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1. 发明授权

US06720394B1 Supported olefin polymerization catalyst composition 失效
标题翻译：负载型烯烃聚合催化剂组合物
公开(公告)号：US06720394B1
公开(公告)日：2004-04-13
申请号：US09700996
申请日：2001-01-22
申请人： Kalle Kallio , Marja Mustonen , Hilkka Knuuttila
发明人： Kalle Kallio , Marja Mustonen , Hilkka Knuuttila
IPC分类号： C08F4642
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/02 , Y10S526/943 , C08F4/65916
摘要： Alumoxanes having C2-C12 alkyl groups can conveniently be used in supported olefin polymerization catalyst compositions prepared by contacting, either previous to or immediately before the beginning of the olefin polymerization, a support comprising a porous carrier with (a) an organometallic compound of the general formula R1MXv−1, (b) a metallocene of the general formula (CpY)mM′X′nZo and an alumoxane of the following general formula in any order.
摘要翻译：具有C 2 -C 12烷基的异氰酸酯可以方便地用于通过在烯烃聚合之前或之前或之前使包含多孔载体的载体与（a）一般的有机金属化合物接触而制备的负载型烯烃聚合催化剂组合物式（R 1 MXv-1），（b）通式（CpY）mM'X'nZo的茂金属和下列通式的铝氧烷任意有序。

2. 发明申请

US20130253152A1 PREPARATION OF A SOLID CATALYST SYSTEM 有权
标题翻译：固体催化剂体系的制备
公开(公告)号：US20130253152A1
公开(公告)日：2013-09-26
申请号：US13695884
申请日：2011-04-28
申请人： Kalle Kallio , Marja Mustonen , Pertti Elo , Peter Denifl , John Severn
发明人： Kalle Kallio , Marja Mustonen , Pertti Elo , Peter Denifl , John Severn
IPC分类号： C08F4/76 , C08F4/52
CPC分类号： C08F4/76 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , B01J2531/94 , C07F5/068 , C08F4/52 , C08F4/6028 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system (CS) comprising the steps of preparing a liquid clathrate (LC) comprising (a) a lattice (L) being the reaction product of (i) aluminoxane (A), (ii) an organometallic compound (O) of a transition metal (M) of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and (i) a compound (B) being effective to form with the aluminoxane (A) and the organometallic compound (O) the lattice (L), and (b) a guest (G) being an hydro-carbon compound (HC), and subsequently precipitating said liquid clathrate (LC) obtaining said solid catalyst system (SC).
摘要翻译：制备固体催化剂体系（CS）的方法，包括以下步骤：制备液体包合物（LC），其包含（a）格子（L），其为（i）铝氧烷（A），（ii）有机金属（IUPAC 2007）第3至10族的过渡金属（M）或锕系元素或镧系元素的化合物（O）和（i）与铝氧烷（A）形成有效的化合物（B）和有机金属化合物（O），晶格（L）和（b）作为氢碳化合物（HC）的客体（G），随后沉淀得到所述固体催化剂体系（SC）的所述液体包合物（LC）。

