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1. 发明授权

US4895767A Transparent article and process for preparation thereof 失效
标题翻译：透明制品及其制备方法
公开(公告)号：US4895767A
公开(公告)日：1990-01-23
申请号：US208845
申请日：1988-06-17
申请人： Kaoru Mori , Naoki Shimoyama , Takashi Taniquchi
发明人： Kaoru Mori , Naoki Shimoyama , Takashi Taniquchi
IPC分类号： C09D163/00 , C09D183/04 , G02B1/10
CPC分类号： G02B1/105 , C09D163/00 , C09D183/04 , Y10T428/256 , Y10T428/31507 , Y10T428/31511 , Y10T428/31515 , Y10T428/31518 , Y10T428/31612 , Y10T428/31663
摘要： A transparent article comprising on the surface of a transparent substrate a cured transparent coating film composed of a composition comprising 100 parts by weight of an organic silicon compound represented by the following general formula (I) and/or a hydrolysis product thereof:R.sup.1.sub.a R.sup.2.sub.b Si(OR.sup.3).sub.4-a-b (I)wherein R.sup.1 and R.sup.2 each stand for an alkyl group, an alkenyl group, an aryl group or a hydrocarbon group having a halogen group, an epoxy group, a glycidoxy group, an amino group, a mercapto group, a methacryloxy group or a cyano group, R.sup.3 stands for an alkyl group having 1 to 8 carbon atoms, an alkoxyalkyl group, an acyl group or a phenyl group, and a and b are 0 or 1,10 to 300 parts by weight of a polyfunctional epoxy resin having an aromatic ring and/or an aliphatic ring and 25 to 800 parts by weight of antimony oxide fine particles having an average particle size of 1 to 200 m.mu..
摘要翻译：一种透明制品，在透明基材的表面上包含固化的透明涂膜，所述固化的透明涂膜由包含100重量份由下列通式（I）表示的有机硅化合物和/或其水解产物的组合物组成：R1aR2bSi（OR3））4-ab（I）其中R 1和R 2各自代表烷基，烯基，芳基或具有卤素基团，环氧基，缩水甘油氧基，氨基，巯基，甲基丙烯酰氧基或氰基，R3表示碳原子数1〜8的烷基，烷氧基烷基，酰基或苯基，a和b分别为0或1〜10〜300重量份具有芳香环和/或脂肪族环的多官能环氧树脂和25〜800重量份平均粒径为1〜200μm的氧化锑微粒。

2. 发明申请

US20060012750A1 Monomer composition and polysmers and ophthalmic lenses in which it is used 审中-公开
标题翻译：单体组合物和使用它的聚合物和眼科镜片
公开(公告)号：US20060012750A1
公开(公告)日：2006-01-19
申请号：US10363162
申请日：2001-08-28
申请人： Masataka Nakamura , Naoki Shimoyama , Mitsuru Yokoto
发明人： Masataka Nakamura , Naoki Shimoyama , Mitsuru Yokoto
IPC分类号： G02C7/04
CPC分类号： C08F230/08 , G02B1/043 , C08L43/04
摘要： This invention has the objective of providing monomer compositions with which polymers of a superior balance of various physical properties such as high oxygen permeability, high water content and a low modulus of elasticity can be obtained. It has the further objective of providing polymers and ophthalmic lenses comprised of said monomers. It is a monomer composition in which three types of monomers specified by the values of Q=(mass of Si atoms in 1 molecule of monomer)/(molecular weight of the monomer) and of Z=(number of ether oxygens in 1 molecule of monomer)+(number of hydroxyl groups in 1 molecule of monomer) are combined in suitable weight ratios.
摘要翻译：本发明的目的是提供可以获得具有高氧渗透性，高含水量和低弹性模量的各种物理性能优异平衡的聚合物的单体组合物。进一步的目的是提供由所述单体组成的聚合物和眼用透镜。它是一种单体组合物，其中三种类型的单体由Q =（单体的1分子中的Si原子的质量）/（单体的分子量）和Z =（1分子中的醚氧的数量）单体）+（1分子单体中的羟基数）以合适的重量比组合。

