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1. 发明授权

US07666957B2 Polymerization process 有权
标题翻译：聚合过程
公开(公告)号：US07666957B2
公开(公告)日：2010-02-23
申请号：US10585199
申请日：2004-12-27
申请人： Kalle Kallio , Janne Maaranen , Eija Lappi , Marina Surakka
发明人： Kalle Kallio , Janne Maaranen , Eija Lappi , Marina Surakka
IPC分类号： C08F2/38 , C08F2/04 , C08F2/12 , B01J19/18
CPC分类号： C08F10/02 , B01J8/0015 , B01J19/2435 , B01J2208/00283 , B01J2208/00707 , C08F210/16 , Y10S526/905 , C08F2/00 , C08F2/06 , C08F2/42 , C08F2/14 , C08F210/14
摘要： A process for the polymerisation of ethylene and optionally at least one C3-20 alpha olefin comonomer in the slurry or solution phase in a reactor having a polymer outlet stream, a procatalyst or catalyst feed stream and a hydrogen feed stream, said polymerisation being effected in the presence of a metallocene catalyst, a diluent and hydrogen, wherein said diluent is recycled from said outlet stream to said hydrogen feed stream, said procatalyst or catalyst feed stream is free of hydrogen, said hydrogen feed stream is free of procatalyst or catalyst and said procatalyst or catalyst feed stream does not comprise recycled diluent.
摘要翻译：在具有聚合物出口流，原催化剂或催化剂进料流和氢气进料流的反应器中，在浆液或溶液相中使乙烯和任选的至少一种C 3-20α-烯烃共聚单体聚合的方法，所述聚合反应在金属茂催化剂，稀释剂和氢气的存在，其中所述稀释剂从所述出口流再循环到所述氢气进料流，所述前催化剂或催化剂进料流不含氢气，所述氢气进料流不含前催化剂或催化剂，并且所述前催化剂或催化剂进料流不包含再循环的稀释剂。

2. 发明申请

US20080269435A1 Polymerization Process 有权
标题翻译：聚合过程
公开(公告)号：US20080269435A1
公开(公告)日：2008-10-30
申请号：US10585199
申请日：2004-12-27
申请人： Kalle Kallio , Janne Maaranen , Eija Lappi , Marina Surakka
发明人： Kalle Kallio , Janne Maaranen , Eija Lappi , Marina Surakka
IPC分类号： C08F2/00 , B01J19/00
CPC分类号： C08F10/02 , B01J8/0015 , B01J19/2435 , B01J2208/00283 , B01J2208/00707 , C08F210/16 , Y10S526/905 , C08F2/00 , C08F2/06 , C08F2/42 , C08F2/14 , C08F210/14
摘要： A process for the polymerisation of ethylene and optionally at least one C3-20 alpha olefin comonomer in the slurry or solution phase in a reactor having a polymer outlet stream, a procatalyst or catalyst feed stream and a hydrogen feed stream, said polymerisation being effected in the presence of a metallocene catalyst, a diluent and hydrogen, wherein said diluent is recycled from said outlet stream to said hydrogen feed stream, said procatalyst or catalyst feed stream is free of hydrogen, said hydrogen feed stream is free of procatalyst or catalyst and said procatalyst or catalyst feed stream does not comprise recycled diluent.
摘要翻译：在具有聚合物出口流，原催化剂或催化剂进料流和氢气的反应器中，在淤浆或溶液相中使乙烯和任选的至少一种C 3-20α-烯烃共聚单体聚合的方法所述聚合在茂金属催化剂，稀释剂和氢气存在下进行，其中所述稀释剂从所述出口流再循环到所述氢气进料流中，所述前催化剂或催化剂进料流不含氢气，所述氢气进料流不含主催化剂或催化剂，并且所述原催化剂或催化剂进料流不包含再循环稀释剂。