3. 发明授权

US08962509B2 Preparation of a solid catalyst system 有权
标题翻译：固体催化剂体系的制备
公开(公告)号：US08962509B2
公开(公告)日：2015-02-24
申请号：US13695884
申请日：2011-04-28
申请人： Kalle Kallio , Marja Mustonen , Pertti Elo , Peter Denifl , John Severn
发明人： Kalle Kallio , Marja Mustonen , Pertti Elo , Peter Denifl , John Severn
IPC分类号： C08F4/602 , C08F4/642 , C08F4/6592 , C08F10/00 , C08F4/76 , C07F5/06 , C08F4/52 , B01J31/12 , B01J31/14 , B01J31/22 , B01J31/26
CPC分类号： C08F4/76 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , B01J2531/94 , C07F5/068 , C08F4/52 , C08F4/6028 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system (CS) comprising the steps of preparing a liquid clathrate (LC) comprising (a) a lattice (L) being the reaction product of (i) aluminoxane (A), (ii) an organometallic compound (O) of a transition metal (M) of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and (i) a compound (B) being effective to form with the aluminoxane (A) and the organometallic compound (O) the lattice (L), and (b) a guest (G) being an hydrocarbon compound (HC), and subsequently precipitating said liquid clathrate (LC) obtaining said solid catalyst system (SC).
摘要翻译：制备固体催化剂体系（CS）的方法，包括以下步骤：制备液体包合物（LC），其包含（a）格子（L），其为（i）铝氧烷（A），（ii）有机金属（IUPAC 2007）第3至10族的过渡金属（M）或锕系元素或镧系元素的化合物（O）和（i）与铝氧烷（A）形成有效的化合物（B）和有机金属化合物（O），晶格（L）和（b）作为烃化合物（HC）的客体（G），随后沉淀得到所述固体催化剂体系（SC）的所述液体包合物（LC）。

4. 发明授权

US08828901B2 Preparation of a solid catalyst system 有权
标题翻译：固体催化剂体系的制备
公开(公告)号：US08828901B2
公开(公告)日：2014-09-09
申请号：US13696184
申请日：2011-04-28
申请人： Kalle Kallio , Marja Mustonen , Pertti Elo , John Severn , Peter Denifl
发明人： Kalle Kallio , Marja Mustonen , Pertti Elo , John Severn , Peter Denifl
IPC分类号： C08F4/642 , C08F4/6592
CPC分类号： C08F4/76 , B01J31/0239 , B01J31/0268 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/90 , C08F4/52 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system comprising the steps of generating an emulsion by dispersing a liquid clathrate in a solution wherein (i) the solution constitutes the continuous phase of the emulsion and (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises a lattice being the reaction product of aluminoxane, an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and a further compound being effective to form with the aluminoxane and the organometallic compound the lattice, and a guest being an hydrocarbon compound, and the solution comprises a silicon fluid and a hydrocarbon solvent.
摘要翻译：制备固体催化剂体系的方法，包括以下步骤：通过将液体包合物分散在溶液中产生乳液，其中（i）溶液构成乳液的连续相，和（ii）液体包合物以液滴的形式构成分散相，固化所述分散相，将所述液滴转化为固体颗粒，任选地回收所述颗粒以获得所述催化剂体系，其中所述液体包合物包含格子，其为铝氧烷，过渡金属的有机金属化合物周期表第3至10组（IUPAC 2007）或锕系元素或镧系元素，以及有效与铝氧烷和有机金属化合物形成晶格的另外的化合物，以及作为烃化合物的客体，该溶液包含硅液和烃溶剂。

5. 发明申请

US20130245212A1 PREPARATION OF A SOLID CATALYST SYSTEM 有权
标题翻译：固体催化剂体系的制备
公开(公告)号：US20130245212A1
公开(公告)日：2013-09-19
申请号：US13696184
申请日：2011-04-28
申请人： Kalle Kallio , Marja Mustonen , Pertti Elo , John Severn , Peter Denifl
发明人： Kalle Kallio , Marja Mustonen , Pertti Elo , John Severn , Peter Denifl
IPC分类号： C08F4/76 , C08F4/52
CPC分类号： C08F4/76 , B01J31/0239 , B01J31/0268 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/90 , C08F4/52 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system comprising the steps of generating an emulsion by dispersing a liquid clathrate in a solution wherein (i) the solution constitutes the continuous phase of the emulsion and (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises a lattice being the reaction product of aluminoxane, an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and a further compound being effective to form with the aluminoxane and the organometallic compound the lattice, and a guest being an hydrocarbon compound, and the solution comprises a silicon fluid and a hydrocarbon solvent.
摘要翻译：制备固体催化剂体系的方法，包括以下步骤：通过将液体包合物分散在溶液中产生乳液，其中（i）溶液构成乳液的连续相，和（ii）液体包合物以液滴的形式构成分散相，固化所述分散相，将所述液滴转化为固体颗粒，任选地回收所述颗粒以获得所述催化剂体系，其中所述液体包合物包含格子，其为铝氧烷，过渡金属的有机金属化合物周期表第3至10组（IUPAC 2007）或锕系元素或镧系元素，以及有效与铝氧烷和有机金属化合物形成晶格的另外的化合物，以及作为烃化合物的客体，该溶液包含硅液和烃溶剂。