3. 发明申请

US20100291460A1 MEMBRANE ELECTRODE ASSEMBLY AND METHOD OF PRODUCING THE SAME AND FUEL CELL 有权
标题翻译：膜电极组件及其制造方法和燃料电池
公开(公告)号：US20100291460A1
公开(公告)日：2010-11-18
申请号：US12833760
申请日：2010-07-09
申请人： SHINYA ADACHI , Daisuke Izuhara , Masataka Nakamura , Naoki Shimoyama , Takao Uete , Masayuki Kidai
发明人： SHINYA ADACHI , Daisuke Izuhara , Masataka Nakamura , Naoki Shimoyama , Takao Uete , Masayuki Kidai
IPC分类号： H01M8/10
CPC分类号： H01M8/1004 , H01M8/0297 , H01M8/04197 , H01M8/1011 , H01M8/1025 , H01M8/1039 , H01M8/1053 , H01M8/1067 , H01M8/241 , H01M2300/0094 , Y02E60/523 , Y02P70/56 , Y10T156/1092
摘要： It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
摘要翻译：本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法，其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻即使使用具有高耐热性，高强度，高拉伸弹性模量和低含水量的电解质膜，也保持抑制燃料分选的效果。这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的，包括以下步骤：将至少一个电极粘合到电解质膜上，该电解质膜夹着含有增塑剂的界面电阻降低组合物，所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件，其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层（A），并且所述储能模量C 当用超微量透度计测量的电解质膜和层（A）的存储模量分别被认为是C和D时，为1GPA或更高。

4. 发明授权

US07112641B2 Monomer, polymers, and ophthalmic lenses and contact lenses made by using the same 有权
标题翻译：单体，聚合物和眼科镜片及使用其制成的隐形眼镜
公开(公告)号：US07112641B2
公开(公告)日：2006-09-26
申请号：US10473488
申请日：2002-03-13
申请人： Kazuhiko Fujisawa , Naoki Shimoyama , Mitsuru Yokota
发明人： Kazuhiko Fujisawa , Naoki Shimoyama , Mitsuru Yokota
IPC分类号： C08F130/08
CPC分类号： C08F30/08 , C07F7/0838 , G02B1/043 , C08L43/04
摘要： A monomer as represented by general formula (a) or (a′) below, with which a polymer having high oxygen permeability and transparency and suited to an ophthalmic lens is obtained, is provided. Suitable monomers include: wherein A is a siloxanyl group; R1 is H or a methyl group; R2 is a substituted group that is selected from the group consisting of alkyl groups with 1 to 20 carbon atoms that may be substituted, aryl groups with 6 to 20 carbon atoms that may be substituted and formula (c) below.
摘要翻译：提供了由通式（a）或（a'）表示的单体，其具有高透氧性和透明度并且适合于眼用透镜的聚合物。合适的单体包括：其中A是硅氧烷基; R 1是H或甲基; R 2是选自可以被取代的具有1至20个碳原子的烷基，可以被取代的具有6至20个碳原子的芳基的取代基和式（c ）。

5. 发明授权

US07838164B2 Film electrode composite element and production method therefor, and fuel cell 有权
标题翻译：薄膜电极复合元件及其制备方法和燃料电池
公开(公告)号：US07838164B2
公开(公告)日：2010-11-23
申请号：US11721143
申请日：2005-11-24
申请人： Shinya Adachi , Daisuke Izuhara , Masataka Nakamura , Naoki Shimoyama , Takao Uete , Masayuki Kidai
发明人： Shinya Adachi , Daisuke Izuhara , Masataka Nakamura , Naoki Shimoyama , Takao Uete , Masayuki Kidai
IPC分类号： H01M8/10 , H01M4/86
CPC分类号： H01M8/1004 , H01M8/0297 , H01M8/04197 , H01M8/1011 , H01M8/1025 , H01M8/1039 , H01M8/1053 , H01M8/1067 , H01M8/241 , H01M2300/0094 , Y02E60/523 , Y02P70/56 , Y10T156/1092
摘要： It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
摘要翻译：本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法，其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻即使使用具有高耐热性，高强度，高拉伸弹性模量和低含水量的电解质膜，也保持抑制燃料分选的效果。这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的，包括以下步骤：将至少一个电极粘合到电解质膜上，该电解质膜夹着含有增塑剂的界面电阻降低组合物，所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件，其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层（A），并且所述储能模量C 当用超微量透度计测量的电解质膜和层（A）的存储模量分别被认为是C和D时，为1GPA或更高。

