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    • 1. 发明授权
    • Olefin polymerization catalyst system, producing and using it
    • 烯烃聚合催化剂体系,生产和使用它
    • US06225423B1
    • 2001-05-01
    • US09101869
    • 1998-09-21
    • Ove S. AndellHarri HokkanenMarja Mustonen
    • Ove S. AndellHarri HokkanenMarja Mustonen
    • C08F444
    • C08F10/00C08F4/61908C08F4/61912C08F4/61916C08F210/16Y10S526/943C08F4/611C08F210/14C08F2500/12
    • The invention relates to a novel olefin polymerization catalyst system comprising a reaction product of a transition metal compound. A stable and active single active site catalyst is obtained by producing said reaction product by: (I) contacting in an organic solvent the following reactive components (a) a transition metal compound, which is at least partially soluble in the organic solvent and contains in its molecule at least one organic group and a transition metal chosen from periods 4-7 and groups 3-10 of the Periodic Table (IUPAC 1990), and (b) 0.05-500 moles of an unsaturated organic compound per mole of transition metal of the transition metal compound, which unsaturated organic compound is at least partially soluble in the organic solvent, has in its molecule 2-30 carbon atoms and at least one terminal double bond,  to obtain a reaction product dissolved in the organic solvent; and (II) recovering the reaction product of the transition metal compound.
    • 本发明涉及包含过渡金属化合物的反应产物的新型烯烃聚合催化剂体系。 通过以下方法得到稳定且活性的单活性位点催化剂:(I)在有机溶剂中接触下列反应性组分(a)过渡金属化合物,该过渡金属化合物至少部分可溶于有机溶剂并含有 其分子中至少有一种有机基团和选自周期表第4-7和3-10族的过渡金属(IUPAC 1990)和(b)每摩尔过渡金属的0.05-500摩尔不饱和有机化合物 该不饱和有机化合物至少部分可溶于有机溶剂的过渡金属化合物在其分子中具有2-30个碳原子和至少一个末端双键,以获得溶解在有机溶剂中的反应产物; 和(II)回收过渡金属化合物的反应产物。