6. 发明授权

US08822365B2 Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins 有权
公开(公告)号：US08822365B2
公开(公告)日：2014-09-02
申请号：US13643898
申请日：2011-04-28
申请人： Jenni Valonen , Marja Mustonen
发明人： Jenni Valonen , Marja Mustonen
IPC分类号： C08F4/642 , C08F4/6592
CPC分类号： C08F10/00 , B01J31/0239 , B01J31/0268 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , B01J2531/94 , C08F4/6592 , C08F4/65922 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a solid olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) in the form of solid particles comprising the steps of I) generating an emulsion by dispersing a liquid clathrate in a solvent (S) wherein (i) the solvent (S) constitutes the continuous phase of the emulsion and comprises a nonreactive fluorinated synthetic oil having a viscosity at 20° C. according to ASTM D445 of at least 10 cSt up to 2000 cSt (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, II) solidifying said dispersed phase to convert said droplets to solid particles and III) optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises (a) a lattice being the reaction product of a1) a transition metal compound of formula (I) LmRnTXq wherein “T” is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC2007), preferably a transition metal of anyone of the groups 4 to 6 of the periodic table (IUPAC2007), more preferably titanium (Ti), zirconium (Zr) or hafnium (Hf), i.e. zirconium (Zr) or hafnium (Hf), each “X” is independently a monovalent s-ligand, each “L” is independently an organic ligand which coordinates to the transition metal (T), “R” is a bridging group linking said organic ligands (L), “m” is 2 or 3, preferably 2, “n” is 0, 1 or 2, preferably 1, “q” is 1, 2 or 3, preferably 2, m+q is equal to the valency of the transition metal (T), a2) a cocatalyst comprising aluminoxane a3) a compound being effective to form the lattice with the transition metal compound and/or the aluminoxane and b) a hydrocarbon solvent (HS).

7. 发明授权

US08420562B2 Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins 有权
标题翻译：制备无载体固体茂金属催化剂体系的方法及其在烯烃聚合中的应用
公开(公告)号：US08420562B2
公开(公告)日：2013-04-16
申请号：US12998627
申请日：2009-11-04
申请人： Pertti Elo , John Severn , Peter Denifl , Soile Rautio , Marja Mustonen , Anu-Leena Hongell
发明人： Pertti Elo , John Severn , Peter Denifl , Soile Rautio , Marja Mustonen , Anu-Leena Hongell
IPC分类号： B01J31/22 , C08F4/642 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65925 , C08F210/16 , C08F4/65912 , C08F210/14 , C08F2500/18 , C08F2500/03 , C08F2500/12
摘要： Improved process for the preparation of an unsupported, heterogeneous olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC) or of an actinide or lanthanide in the form of solid particles comprising the steps of a) preparing a solution of catalyst components, including an aluminoxane, a compound being effective to form stable, liquid clathrates with aluminoxane and an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, in a hydrocarbon solvent, yielding a two phase system with an upper solvent layer, which is separated, b) preparing a liquid/liquid emulsion system comprising a continuous phase in which said solution of the catalyst components forms a dispersed phase in the form of droplets, c) solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, the catalysts system itself and its use for olefin polymerization.
摘要翻译：用于制备无支撑的非均相烯烃聚合催化剂体系的改进方法，其包含周期表（IUPAC）的第3至10族的过渡金属或固体颗粒形式的锕系元素或镧系元素的有机金属化合物，其包括步骤 a）制备催化剂组分溶液，包括铝氧烷，有效与铝氧烷和周期表第3至10族过渡金属的有机金属化合物（IUPAC 2007）形成稳定的液体包合物的化合物或锕系元素或镧系元素，在烃溶剂中，产生具有上溶剂层的两相体系，其被分离，b）制备液/液体乳液体系，其包含连续相，其中所述催化剂组分溶液形成分散相液滴的形式，c）固化所述分散相以将所述液滴转化为固体颗粒，并任选地回收所述颗粒以获得所述催化剂体系，催化剂体系本身及其在烯烃聚合中的应用。