6. 发明授权

US07329694B2 Ocular lens 有权
标题翻译：眼镜片
公开(公告)号：US07329694B2
公开(公告)日：2008-02-12
申请号：US10488089
申请日：2001-08-28
申请人： Masataka Nakamura , Kazuhiko Fujisawa , Naoki Shimoyama , Mitsuru Yokota
发明人： Masataka Nakamura , Kazuhiko Fujisawa , Naoki Shimoyama , Mitsuru Yokota
IPC分类号： G02B1/04
CPC分类号： C08F20/58 , G02B1/043 , C08L33/26 , C08L33/24 , C08L43/04
摘要： This invention provides an ophthalmic lens of high tensile elongation (i.e., that does not break easily). It is an ophthalmic lens comprising, as a polymerization component, monomers represented by formula (a) below: wherein, in formula (a), R1 is H or a methyl group; R2 is a group that is selected from alkyl groups with 1 to 8 carbon atoms, aralkyl groups with 7 to 12 carbon atoms and aryl groups with 6 to 10 carbon atoms; L1 is a substituent that is selected from ethylene groups, 1,2-propylene groups, 1,3-propylene groups and 1,4-butylene groups; and L2 is a substituent that is selected from methylene groups, ethylene groups, 1,2-propylene groups, 1,3-propylene groups and 1,4-butylene groups.
摘要翻译：本发明提供了一种具有高拉伸伸长率（即不容易破裂）的眼科镜片。作为聚合成分的眼用透镜，含有由下式（a）表示的单体：式（a）中，R 1为H或甲基; R 2是选自具有1至8个碳原子的烷基，具有7至12个碳原子的芳烷基和具有6至10个碳原子的芳基的基团; L 1是选自亚乙基，1,2-亚丙基，1,3-亚丙基和1,4-亚丁基的取代基; L 2是选自亚甲基，亚乙基，1,2-亚丙基，1,3-亚丙基和1,4-亚丁基的取代基。

7. 发明授权

US06818719B2 Polymers and ophthalmic lenses in which they are used 有权
公开(公告)号：US06818719B2
公开(公告)日：2004-11-16
申请号：US10398919
申请日：2003-04-11
申请人： Kazuhiko Fujisawa , Naoki Shimoyama , Mitsuru Yokota
发明人： Kazuhiko Fujisawa , Naoki Shimoyama , Mitsuru Yokota
IPC分类号： C08F12010
CPC分类号： G02B1/043 , A61L27/16 , C08F230/08 , C08L43/04 , C08L33/26
摘要： Polymers of high oxygen permeability and a low modulus of elasticity and ophthalmic lenses and contact lenses using the same are provided. The polymers are characterized in that they are obtained by copolymerizing 5 to 90 parts by weight of a monomer (SiMAA) represented by the formula below, 5 to 90 parts by weight of 3-tris (trimethylsiloxy) silyl propyl methacrylate (TRIS), 5 to 70 parts by weight of N,N-dimethyl acrylamide (DMAA) and 0.1 to 3 parts by weight of monomer having two or more copolymerizable carbon-carbon unsaturated bonds in 1 molecule (provided that the total quantity of SiMAA, TRIS and DMAA is 100 parts by weight and that the total quantity of SiMAA and TRIS is 30 to 95 parts by weight), and which are used for ophthalmic lenses.

8. 发明授权

US5645901A Electrode substrate for liquid crystal display device and liquid crystal display device 失效
标题翻译：液晶显示装置用电极基板及液晶显示装置
公开(公告)号：US5645901A
公开(公告)日：1997-07-08
申请号：US495666
申请日：1995-07-27
申请人： Shunsei Fukuchi , Makoto Iwamoto , Akihiro Kitabatake , Masahiro Tanimoto , Masaki Maekawa , Naoki Shimoyama
发明人： Shunsei Fukuchi , Makoto Iwamoto , Akihiro Kitabatake , Masahiro Tanimoto , Masaki Maekawa , Naoki Shimoyama
IPC分类号： B82B1/00 , G02F1/1333
CPC分类号： G02F1/133345 , G02F1/133305 , Y10T428/1055 , Y10T428/31663 , Y10T428/31667
摘要： An electrode substrate for liquid crystal display devices is constructed with a resin substrate 4, a cured coating 3, a cured coating 2 and an ITO film 6 laminated in that order. The resin substrate 4 comprises a transparent resin which is a copolymer containing not less than 20% by weight of maleimide type monomer units, having a crosslinked structure and having a glass transition temperature of not lower than 160.degree. C. and not higher than 200.degree. C., and has a thickness of 0.1 to 0.8 mm. The cured coating 3 is a cured coating comprising a polyvinyl alcohol crosslinked with an epoxysilane represented by the formula R.sup.1 SiX.sub.3 wherein R.sup.1 is an organic group of 1 to 10 carbon atoms having a glycidyl group and X is a hydrolyzable group. The cured coating 2 is a siloxane type cured coating containing fine silica particles. The ITO film 6 is an ITO film having a grainy surface with grains of a diameter of not larger than 500 nm, formed at a substrate temperature of not higher than 100.degree. C., and having a thickness of 15 to 500 nm.
摘要翻译： PCT No.PCT / JP94 / 02067 Sec。 371日期：1995年7月27日 102（e）日期1995年7月27日PCT 1994年12月8日PCT PCT。 WO95 / 16936 PCT出版物日期：1995年6月22日。液晶显示装置用电极基板由树脂基板4，固化涂层3，固化涂层2和ITO膜6构成。树脂基板4包括透明树脂，其是含有不少于20重量％马来酰亚胺型单体单元的共聚物，其具有交联结构并且玻璃化转变温度不低于160℃且不高于200℃ 厚度为0.1〜0.8mm。固化涂层3是包含与由式R 1 SiX 3表示的环氧硅烷交联的聚乙烯醇的固化涂层，其中R1是具有缩水甘油基的1至10个碳原子的有机基团，X是可水解基团。固化涂层2是含有二氧化硅微粒的硅氧烷型固化涂层。 ITO膜6是在基板温度不高于100℃，厚度为15〜500nm的条件下形成具有粒径不大于500nm的粒状的ITO膜。