3. 发明申请

US20080139749A1 Copolymer 审中-公开
标题翻译：共聚物
公开(公告)号：US20080139749A1
公开(公告)日：2008-06-12
申请号：US11792877
申请日：2005-12-22
申请人： Arja Lehtinen , Merete Skar , Jarmo Lindroos , Janne Maaranen , Markku Vahteri , Hans Eklind , Holger Poehler , Alexander Krajete
发明人： Arja Lehtinen , Merete Skar , Jarmo Lindroos , Janne Maaranen , Markku Vahteri , Hans Eklind , Holger Poehler , Alexander Krajete
IPC分类号： C08L23/08
CPC分类号： C08L23/0815 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08J5/18 , C08J7/04 , C08J2323/08 , C08J2423/08 , C08L2205/02 , C08L2308/00 , C08L2666/06 , C08F4/65925 , C08F210/08 , C08F2500/08 , C08F2500/02 , C08F2500/12 , C08F2500/17 , C08F210/14 , C08F2500/26
摘要： A multimodal copolymer of ethylene comprising at least (i) a lower molecular weight fraction of a copolymer of ethylene and at least one alpha-olefin comonomer and (ii) a higher molecular weight fraction of a copolymer of ethylene and at least one alpha-olefin comonomer, wherein said copolymer has a density below 920 kg/m3.
摘要翻译：一种乙烯的多峰共聚物，其至少包含（i）乙烯与至少一种α-烯烃共聚单体的共聚物的较低分子量馏分和（ii）乙烯与至少一种α-烯烃的共聚物的较高分子量馏分共聚单体，其中所述共聚物的密度低于920kg / m 3。

4. 发明申请

US20120252993A1 CATALYSTS 失效
标题翻译：催化剂
公开(公告)号：US20120252993A1
公开(公告)日：2012-10-04
申请号：US13493080
申请日：2012-06-11
申请人： Alexander Zelmanovich VOSKOBOYNIKOV , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
发明人： Alexander Zelmanovich VOSKOBOYNIKOV , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
IPC分类号： C08F4/76 , C07F19/00 , C08F10/14 , C07C13/70 , C07C13/465 , C08F10/02 , C07F17/00 , C07F7/08
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.
摘要翻译：含有式（I）配体的络合物：可用于形成烯烃聚合催化剂及其在烯烃聚合中的应用。

5. 发明申请

US20070037939A1 Process 审中-公开
标题翻译：处理
公开(公告)号：US20070037939A1
公开(公告)日：2007-02-15
申请号：US10550237
申请日：2004-03-24
申请人： Janne Maaranen , Jouni Hoikka , Soile Rautio
发明人： Janne Maaranen , Jouni Hoikka , Soile Rautio
IPC分类号： C07F17/00 , C08F4/64
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F210/02 , C08F210/16 , C08F4/65925 , C08F210/14
摘要： A process for the preparation of an olefin homopolymer or copolymer comprising polymerising at least one C2-20-α-olefin in slurry phase in the presence of 1) a metallocene compound of formula I: (Cp) (Cp″) RnMX2 (I) wherein: Cp is an optionally substituted and/or optionally fused homo- or heterocyclopentadienyl ligand; Cp″ is a cyclopentadienyl substituted by at least one C1-20-alkyl group; R is a bridge of 1-7 bridging atoms; M is a group 4 to 6 transition metal; each X is —CH2—Y, wherein Y is C6-20-aryl, C6-20 heteroaryl, C1-20-alkoxy, C6-20-aryloxy, —NR′2, —SR′, —PR′3, —SiR′3, —OSiR′3 or halogen; R′is C1-20-hydrocarbyl or in case of —NR′2, the two substituents R′ can form a ring together with the nitrogen atom wherein they are attached to; and each non-cyclopentadienyl ring moiety can further be substituted; n is 0 or 1; and (11) an aluminoxane.
摘要翻译：一种用于制备烯烃均聚物或共聚物的方法，其包括在1）茂金属化合物的存在下，在淤浆相中聚合至少一种C 2〜20α-烯烃：（Cp）（Cp“）其中：Cp是任选取代的和/或任选稠合的同 - 或杂环戊二烯基配体; Cp“是被至少一个C 1-20 - 烷基取代的环戊二烯基; R是1-7桥桥原子; M为4〜6族过渡金属; 每个X是-CH 2 -Y，其中Y是C 6-20 - 芳基，C 6-20-20杂芳基，C 1 -C 20 - 1-20烷氧基，C 6-20芳氧基，-NR'2，-SR'，-PR'3

