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1. 发明授权

US09102824B2 Polymer compositions, methods of making the same, and articles prepared from the same 有权
标题翻译：聚合物组合物，其制备方法和由其制备的制品
公开(公告)号：US09102824B2
公开(公告)日：2015-08-11
申请号：US13377916
申请日：2010-07-14
申请人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
发明人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
IPC分类号： C08L23/16 , C08L47/00 , C08F297/06
CPC分类号： C08L23/16 , C08F297/06 , C08L2205/02 , C08L2666/08 , C08L2666/06
摘要： The invention provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has at least one of the following features: a) an [(ML(1+4, 125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g; b) a Mooney Viscosity (ML, 1+4, 125° C.) greater than, or equal to, 70, and has a low shear viscosity (η at 0.1 rad/sec) less than, or equal to, 100,000 Pa·sec; and c) a Mooney Viscosity (ML(1+4, 125° C.)) greater than, or equal to, 70, and has an [Mw(abs)]/[Mw(conv)] less than 1.2.
摘要翻译：本发明提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）第一共聚物，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中所述第一组合物具有以下特征中的至少一个：a）大于0.429摩尔/ g的[（ML（1 + 4,125℃））/ Mw（conv）] * 1000; b）大于或等于70的门尼粘度（ML，1 + 4，125℃），并具有小于或等于100,000Pa的低剪切粘度（＆amp; 0.1rad / sec） ·秒和c）大于或等于70的门尼粘度（ML（1 + 4，125℃）），并且具有小于1.2的[Mw（abs）] / [Mw（conv）]。

2. 发明申请

US20120116021A1 POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 有权
标题翻译：聚合物组合物，其制备方法和由其制备的制品
公开(公告)号：US20120116021A1
公开(公告)日：2012-05-10
申请号：US13377916
申请日：2010-07-14
申请人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
发明人： Wenbin Liang , Brian W. Walther , Timothy E. Clayfield , Arnis U. Paeglis , Sherrika D. Daniel , Larry A. Meiske
IPC分类号： C08L47/00
CPC分类号： C08L23/16 , C08F297/06 , C08L2205/02 , C08L2666/08 , C08L2666/06
摘要： The invention provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an [(ML(1+4, 125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML, 1+4, 125° C.) greater than, or equal to, 70, and has a low shear viscosity (11 at 0.1 rad/sec) less than, or equal to, 100,000 Pa·sec. The invention also provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has a Mooney Viscosity (ML(1+4, 125° C.)) greater than, or equal to, 70, and has an [Mw(abs)]/[Mw(conv)] less than 1.2.
摘要翻译：本发明提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）第一共聚物，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中所述第一组合物具有大于0.429摩尔/ g的[（ML（1 + 4,125℃））/ Mw（conv）] * 1000。本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML，1 + 4，125℃），并且具有小于或等于70的低剪切粘度（11弧度/秒），100,000Pa·秒。本发明还提供一种包含第一组合物的组合物，其第一组合物包含以下物质：A）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; B）第二共聚体，其包含聚合形式的乙烯，α-烯烃和非共轭多烯; 并且其中第一组合物具有大于或等于70的门尼粘度（ML（1 + 4，125℃）），并且具有小于1.2的[Mw（abs）] / [Mw（conv））。