9. 发明授权

US08455141B2 Polymer electrolyte as well as polymer electrolyte membrane, membrane electrode assembly and polymer electrolyte fuel cell using the same 有权
标题翻译：聚合物电解质以及聚合物电解质膜，膜电极组件和聚合物电解质燃料电池使用相同
公开(公告)号：US08455141B2
公开(公告)日：2013-06-04
申请号：US10562110
申请日：2003-06-25
申请人： Masataka Nakamura , Naoki Shimoyama , Daisuke Izuhara , Shunji Kono , Masayuki Kidai
发明人： Masataka Nakamura , Naoki Shimoyama , Daisuke Izuhara , Shunji Kono , Masayuki Kidai
IPC分类号： H01M8/10
CPC分类号： H01B1/122 , H01M8/1009 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1044 , H01M2300/0088
摘要： The present invention relates to a polymer electrolyte that provides high proton conductivity and low fuel crossover at the same time, as well as a member using the same. The embodiments of the invention can achieve high output and high energy density in the form of a polymer electrolyte fuel cell. A polymer electrolyte comprising a proton conductive polymer (A) and a polymer (B) which is different from (A) wherein a ratio of the amount of unfreezable water, represented by formula (S1), in said polymer electrolyte is no less than 40 wt % and no greater than 100 wt % is disclosed. The ratio of amount of unfreezable water (S1)=(amount of unfreezable water)/(amount of low melting point water+amount of unfreezable water)×100 (%).
摘要翻译：本发明涉及同时提供高质子传导性和低燃料分选的聚合物电解质以及使用其的构件。本发明的实施例可以以聚合物电解质燃料电池的形式实现高输出和高能量密度。包含不同于（A）的质子传导性聚合物（A）和聚合物（B）的高分子电解质，其中，所述聚合物电解质中由式（S1）表示的不可冻结水的比例为40以上 wt％和不大于100wt％。不可冻水量（S1）=（不可冻水量）/（低熔点水量+不可冻水量）×100（％）。

10. 发明申请

US20080282832A1 Tilt steering apparatus 有权
标题翻译：倾斜转向装置
公开(公告)号：US20080282832A1
公开(公告)日：2008-11-20
申请号：US12073236
申请日：2008-03-03
申请人： Naoki Shimoyama , Tohru Ohta , Kazunari Machida
发明人： Naoki Shimoyama , Tohru Ohta , Kazunari Machida
IPC分类号： B62D1/18
CPC分类号： B62D1/184 , G05G1/04 , G05G5/06
摘要： A tilt steering apparatus comprises a tilt adjusting mechanism in which a tilt lock release is established only when an oscillation-free end of an operating arm portion of a tilt operating lever is positioned toward a steering wheel side. Even when the tilt operating lever is oscillated to the steering wheel side, the tilt operating lever is prevented from returning under its own weight, thereby preventing it from being difficult to operate. The tilt steering apparatus is configured from an oscillation latch portion formed on the circumference of an oscillation center portion of an oscillation base portion of the tilt operating lever to move reciprocally in the circumferential direction, a hook portion formed in the movable bracket, and a spring that extends between the oscillation latch portion and the hook portion elastically urged in the direction of contraction. The centerline of the spring is able to pass through the oscillation center portion of the tilt operating lever as appropriate.
摘要翻译：倾斜转向装置包括倾斜调节机构，其中只有当倾斜操作杆的操作臂部分的无振动端朝向方向盘侧时才建立倾斜锁定释放。即使当倾斜操作杆向方向盘侧摆动时，防止倾斜操作杆在其自重下返回，从而防止其操作困难。倾斜转向装置由形成在倾斜操作杆的摆动基部的振荡中心部的圆周上的摆动锁定部构成，能够沿圆周方向往复移动，形成在可动支架上的钩部和弹簧其在振动锁定部分和在收缩方向上弹性推动的钩部分之间延伸。弹簧的中心线能够适当地通过倾斜操作杆的振荡中心部分。

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