8. 发明授权

US07718563B2 Production of olefin polymerization catalysts 有权
标题翻译：生产烯烃聚合催化剂
公开(公告)号：US07718563B2
公开(公告)日：2010-05-18
申请号：US12044350
申请日：2008-03-07
申请人： Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
发明人： Peter Denifl , Erik Van Praet , Michael Bartke , Marita Oksman , Marja Mustonen , Thomas Garoff , Kari Pesonen
IPC分类号： C08F4/42 , C08F4/6192 , B01J31/00 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , Y10S526/943 , C08F4/65912 , C08F2/22
摘要： The invention provides a process for producing an olefin polymerization catalyst, comprising an organometallic compound of a transition metal or of an actinide or lanthanide, in the form of solid catalyst particles, comprising forming a liquid/liquid emulsion system which comprises a solution of one or more catalyst components dispersed in a solvent immiscible therewith; and solidifying said dispersed phase to convert said droplets to solid particles comprising the catalyst and optionally recovering said particles.
摘要翻译：本发明提供了一种生产烯烃聚合催化剂的方法，其包括过渡金属或锕系元素或镧系元素的有机金属化合物，其为固体催化剂颗粒形式，包括形成液体/液体乳液体系，其包含一种或多种更多的催化剂组分分散在与其不混溶的溶剂中; 并固化所述分散相以将所述液滴转化成包含催化剂的固体颗粒，并任选地回收所述颗粒。

9. 发明授权

US06225423B1 Olefin polymerization catalyst system, producing and using it 有权
标题翻译：烯烃聚合催化剂体系，生产和使用它
公开(公告)号：US06225423B1
公开(公告)日：2001-05-01
申请号：US09101869
申请日：1998-09-21
申请人： Ove S. Andell , Harri Hokkanen , Marja Mustonen
发明人： Ove S. Andell , Harri Hokkanen , Marja Mustonen
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F210/16 , Y10S526/943 , C08F4/611 , C08F210/14 , C08F2500/12
摘要： The invention relates to a novel olefin polymerization catalyst system comprising a reaction product of a transition metal compound. A stable and active single active site catalyst is obtained by producing said reaction product by: (I) contacting in an organic solvent the following reactive components (a) a transition metal compound, which is at least partially soluble in the organic solvent and contains in its molecule at least one organic group and a transition metal chosen from periods 4-7 and groups 3-10 of the Periodic Table (IUPAC 1990), and (b) 0.05-500 moles of an unsaturated organic compound per mole of transition metal of the transition metal compound, which unsaturated organic compound is at least partially soluble in the organic solvent, has in its molecule 2-30 carbon atoms and at least one terminal double bond, to obtain a reaction product dissolved in the organic solvent; and (II) recovering the reaction product of the transition metal compound.
摘要翻译：本发明涉及包含过渡金属化合物的反应产物的新型烯烃聚合催化剂体系。通过以下方法得到稳定且活性的单活性位点催化剂：（I）在有机溶剂中接触下列反应性组分（a）过渡金属化合物，该过渡金属化合物至少部分可溶于有机溶剂并含有其分子中至少有一种有机基团和选自周期表第4-7和3-10族的过渡金属（IUPAC 1990）和（b）每摩尔过渡金属的0.05-500摩尔不饱和有机化合物该不饱和有机化合物至少部分可溶于有机溶剂的过渡金属化合物在其分子中具有2-30个碳原子和至少一个末端双键，以获得溶解在有机溶剂中的反应产物; 和（II）回收过渡金属化合物的反应产物。

