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1. 发明授权

US08557025B2 Generating oxygen in hospitals 失效
标题翻译：在医院生产氧气
公开(公告)号：US08557025B2
公开(公告)日：2013-10-15
申请号：US13048114
申请日：2011-03-15
申请人： Matthias Grahl , Philippe Sage , Alfred Bolkart , Paul Leitgeb
发明人： Matthias Grahl , Philippe Sage , Alfred Bolkart , Paul Leitgeb
IPC分类号： B01D53/047
CPC分类号： B01D53/0476 , A61M16/10 , A61M16/101 , B01D2259/4541
摘要： An arrangement for generating oxygen in a facility is described, which arrangement has at least one unit for generating medical air (V, R), a vacuum system (VS), and a PSA unit (A), which serves to generate an oxygen product stream. According to the invention, the PSA unit (A) and the vacuum system (VS) are interconnected in such a way that the adsorber or adsorbers of the PSA unit (A) can be regenerated by means of the vacuum system (VS), and/or the unit for generating medical air (V, R) is connected to the PSA unit (A) in such a way that at least a subsidiary stream (2) of the generated medical air is delivered as feed gas to the PSA unit (A).
摘要翻译：描述了一种用于在设施中产生氧气的装置，该装置具有用于产生医用空气（V，R），真空系统（VS）和PSA单元（A））的至少一个单元，其用于产生氧气产物流。根据本发明，PSA单元（A）和真空系统（VS）以使得PSA单元（A）的吸附器或吸附器可以通过真空系统（VS）再生的方式相互连接，以及 /或用于产生医用空气的单元（V，R）以至少所生成的医用空气的辅助流（2）作为进料气体输送到PSA单元的方式连接到PSA单元（A）一个）。

2. 发明申请

US20220054976A1 METHOD AND SYSTEM FOR PRE-PURIFICATION OF A FEED GAS STREAM 有权
公开(公告)号：US20220054976A1
公开(公告)日：2022-02-24
申请号：US17361395
申请日：2021-06-29
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
IPC分类号： B01D53/86 , B01D53/04 , B01D53/26 , B01D53/28 , B01J23/889 , B01J20/08 , B01J20/18
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

3. 发明申请

US20130206004A1 METHOD AND DEVICE FOR VACUUM PRESSURE SWING ADSORPTION WITH TEMPORARY STORAGE 有权
标题翻译：用于真空压力的方法和装置用临时储存吸附
公开(公告)号：US20130206004A1
公开(公告)日：2013-08-15
申请号：US13879033
申请日：2011-10-05
申请人： Matthias Grahl
发明人： Matthias Grahl
IPC分类号： B01D53/047
CPC分类号： B01D53/0476 , B01D53/053 , B01D2256/12 , B01D2259/402 , B01D2259/4533 , C01B13/0259
摘要： Adsorptive decomposition of a gas mixture is performed by vacuum pressure swing adsorption. The gas mixture is condensed to the adsorption pressure by means of at least one condenser prior to being fed into the vacuum pressure swing adsorption process. Regeneration of the adsorber(s) is carried out by means of at least one vacuum pump. The condensed gas mixture (1, 5, 6) is at least periodically and/or at least partially temporarily stored (S1) and/or fed to a consumer at those times when no gas mixture is being fed to the vacuum pressure swing adsorption process; and/or at least one of the vacuum pumps (P) that is not required for the regeneration is used at least occasionally for another application at those times when no regeneration of the adsorber or an adsorber (A, A′) is being carried out.
摘要翻译：通过真空变压吸附进行气体混合物的吸附分解。在进入真空变压吸附过程之前，通过至少一个冷凝器将气体混合物冷凝成吸附压力。吸附器的再生通过至少一个真空泵进行。冷凝的气体混合物（1,5,6）至少周期性地和/或至少部分地暂时储存（S1）和/或在没有气体混合物进料到真空变压吸附过程的那些时间内供给消费者 ; 在不进行吸附塔或吸附剂（A，A'）的再生的时候，至少偶尔使用不需要再生的真空泵（P）和/或至少一个真空泵（P）。

4. 发明申请

US20230042248A1 METHOD AND SYSTEM FOR PRE-PURIFICATION OF A FEED GAS STREAM 有权
公开(公告)号：US20230042248A1
公开(公告)日：2023-02-09
申请号：US17959360
申请日：2022-10-04
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
IPC分类号： B01D53/86 , B01D53/04 , B01D53/26 , B01D53/28 , B01J20/08 , B01J20/18 , B01J23/889
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

5. 发明授权

US08961653B2 Method and device for vacuum pressure swing adsorption with temporary storage 有权
标题翻译：用于临时储存的真空变压吸附的方法和装置
公开(公告)号：US08961653B2
公开(公告)日：2015-02-24
申请号：US13879033
申请日：2011-10-05
申请人： Matthias Grahl
发明人： Matthias Grahl
IPC分类号： B01D53/047 , B01D53/053 , C01B13/02
CPC分类号： B01D53/0476 , B01D53/053 , B01D2256/12 , B01D2259/402 , B01D2259/4533 , C01B13/0259
摘要： Adsorptive decomposition of a gas mixture is performed by vacuum pressure swing adsorption. The gas mixture is condensed to the adsorption pressure by means of at least one condenser prior to being fed into the vacuum pressure swing adsorption process. Regeneration of the adsorber(s) is carried out by means of at least one vacuum pump. The condensed gas mixture (1, 5, 6) is at least periodically and/or at least partially temporarily stored (S1) and/or fed to a consumer at those times when no gas mixture is being fed to the vacuum pressure swing adsorption process; and/or at least one of the vacuum pumps (P) that is not required for the regeneration is used at least occasionally for another application at those times when no regeneration of the adsorber or an adsorber (A, A′) is being carried out.
摘要翻译：通过真空变压吸附进行气体混合物的吸附分解。在进入真空变压吸附过程之前，通过至少一个冷凝器将气体混合物冷凝成吸附压力。通过至少一个真空泵进行吸附器的再生。冷凝气体混合物（1,5,6）至少周期性地和/或至少部分地暂时储存（S1）和/或在没有气体混合物被供给到真空变压吸附过程的那些时间内被供给到消费者 ; 在不进行吸附塔或吸附剂（A，A'）的再生的时候，至少偶尔使用不需要再生的真空泵（P）和/或至少一个真空泵（P）。