6. 发明授权

US08569532B2 Catalysts 失效
标题翻译：催化剂
公开(公告)号：US08569532B2
公开(公告)日：2013-10-29
申请号：US13493080
申请日：2012-06-11
申请人： Alexander Zelmanovich Voskoboynik , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
发明人： Alexander Zelmanovich Voskoboynik , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
IPC分类号： C07F17/00 , B01J31/22 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.
摘要翻译：含有式（I）配体的络合物：可用于形成烯烃聚合催化剂及其在烯烃聚合中的应用。

7. 发明申请

US20130030125A1 MOULDING COMPOSITION 有权
标题翻译：成型组合物
公开(公告)号：US20130030125A1
公开(公告)日：2013-01-31
申请号：US13575334
申请日：2011-01-27
申请人： Andrey Buryak , Albrecht Dix , Magnus Palmlof , Anneli Pakkanen , Christian Piel , Ayodele Olutayo Fiola , Tore Dreng , Janne Maaranen , Alexander Krajete , Susana Filipe
发明人： Andrey Buryak , Albrecht Dix , Magnus Palmlof , Anneli Pakkanen , Christian Piel , Ayodele Olutayo Fiola , Tore Dreng , Janne Maaranen , Alexander Krajete , Susana Filipe
IPC分类号： C08L23/04 , C08L23/20
CPC分类号： C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2308/00 , C08L2666/04
摘要： A polyethylene moulding composition having a multimodal molecular weight distribution, having a density according to ISO 1183 at 23° C. in the range of 920 to 960 kg/m3 and an MFR190/2 according to ISO 1133 in the range of 0.05 to 10 g/10 min, said polyethylene moulding composition comprising at least three ethylene polymer fractions having distinct molecular weights: A) 15 to 50 wt % of a low molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 15 to 40 kg/mol; B) 15 to 50 wt % of a medium molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 70 to 200 kg/mol; and C) 15 to 50 wt % of a high molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 220 to 400 kg/mol, provided that one of A, B and C is an ethylene homopolymer and at least one other component is an ethylene copolymer with at least one C3-C10 comonomer; and wherein the composition has—a Shore D hardness measured according to ASTM D2240-05 (15 sec) of at least 56.0.
摘要翻译：具有多峰分子量分布的聚乙烯模塑组合物，其在23℃下的密度在920至960kg / m 3范围内，根据ISO 1133的MFR190 / 2在0.05至10g的范围内 10分钟，所述聚乙烯模塑组合物包含至少三种具有不同分子量的乙烯聚合物级分：A）15至50重量％的低分子量乙烯均聚物或共聚物部分，其重均分子量Mw在15至 40公斤/摩尔; B）15至50重量％的中等分子量的乙烯均聚物或共聚物部分，其重均分子量Mw为70-200kg / mol; 和C）15至50重量％的重均分子量Mw在220至400kg / mol范围内的高分子量乙烯均聚物或共聚物部分，条件是A，B和C中的一个是乙烯均聚物，至少一种其它组分是与至少一种C 3 -C 10共聚单体的乙烯共聚物; 并且其中所述组合物具有根据ASTM D2240-05（15秒）测量的至少56.0的肖氏D硬度。

8. 发明授权

US06815514B2 Catalysts 失效
标题翻译：催化剂
公开(公告)号：US06815514B2
公开(公告)日：2004-11-09
申请号：US10344855
申请日：2003-05-28
申请人： Ove Andell , Janne Maaranen , Jouni Hoikka , Tiina Vanne , Soile Rautio
发明人： Ove Andell , Janne Maaranen , Jouni Hoikka , Tiina Vanne , Soile Rautio
IPC分类号： C08F444
CPC分类号： C07F17/00 , C07F7/1804 , C08F4/639 , C08F4/63912 , C08F4/63916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/6392 , C08F2500/12 , C08F2500/04 , C08F210/06 , C08F210/14
摘要： The invention describes ligands of formula (I), wherein LIG represents an &eegr;5-ligand substituted by a group R1 and a group (R″)m; X represents a 1 to 3 atom bridge; Y represents a nitrogen or phosphorus atom; Z represents a carbon, nitrogen or phosphorus atom.
摘要翻译：本发明描述了式（I）的配体，其中LIG表示被基团R 1和基团（R“）m取代的η5 - X表示1〜3原子桥; Y表示氮或磷原子; Z表示碳，氮或磷原子。