3. 发明申请

US20140287178A1 POLYMER COMPOSITIONS WITH IMPROVED RETENTION OF PROPERTIES UNDER MECHANICAL AND THERMAL STRESSES 有权
标题翻译：具有机械和热应力性能改善的聚合物组合物
公开(公告)号：US20140287178A1
公开(公告)日：2014-09-25
申请号：US14350954
申请日：2012-10-09
申请人： Timothy E. Clayfield , Arnis U. Paeglis
发明人： Timothy E. Clayfield , Arnis U. Paeglis
IPC分类号： C08L23/16 , C08L23/18
CPC分类号： C08L23/16 , C08L23/08 , C08L23/0807 , C08L23/14 , C08L23/142 , C08L23/18 , C08L23/20 , C08L2205/02 , C08L2312/00 , F16L9/14 , F16L11/04 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , C08L23/0815
摘要： The invention provides a composition comprising the following: A) an ethylene/α-olefin/diene interpolymer; B) an ethylene/α-olefin copolymer with a Mooney Viscosity [ML(1+4) at 125° C.] greater than 40; and C) a peroxide; and wherein the α-olefin of the ethylene/α-olefin copolymer of component B comprises at least four carbon atoms; and wherein component A is present in an amount from 50 to 95 weight percent, based on the sum weight of components A and B.
摘要翻译：本发明提供一种包含以下物质的组合物：A）乙烯/α-烯烃/二烯互聚物; B）乙烯/α-烯烃共聚物，门尼粘度[ML（1 + 4）在125℃]大于40; 和C）过氧化物; 并且其中组分B的乙烯/α-烯烃共聚物的α-烯烃包含至少四个碳原子; 并且其中组分A以基于组分A和B的总重量的50至95重量％的量存在。

4. 发明授权

US09580587B2 Polymer compositions with improved retention of properties under mechanical and thermal stresses 有权
标题翻译：在机械和热应力下具有改进的性能保持性的聚合物组合物
公开(公告)号：US09580587B2
公开(公告)日：2017-02-28
申请号：US14350954
申请日：2012-10-09
申请人： Timothy E. Clayfield , Arnis U. Paeglis
发明人： Timothy E. Clayfield , Arnis U. Paeglis
IPC分类号： C08L23/16 , C08L23/14 , C08L23/08 , C08L23/20 , F16L9/14 , F16L11/04 , C08L23/18
CPC分类号： C08L23/16 , C08L23/08 , C08L23/0807 , C08L23/14 , C08L23/142 , C08L23/18 , C08L23/20 , C08L2205/02 , C08L2312/00 , F16L9/14 , F16L11/04 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/1393 , Y10T428/1397 , C08L23/0815
摘要： The invention provides a composition comprising the following: A) an ethylene/α-olefin/diene interpolymer; B) an ethylene/α-olefin copolymer with a Mooney Viscosity [ML(1+4) at 125° C.] greater than 40; and C) a peroxide; and wherein the α-olefin of the ethylene/α-olefin copolymer of component B comprises at least four carbon atoms; and wherein component A is present in an amount from 50 to 95 weight percent, based on the sum weight of components A and B.
摘要翻译：本发明提供一种包含以下物质的组合物：A）乙烯/α-烯烃/二烯互聚物; B）乙烯/α-烯烃共聚物，门尼粘度[ML（1 + 4）在125℃]大于40; 和C）过氧化物; 并且其中组分B的乙烯/α-烯烃共聚物的α-烯烃包含至少四个碳原子; 并且其中组分A以基于组分A和B的总重量的50至95重量％的量存在。

5. 发明申请

US20140378602A1 ETHYLENE-BASED POLYMER COMPOSITIONS WITH IMPROVED VISCOSITIES 有权
标题翻译：具有改进粘度的基于乙烯的聚合物组合物
公开(公告)号：US20140378602A1
公开(公告)日：2014-12-25
申请号：US14368980
申请日：2012-12-27
申请人： Brian W. Walther , Timothy E. Clayfield , Curvel Hypolite
发明人： Brian W. Walther , Timothy E. Clayfield , Curvel Hypolite
IPC分类号： C08L23/16 , C08L23/08
CPC分类号： C08L23/16 , C08L23/0807 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/25
摘要： The invention provides a composition comprising a first composition comprising the following: A) a first ethylene/α-olefin interpolymer that has a weight average molecular weight (Mw) greater than 90,000 g/mole and a MWD less than, or equal to 3, each as determined by conventional GPC; B) a second ethylene/α-olefin interpolymer; and wherein the first composition has a number average molecular weight (Mn) less than 10,000 g/mole, as determined by conventional GPC; and wherein the α-olefin of first interpolymer is the same as the α-olefin of the second interpolymer.
摘要翻译：本发明提供一种包含第一组合物的组合物，其包含以下物质：A）第一乙烯/α-烯烃互聚物，其重均分子量（Mw）大于90,000g / mol，MWD小于或等于3，每个由常规GPC测定; B）第二乙烯/α-烯烃互聚物; 并且其中所述第一组合物具有通过常规GPC测定的小于10,000g / mole的数均分子量（Mn）; 并且其中第一互聚物的α-烯烃与第二互聚物的α-烯烃相同。

