K3/36 , C08K5/5406 , C08K5/5419 , C08L21/00
摘要： The invention relates to rubber mixtures, comprising: (A) at least one rubber, (B) at least one oxidic filler and (C) at least one (haloorganyl)alkylpolyethersilane of the general formula (X)(X′)(X″)Si—RI-Hal. The rubber mixtures can be used for production of mouldings.
摘要翻译：本发明涉及橡胶混合物，其包含：（A）至少一种橡胶，（B）至少一种氧化物填料和（C）至少一种通式（X）（X'）（X“）的（卤代有机基）烷基聚醚硅烷）Si-RI-Hal。橡胶混合物可用于生产模制品。

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