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1. 发明授权

US6140420A Impact-modified thermoplastic polyolefins and articles fabricated therefrom 有权
标题翻译：冲击改性的热塑性聚烯烃及其制造的制品
公开(公告)号：US6140420A
公开(公告)日：2000-10-31
申请号：US204008
申请日：1998-12-01
申请人： Kalyan Sehanobish , Larry A. Meiske , Shaofu Wu , Pak-Wing Steve Chum
发明人： Kalyan Sehanobish , Larry A. Meiske , Shaofu Wu , Pak-Wing Steve Chum
IPC分类号： C08J3/20 , C08F10/02 , C08L23/00 , C08L23/08 , C08L23/12 , C08L23/16 , C08L51/00 , C08L101/00 , C08F8/30
CPC分类号： C08L23/12 , C08L101/00 , C08L23/16 , C08L23/0815 , C08L2314/06 , Y10T428/1352
摘要： Melt processible thermoplastic compositions and method for making them are described, these compositions comprising a thermoplastic polymer resin matrix selected from the group consisting of thermoplastic polyurethanes, polyvinyl chlorides, styrenics, engineering thermoplastics, and polyolefins, at least about 25 percent (by weight based on the total composition) of an elastomeric impact modifier dispersed as discrete particles in the thermoplastic matrix (a); and at least about 10 percent (by weight based on the total composition) of at least one homogeneous linear or substantially linear ethylene polymer dispersed as discrete particles in at least the impact modifier (b), the ethylene polymer having a molecular weight distribution less than 3.5 and a density of at least 0.04 g/cm.sup.3 higher than the density of the impact modifier component (b), wherein the elastic modulus of the thermoplastic component (a) is at least 200 times greater than the elastic modulus of the impact modifier component (b). These thermoplastic compositions have improved processability. Processes for fabricating articles from them are described. The articles made with these compositions have improved properties such as low temperature impact strength, improved percent elongation to break, greater stiffness, and improved weld line strength, making them useful for applications requiring both strength and flexibility in low temperature environments, such as automotive components and facia.
摘要翻译：描述了可熔融加工的热塑性组合物及其制备方法，这些组合物包含选自热塑性聚氨酯，聚氯乙烯，苯乙烯，工程热塑性塑料和聚烯烃的热塑性聚合物树脂基体，至少约25％（以分散在热塑性基体（a）中的离散颗粒的弹性体抗冲改性剂的总组成）; 至少约10％（基于总组合物的重量计）至少一种均匀的直链或基本上线性的乙烯聚合物，其至少在至少抗冲改性剂（b）中分散成分散的颗粒，乙烯聚合物的分子量分布小于 3.5，并且比冲击改性剂组分（b）的密度高至少0.04g / cm 3的密度，其中热塑性组分（a）的弹性模量是冲击改性剂组分（a）的弹性模量的至少200倍（b）。这些热塑性组合物具有改善的加工性能。描述从它们制造制品的方法。用这些组合物制成的制品具有改进的性能，例如低温冲击强度，改善的断裂延伸百分比，更大的刚度和更好的焊接线强度，使得它们可用于在低温环境中要求强度和柔性的应用，例如汽车部件和面。