10. 发明申请

US20130045862A1 Process for the Preparation of a Solid Metallocene Catalyst System and its use in Polymerisation of Olefins 有权
标题翻译：制备固体茂金属催化剂体系的方法及其在烯烃聚合中的应用
公开(公告)号：US20130045862A1
公开(公告)日：2013-02-21
申请号：US13643898
申请日：2011-04-28
申请人： Jenni Valonen , Marja Mustonen
发明人： Jenni Valonen , Marja Mustonen
IPC分类号： C08F4/52 , C08F4/642
CPC分类号： C08F10/00 , B01J31/0239 , B01J31/0268 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , B01J2531/94 , C08F4/6592 , C08F4/65922 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a solid olefin polymerisation catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) in the form of solid particles comprising the steps of I) generating an emulsion by dispersing a liquid clathrate in a solvent (S) wherein (i) the solvent (S) constitutes the continuous phase of the emulsion and comprises a nonreactive fluorinated synthetic oil having a viscosity at 20° C. according to ASTM D445 of at least 10 cSt up to 2000 cSt (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, II) solidifying said dispersed phase to convert said droplets to solid particles and III) optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises (a) a lattice being the reaction product of a1) a transition metal compound of formula (I) LmRnTXq wherein “T” is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC2007), preferably a transition metal of anyone of the groups 4 to 6 of the periodic table (IUPAC2007), more preferably titanium (Ti), zirconium (Zr) or hafnium (Hf), i.e. zirconium (Zr) or hafnium (Hf), each “X” is independently a monovalent s-ligand, each “L” is independently an organic ligand which coordinates to the transition metal (T), “R” is a bridging group linking said organic ligands (L), “m” is 2 or 3, preferably 2, “n” is 0, 1 or 2, preferably 1, “q” is 1, 2 or 3, preferably 2, m+q is equal to the valency of the transition metal (T), a2) a cocatalyst comprising aluminoxane a3) a compound being effective to form the lattice with the transition metal compound and/or the aluminoxane and b) a hydrocarbon solvent (HS).
摘要翻译：制备固体烯烃聚合催化剂体系的方法，其包含固体颗粒形式的元素周期表第3至10族的过渡金属的有机金属化合物（IUPAC 2007），包括以下步骤：I）通过分散在溶剂（S）中的液体包合物，其中（i）溶剂（S）构成乳液的连续相，并且包含根据ASTM D445在20℃下具有至少10cSt上升的粘度的非反应性氟化合成油（ii）液体包合物以液滴的形式构成乳液的分散相，II）固化所述分散相以将所述液滴转化为固体颗粒，和III）任选地回收所述颗粒以获得所述催化剂体系，其中所述液体包合物包括（a）作为a1）式（I）的过渡金属化合物的反应产物的晶格LmRnTXq其中T是第3〜10族中任一者的过渡金属周期表（IUPAC2007）优选周期表（IUPAC2007）中第4至6族中任何一种的过渡金属，更优选钛（Ti），锆（Zr）或铪（Hf），即锆（Zr）或铪（Hf），每个X独立地是一价s配体，每个L独立地是与过渡金属（T）配位的有机配体，R是连接所述有机配体（L）的桥连基团，m是2或3 优选2，n为0,1或2，优选1，q为1,2或3，优选2，m + q等于过渡金属（T）的化合价，a2）包含铝氧烷的助催化剂a3）与过渡金属化合物和/或铝氧烷有效形成晶格的化合物和b）烃溶剂（HS）。

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