6. 发明授权

US06319969B1 Interpolymer compositions for use in sound management 有权
标题翻译：用于声音管理的共聚物组合物
公开(公告)号：US06319969B1
公开(公告)日：2001-11-20
申请号：US09374096
申请日：1999-08-12
申请人： Brian W. Walther , Timothy E. Clayfield , Stephen R. Betso , Stephen M. Hoenig
发明人： Brian W. Walther , Timothy E. Clayfield , Stephen R. Betso , Stephen M. Hoenig
IPC分类号： C08K509
CPC分类号： B32B27/28 , C08J5/18 , C08J2323/08 , C08K3/01 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L2314/06 , C08L2666/02 , C08L25/08
摘要： Disclosed are novel compositions of ethylene and/or &agr;-olefin/vinyl or vinylidene interpolymers and an organic acid and a filler. Also disclosed are compositions including ethylene and/or &agr;-olefin/vinyl or vinylidene interpolymers, an organic acid, various processing agents, coupling agents and a filler. The compositions disclosed herein are particularly useful in sound management applications, or as insulators.
摘要翻译：公开了乙烯和/或α-烯烃/乙烯基或亚乙烯基互聚物和有机酸和填料的新型组合物。还公开了包括乙烯和/或α-烯烃/乙烯基或亚乙烯基互聚物，有机酸，各种加工剂，偶联剂和填料的组合物。本文公开的组合物在声音管理应用或绝缘体中特别有用。

7. 发明授权

US09809703B2 Ethylene-based polymer compositions with improved viscosities 有权
公开(公告)号：US09809703B2
公开(公告)日：2017-11-07
申请号：US14368980
申请日：2012-12-27
申请人： Brian W. Walther , Timothy E. Clayfield , Curvel Hypolite
发明人： Brian W. Walther , Timothy E. Clayfield , Curvel Hypolite
IPC分类号： C08L23/00 , C08L23/16 , C08L23/08
CPC分类号： C08L23/16 , C08L23/0807 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F210/16 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/25
摘要： The invention provides a composition comprising a first composition comprising the following: A) a first ethylene/α-olefin interpolymer that has a weight average molecular weight (Mw) greater than 90,000 g/mole and a MWD less than, or equal to 3, each as determined by conventional GPC; B) a second ethylene/α-olefin interpolymer; and wherein the first composition has a number average molecular weight (Mn) less than 10,000 g/mole, as determined by conventional GPC; and wherein the α-olefin of first interpolymer is the same as the α-olefin of the second interpolymer.