6. 发明授权

US11826703B2 Method and system for pre-purification of a feed gas stream 有权
公开(公告)号：US11826703B2
公开(公告)日：2023-11-28
申请号：US17959360
申请日：2022-10-04
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
IPC分类号： B01D53/04 , B01D53/26 , B01D53/28 , B01D53/86 , B01J20/08 , B01J20/18 , B01J23/889
CPC分类号： B01D53/869 , B01D53/0407 , B01D53/261 , B01D53/28 , B01D53/864 , B01D53/8671 , B01J20/08 , B01J20/18 , B01J23/8892 , B01D2253/104 , B01D2253/108 , B01D2253/25 , B01D2255/2073 , B01D2255/20761 , B01D2255/40 , B01D2255/9022 , B01D2255/9025 , B01D2255/9027 , B01D2257/108 , B01D2257/502 , B01D2257/504 , B01D2257/80
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

7. 发明公开

US20230285898A1 SYSTEM AND METHOD FOR PRE-PURIFICATION OF A FEED GAS STREAM 审中-公开
公开(公告)号：US20230285898A1
公开(公告)日：2023-09-14
申请号：US18321067
申请日：2023-05-22
申请人： Ralph J. Mancini , Cem E. Celik , Arthur C. Selover , Sesha Hari Vemuri , Thomas A. McNamara , Matthias Grahl , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Arthur C. Selover , Sesha Hari Vemuri , Thomas A. McNamara , Matthias Grahl , Helko Schneider
IPC分类号： B01D53/86 , B01D53/26 , B01D53/04 , B01D53/28 , B01J23/889 , B01J35/02 , B01J20/08 , B01J20/16
CPC分类号： B01D53/869 , B01D53/864 , B01D53/8671 , B01D53/261 , B01D53/0407 , B01D53/28 , B01J23/8892 , B01J35/026 , B01J20/08 , B01J20/16 , B01D2257/108 , B01D2257/502 , B01D2257/504 , B01D2255/40 , B01D2255/20761 , B01D2255/2073 , B01D2253/108 , B01D2253/104 , B01D2257/80
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. The separate layers of hopcalite catalyst preferably have different volumes and/or different average particle sizes of the hopcalite materials.

8. 发明公开

US20230249130A1 METHOD AND SYSTEM FOR PRE-PURIFICATION OF A FEED AIR STREAM 审中-公开
公开(公告)号：US20230249130A1
公开(公告)日：2023-08-10
申请号：US18304921
申请日：2023-04-21
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
IPC分类号： B01D53/86 , B01D53/04 , B01D53/26 , B01D53/28 , B01J20/08 , B01J20/18 , B01J23/889
CPC分类号： B01D53/869 , B01D53/28 , B01D53/261 , B01D53/0407 , B01D53/864 , B01D53/8671 , B01J20/08 , B01J20/18 , B01J23/8892 , B01D2253/25 , B01D2253/104 , B01D2253/108 , B01D2255/40 , B01D2255/2073 , B01D2255/9022 , B01D2255/9025 , B01D2255/9027 , B01D2255/20761 , B01D2257/80 , B01D2257/108 , B01D2257/502 , B01D2257/504
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

9. 发明公开

US20240252976A1 METHOD FOR PRE-PURIFICATION OF A FEED GAS STREAM 审中-公开
公开(公告)号：US20240252976A1
公开(公告)日：2024-08-01
申请号：US17264445
申请日：2020-12-10
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
IPC分类号： B01D53/047
CPC分类号： B01D53/047 , B01D2253/104 , B01D2255/1023 , B01D2257/504 , B01D2257/80
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. Alternatively, the pre-purification systems and methods employ a hopcalite catalyst layer and a noble metal catalyst layer separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layer.

10. 发明授权

US11850553B2 System for pre-purification of a feed gas stream 有权
公开(公告)号：US11850553B2
公开(公告)日：2023-12-26
申请号：US17264457
申请日：2021-01-29
申请人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
发明人： Ralph J. Mancini , Cem E. Celik , Matthias Grahl , Arthur C. Selover , Sesha Hari Vemuri , Helko Schneider
IPC分类号： B01D53/86 , B01D53/04 , B01D53/047 , B01D53/26 , B01D53/28
CPC分类号： B01D53/869 , B01D53/047 , B01D53/0462 , B01D53/261 , B01D53/28 , B01D53/864 , B01D53/8671 , B01D2253/104 , B01D2253/108 , B01D2255/1023 , B01D2255/2073 , B01D2255/20761 , B01D2255/40 , B01D2255/9025 , B01D2257/108 , B01D2257/502 , B01D2257/504 , B01D2257/80 , B01D2259/404 , B01D2259/4061 , B01D2259/414
摘要： A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. Alternatively, the pre-purification systems and methods employ a hopcalite catalyst layer and a noble metal catalyst layer separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layer.

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