9. 发明申请

US20100305286A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：US20100305286A1
公开(公告)日：2010-12-02
申请号：US12675545
申请日：2008-08-27
申请人： Alexander Zelmanovich Voskoboynikov , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
发明人： Alexander Zelmanovich Voskoboynikov , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
IPC分类号： C08F4/76 , C07F7/08 , C07F17/00 , B01J31/22 , C08F4/58
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex comprising a ligand of formula (I), wherein each R1, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R2, which may be the same or different is hydrogen, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R3, which binds to the 6-membered ring of the indenyl group, is —(Si(R5)2)p—, where p is 1 or 2, —(C(R5)2)n- where n is an integer of 2 or more; each R4 which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R5, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, or two R5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
摘要翻译：包含式（I）的配体的络合物，其中每个R 1可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，任选取代的杂环基或相邻碳原子上的两个R 1基团可以一起形成任选取代的5-至8-元稠环; 每个R 2可以相同或不同，为氢，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，或任选取代的杂环基; 结合茚基的6元环的R 3是 - （Si（R 5）2）p - ，其中p是1或2， - （C（R 5）2）n - ，其中n是 2以上; 每个R 4可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基，任选取代的杂芳基，任选取代的杂环基或相邻碳上的两个R 4基团一起取代的原子可以形成任选取代的5至8元稠合碳环; 每个R 5可以相同或不同，为氢，任选取代的C 1-20烃基或两个R 5基团可以形成任选取代的5至8元环; a是0到3; b为0〜3; c为0〜4; 与金属离子络合

10. 发明授权

US08674024B2 Moulding composition 有权
标题翻译：成型组合物
公开(公告)号：US08674024B2
公开(公告)日：2014-03-18
申请号：US13575334
申请日：2011-01-27
申请人： Andrey Buryak , Albrecht Dix , Magnus Palmlof , Anneli Pakkanen , Christian Piel , Ayodele Olutayo Fiola , Tore Dreng , Janne Maaranen , Alexander Krajete , Susana Filipe
发明人： Andrey Buryak , Albrecht Dix , Magnus Palmlof , Anneli Pakkanen , Christian Piel , Ayodele Olutayo Fiola , Tore Dreng , Janne Maaranen , Alexander Krajete , Susana Filipe
IPC分类号： C08F8/00 , C08L23/04
CPC分类号： C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2308/00 , C08L2666/04
摘要： A polyethylene moulding composition having a multimodal molecular weight distribution, having a density according to ISO 1183 at 23° C. in the range of 920 to 960 kg/m3 and an MFR190/2 according to ISO 1133 in the range of 0.05 to 10 g/10 min, said polyethylene moulding composition comprising at least three ethylene polymer fractions having distinct molecular weights: A) 15 to 50 wt % of a low molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 15 to 40 kg/mol; B) 15 to 50 wt % of a medium molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 70 to 200 kg/mol; and C) 15 to 50 wt % of a high molecular weight ethylene homopolymer or copolymer fraction with a weight average molecular weight Mw in the range of 220 to 400 kg/mol, provided that one of A, B and C is an ethylene homopolymer and at least one other component is an ethylene copolymer with at least one C3-C10 comonomer; and wherein the composition has—a Shore D hardness measured according to ASTM D2240-05 (15 sec) of at least 56.0.
摘要翻译：具有多峰分子量分布的聚乙烯模塑组合物，其在23℃下的密度在920至960kg / m 3范围内，根据ISO 1133的MFR190 / 2在0.05至10g的范围内 10分钟，所述聚乙烯模塑组合物包含至少三种具有不同分子量的乙烯聚合物级分：A）15至50重量％的低分子量乙烯均聚物或共聚物部分，其重均分子量Mw在15至 40公斤/摩尔; B）15至50重量％的中等分子量的乙烯均聚物或共聚物部分，其重均分子量Mw为70-200kg / mol; 和C）15至50重量％的重均分子量Mw在220至400kg / mol范围内的高分子量乙烯均聚物或共聚物部分，条件是A，B和C中的一个是乙烯均聚物，至少一种其它组分是与至少一种C 3 -C 10共聚单体的乙烯共聚物; 并且其中所述组合物具有根据ASTM D2240-05（15秒）测量的至少56.0的肖氏D硬度。

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