2. 发明授权

US5861463A Impact-modified thermoplastic polyolefins and articles fabricated therefrom 失效
标题翻译：冲击改性的热塑性聚烯烃及其制造的制品
公开(公告)号：US5861463A
公开(公告)日：1999-01-19
申请号：US741648
申请日：1996-10-31
申请人： Kalyan Sehanobish , Shaofu Wu , Larry A. Meiske , Pak-Wing Steve Chum
发明人： Kalyan Sehanobish , Shaofu Wu , Larry A. Meiske , Pak-Wing Steve Chum
IPC分类号： C08J3/20 , C08F10/02 , C08L23/00 , C08L23/08 , C08L23/12 , C08L23/16 , C08L51/00 , C08L101/00 , C08F30/00
CPC分类号： C08L23/12 , C08L101/00 , C08L23/16 , C08L23/0815 , C08L2314/06 , Y10T428/1352
摘要： Melt processible thermoplastic compositions and method for making them are described, these compositions comprising a) a polypropylene matrix, b) at least about 25 percent (by weight based on the total composition) of an elastomeric impact modifier dispersed as discrete particles in the polypropylene matrix (a); and c) at least about 10 percent (by weight based on the total composition) of at least one homogeneous linear or substantially linear ethylene polymer dispersed as discrete particles in at least the impact modifier (b), the ethylene polymer having a molecular weight distribution less than 3.5 and a density of at least 0.04 g/cm.sup.3 higher than the density of the impact modifier component (b), wherein the elastic modulus of the polypropylene (a) is at least 200 times greater than the elastic modulus of the impact modifier component (b).These thermoplastic compositions have improved processability. Processes for fabricating articles from them are described. The articles made with these compositions have improved properties such as low temperature impact strength, improved percent elongation to break, greater stiffness, and improved weld line strength, making them useful for applications requiring both strength and flexibility in low temperature environments, such as automotive components and facia.
摘要翻译：描述了可熔融加工的热塑性组合物及其制备方法，这些组合物包含a）聚丙烯基体，b）至少约25重量％（基于总组合物的重量）作为分散颗粒分散在聚丙烯基体中的弹性体抗冲改性剂（一个）; 和至少一种在至少一种抗冲改性剂（b）中作为离散颗粒分散的均匀线性或基本上线性的乙烯聚合物的至少约10重量％（基于总组合物计）），乙烯聚合物具有分子量分布小于3.5，并且比冲击改性剂组分（b）的密度高至少0.04g / cm 3的密度，其中聚丙烯（a）的弹性模量比冲击改性剂的弹性模量大至少200倍组分（b）。这些热塑性组合物具有改善的加工性描述从它们制造制品的方法。用这些组合物制成的制品具有改进的性能，例如低温冲击强度，改善的断裂延伸百分比，更大的刚度和更好的焊接线强度，使得它们可用于在低温环境中要求强度和柔性的应用，例如汽车部件和面。

3. 发明授权

US4569975A Polymerization of olefins in presence of a catalyst prepared from organomagnesium compound, carbon dioxide compound, reducing halide source and transition metal compound 失效
标题翻译：在由有机镁化合物，二氧化碳化合物，还原卤素源和过渡金属化合物制备的催化剂存在下烯烃的聚合
公开(公告)号：US4569975A
公开(公告)日：1986-02-11
申请号：US711120
申请日：1985-03-12
申请人： Calvin P. Esneault , Larry A. Meiske , Ricardo Fuentes, Jr.
发明人： Calvin P. Esneault , Larry A. Meiske , Ricardo Fuentes, Jr.
IPC分类号： C08F10/00 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00
摘要： Olefins or mixtures thereof are polymerized in the presence of the product resulting from heating in an inert hydrocarbon diluent a mixture of (A) an organomagnesium material, (B) essentially anhydrous carbon dioxide, (C) a reducing halide source and (D) a transition metal compound.
摘要翻译：在惰性烃稀释剂中加热（A）有机镁材料，（B）基本上无水二氧化碳，（C）还原卤化物源和（D）有机镁材料的混合物，在烯烃或其混合物存在下聚合烯烃或其混合物。过渡金属化合物。

4. 发明授权

US4530915A Catalyst prepared from organomagnesium compound, carbon dioxide compound, reducing halide source and transition metal compound 失效
标题翻译：由有机镁化合物制备的催化剂，二氧化碳化合物，还原卤化物源和过渡金属化合物
公开(公告)号：US4530915A
公开(公告)日：1985-07-23
申请号：US573891
申请日：1984-01-25
申请人： Calvin P. Esneault , Ricardo Fuentes, Jr. , Larry A. Meiske
发明人： Calvin P. Esneault , Ricardo Fuentes, Jr. , Larry A. Meiske
IPC分类号： C08F4/60 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00
摘要： A catalyst for polymerizing olefins is the product resulting from heating in an inert hydrocarbon diluent a mixture of (A) an organomagnesium material, (B) essentially anhydrous carbon dioxide, (C) a reducing halide source and (D) a transition metal compound.
摘要翻译：用于聚合烯烃的催化剂是由（A）有机镁材料，（B）基本上无水二氧化碳，（C）还原卤化物源和（D）过渡金属化合物的混合物在惰性烃稀释剂中加热产生的产物。