8. 发明授权

US06803417B2 Polyolefin powder, processes for making and using slush molded articles made from the same 失效
标题翻译：聚烯烃粉末，其制造和使用由其制成的搪塑制品的方法
公开(公告)号：US06803417B2
公开(公告)日：2004-10-12
申请号：US10254477
申请日：2002-09-25
申请人： Stephen H. Cree , Timothy E. Clayfield
发明人： Stephen H. Cree , Timothy E. Clayfield
IPC分类号： C08J930
CPC分类号： C08L51/06 , B32B27/32 , C08F255/00 , C08F255/02 , C08L23/06 , C08L23/0815 , C08L23/10 , C08L2205/02 , C08L2312/08 , C08L2666/24 , C08L2666/04
摘要： Slush moldable polyolefin powders are prepared by blending a crosslinkable silane-grafted, olefinic interpolymer, optionally containing a crystalline polypropylene homopolymer or interpolymer; and a crosslinked silane-grafted, olefinic interpolymer containing a cure catalyst, the blend optionally containing a crystalline polyolefin powder. The resulting compositions can be slush molded to make a variety of articles of manufacture, especially automotive interior components, having good hot tear properties, low hardness and no glossing after heat aging.
摘要翻译：通过混合任选含有结晶聚丙烯均聚物或互聚物的可交联的硅烷接枝的烯烃互聚物制备可湿性模塑聚烯烃粉末; 和含有固化催化剂的交联的硅烷接枝的烯烃共聚体，所述共混物任选地含有结晶聚烯烃粉末。所得到的组合物可以被模制成制造各种制品，特别是汽车内部组件，具有良好的热撕裂性能，低硬度和热老化后没有光泽。

9. 发明授权

US08779051B2 Thermoplastic composition, method of producing the same, and articles made therefrom 有权
标题翻译：热塑性组合物，其制造方法和由其制成的制品
公开(公告)号：US08779051B2
公开(公告)日：2014-07-15
申请号：US13808951
申请日：2011-07-06
申请人： Srdjan Kisin , Eric G. Lundquist , Timothy E. Clayfield , Yannick Saint-Gerard , Veera Nelliappan
发明人： Srdjan Kisin , Eric G. Lundquist , Timothy E. Clayfield , Yannick Saint-Gerard , Veera Nelliappan
IPC分类号： C08L51/00 , C08L53/00 , C08F290/04 , C08K5/00
CPC分类号： C08L51/003 , C08L51/04 , C08L69/00 , C08L77/00 , C08L77/02 , C08L2666/20 , C08L2666/18 , C08L2666/24
摘要： The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (a) from 10 to 75 percent by weight of a continuous phase, based on the total weight of the thermoplastic composition, wherein said continuous phase comprises one or more thermoplastic polymers; and (b) from 25 to 90 percent by weight of a dispersed phase comprising one or more core/shell polymer particles, based on the total weight of the thermoplastic composition, wherein said one or more core/shell polymer particles comprise a crosslinked elastomer core and a thermoplastic shell and wherein said core/shell polymer has an average particle size diameter in the range of from 70 to 10,000 nm.
摘要翻译：本发明提供一种热塑性组合物，其制造方法和由其制成的制品。根据本发明的热塑性组合物包含：（a）基于热塑性组合物的总重量为10至75重量％的连续相的熔融共混产物，其中所述连续相包含一种或多种热塑性聚合物; 和（b）基于热塑性组合物的总重量，25至90重量％的包含一种或多种核/壳聚合物颗粒的分散相，其中所述一种或多种核/壳聚合物颗粒包含交联弹性体芯和热塑性壳，其中所述核/壳聚合物的平均粒度直径在70至10,000nm的范围内。

10. 发明申请

US20120252917A1 POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 审中-公开
标题翻译：聚合物组合物，其制备方法和由其制备的制品
公开(公告)号：US20120252917A1
公开(公告)日：2012-10-04
申请号：US13515696
申请日：2010-12-22
申请人： Srdjan Kisin , Timothy E. Clayfield
发明人： Srdjan Kisin , Timothy E. Clayfield
IPC分类号： C08L23/20
CPC分类号： C08L23/083 , C08L23/04 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2666/06
摘要： The invention provides a composition comprising at least the following: A) an ethylene/α-olefin/polyene interpolymer, B) an ethylene/α-olefin copolymer, C) optionally at least one filler, D) at least one crosslinking agent, E) at least one blowing agent.
摘要翻译：本发明提供至少包含以下物质的组合物：A）乙烯/α-烯烃/多烯共聚体，B）乙烯/α-烯烃共聚物，C）任选的至少一种填料，D）至少一种交联剂E ）至少一种发泡剂。

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