5. 发明授权

US07166676B2 Process for preparing copolymers and blend compositions containing the same 有权
标题翻译：制备含有它们的共聚物和共混组合物的方法
公开(公告)号：US07166676B2
公开(公告)日：2007-01-23
申请号：US10165815
申请日：2002-06-07
申请人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
发明人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
IPC分类号： C08L23/08
CPC分类号： C08L23/04 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , D01F6/46 , C08F2/14 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08L2666/06
摘要： A process for the preparation of blends including an ethylene copolymer by copolymerizing ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
摘要翻译：一种制备包括乙烯共聚物的共混物的方法，该共聚物通过共聚乙烯和至少一种选自式H 2 C-CHR表示的化合物的共聚单体，其中R是烷基或芳基，和二烯，在包含载体，过渡金属化合物和能够将过渡金属化合物转化为催化活性的过渡金属络合物的活化剂的固体催化剂体系存在下进行。

6. 发明授权

US07714073B2 Ethylene copolymers and blend compositions 有权
标题翻译：乙烯共聚物和共混组合物
公开(公告)号：US07714073B2
公开(公告)日：2010-05-11
申请号：US11477198
申请日：2006-06-28
申请人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
发明人： Grant B. Jacobsen , Jozef J. Van Dun , Pak-Wing S. Chum , Larry A. Meiske , Fumio Matsushita , Akira Miyamoto
IPC分类号： C08L23/08 , C08F4/6592
CPC分类号： C08L23/04 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08L23/06 , C08L23/0815 , C08L2205/02 , D01F6/46 , C08F2/14 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08L2666/06
摘要： The invention provides blends comprising an ethylene copolymer formed from ethylene with at least one comonomer selected from (a) the group comprising compounds represented by the formula H2C═CHR wherein R represents a C1-C20 linear, branched or cyclic alkyl group or a C6-C20 aryl group, and (b) a C4-C20 linear, branched or cyclic diene. Each copolymer has a specific density, a specific molecular weight distribution, and a specific comonomer content distribution characteristic.
摘要翻译：本发明提供了包含由乙烯与至少一种共聚单体形成的共聚物的共混物，所述共聚单体选自（a）由式H2C = CHR表示的化合物的组，其中R表示C1-C20直链，支链或环状烷基或C6- C20芳基，和（b）C 4 -C 20直链，支链或环状二烯。每种共聚物具有特定的密度，特定的分子量分布和特定的共聚单体含量分布特征。

7. 发明授权

US5114897A Catalyst and process for polymerizing olefins 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US5114897A
公开(公告)日：1992-05-19
申请号：US708416
申请日：1991-05-31
申请人： Joseph G. Schell, Jr. , Gary R. Marchand , Larry A. Meiske
发明人： Joseph G. Schell, Jr. , Gary R. Marchand , Larry A. Meiske
IPC分类号： C08F4/646 , C08F10/00
CPC分类号： C08F10/00
摘要： Olefins are polymerized under solution polymerization conditions in the presence of the solid catalytic product resulting from removing the liquid components from the product resulting from admixing in an inert diluent and in an atmosphere which excludes moisture and oxygen (A) at least one hydrocarbon soluble organomagnesium compound; (B) at least one organic hydroxyl-containing compound; (C) at least one reducing halide source; (D) at least one transition metal (Tm) alkoxide.
摘要翻译：烯烃在溶液聚合条件下在固体催化剂存在下进行聚合，这是由惰性稀释剂和不含水分和氧气的气氛中除去来自产物的液体组分得到的（A）至少一种可溶于烃的有机镁化合物 ; （B）至少一种含有机羟基化合物; （C）至少一种还原卤素源; （D）至少一种过渡金属（Tm）醇盐。

8. 发明授权

US4661465A Method for preparing transition metal component of Ziegler-Natta catalysts 失效
标题翻译：制备齐格勒 - 纳塔催化剂的过渡金属组分的方法
公开(公告)号：US4661465A
公开(公告)日：1987-04-28
申请号：US894406
申请日：1986-08-07
申请人： Ricardo Fuentes, Jr. , Gary R. Marchand , Larry A. Meiske
发明人： Ricardo Fuentes, Jr. , Gary R. Marchand , Larry A. Meiske
IPC分类号： C08F4/62 , C08F10/00 , C08F4/64 , C08F4/68
CPC分类号： C08F10/00
摘要： A method for preparing Ziegler catalysts is disclosed wherein a mixture (A) containing the product resulting from mixing in an inert hydrocarbon diluent (1) a hydrocarbon soluble magnesium alkyl compound in said hydrocarbon solvent, (2) an aliphatic alcohol or carbon dioxide and (3) a titanium compound is reacted with (B) a reducing halide source in said hydrocarbon solvent. Components (A) and (B) are mixed at a constant initial temperature. When the magnesium concentration in component (A) and the metal concentration in component (B) are relatively low, the resultant polymer has a relatively narrow particle size distribution whereas when said concentration is relatively high, the resultant polymer has a relatively broad particle size distribution. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively low, the resultant polymer has a relatively small average particle size. When the ratio of the number of moles of aliphatic alcohol:total number of hydrocarbyl groups attached to the metal atom in component (1) is relatively high, the resultant polymer has a relatively large average particle size.
摘要翻译：公开了一种制备齐格勒催化剂的方法，其中含有在惰性烃稀释剂（1）中混合产物的混合物（1）烃溶剂中的烃溶性烷基镁化合物，（2）脂族醇或二氧化碳和（ 3）钛化合物与（B）还原卤化物源在所述烃溶剂中反应。组分（A）和（B）在恒定的初始温度下混合。当组分（A）中的镁浓度和组分（B）中的金属浓度相对较低时，所得聚合物具有相对窄的粒度分布，而当所述浓度相对较高时，所得聚合物具有相对宽的粒度分布。当脂肪族醇的摩尔数：组分（1）中与金属原子相连的烃基的总数相对较低时，所得聚合物的平均粒径相对较小。当脂肪族醇的摩尔数：组分（1）中与金属原子相连的烃基的总数相对较高时，所得聚合物的平均粒径相对较大。

9. 发明申请

US20120116021A1 POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 有权
标题翻译：聚合物组合物，其制备方法和由其制备的制品
公开(公告)号：US20120116021A1
公开(公告)日：2012-05-10
申请号：US13377916
申请日：2010-07-14
申请人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
发明人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
IPC分类号： C08L47/00
CPC分类号： C08L23/16 , C08F297/06 , C08L2205/02 , C08L2666/08 , C08L2666/06
摘要： The invention provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an [(ML(1+4, 125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML, 1+4, 125° C.) greater than, or equal to, 70, and has a low shear viscosity (11 at 0.1 rad/sec) less than, or equal to, 100,000 Pa·sec. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML(1+4, 125° C.)) greater than, or equal to, 70, and has an [Mw(abs)]/[Mw(conv)] less than 1.2.
摘要翻译：本发明提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）第一共聚物，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中所述第一组合物具有大于0.429摩尔/ g的[（ML（1 + 4,125℃））/ Mw（conv）] * 1000。本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML，1 + 4，125℃），并且具有小于或等于70的低剪切粘度（11弧度/秒），100,000Pa·秒。本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML（1 + 4，125℃）），并且具有小于1.2的[Mw（abs）] / [Mw（conv））。

10. 发明授权

US5045612A Catalyst and process for polymerizing olefins 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US5045612A
公开(公告)日：1991-09-03
申请号：US510492
申请日：1990-04-18
申请人： Joseph G. Schell, Jr. , Larry A. Meiske , Gary R. Marchand
发明人： Joseph G. Schell, Jr. , Larry A. Meiske , Gary R. Marchand
IPC分类号： C08F4/658 , C08F4/60 , C08F10/00
CPC分类号： C08F10/00
摘要： Olefins are polymerized under solution polymerization conditions in the presence of the solid catalytic product resulting from removing the liquid components from the product resulting from admixing in an inert diluent and in an atmosphere which excludes moisture and oxygen (A) at least one hydrocarbon soluble organomagnesium compound; (B) at least one organic hydroxyl-containing compound; (C) at least one reducing halide source; (D) at least one transition metal (Tm) alkoxide.
摘要翻译：烯烃在溶液聚合条件下在固体催化剂存在下进行聚合，这是由惰性稀释剂和不含水分和氧气的气氛中除去来自产物的液体组分得到的（A）至少一种可溶于烃的有机镁化合物 ; （B）至少一种含有机羟基化合物; （C）至少一种还原卤素源; （D）至少一种过渡金属（Tm）醇盐。

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