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    • 9. 发明公开
    • Process of producing vinyl acetate polymer
    • Verfahren zur Herstellung eines Vinyl-Acetat-Polymers
    • EP0798316A2
    • 1997-10-01
    • EP97105109.9
    • 1997-03-26
    • Kuraray Co., Ltd.
    • Takachi, HiroshiYoshimi, Kazuyori
    • C08F18/08
    • C08F18/08
    • The present invention provides a process of producing a vinyl acetate polymer by homopolymerization of a vinyl acetate monomer or copolymerization of a vinyl acetate monomer and another copolymerizable comonomer, wherein a polymerization initiator is an organic peroxide having a half life at 60°C of 10 to 110 minutes, and a polymerization liquid contains at least one carboxylic acid or its salt, said carboxylic acid being selected from the group consisting of a hydroxycarboxylic acid and a polycarboxylic acid. According to the process of producing a vinyl acetate polymer of the present invention, the amount of soluble matters is decreased in a waste liquid generated by saponification of the vinyl acetate polymer, the amount of insoluble matters is decreased in a solvent for preparing a solution of the vinyl alcohol polymer obtained by saponification of the vinyl acetate polymer, the transparency of the solution of the vinyl alcohol polymer obtained by saponification of the vinyl acetate polymer is improved, and the odor of the vinyl alcohol polymer obtained by saponification of the vinyl acetate polymer is decreased.
    • 本发明提供了通过乙酸乙烯酯单体的均聚或乙酸乙烯酯单体与另一种可共聚共聚单体的共聚合制备乙酸乙烯酯聚合物的方法,其中聚合引发剂是在60℃下的半衰期为10至 110分钟,聚合液含有至少一种羧酸或其盐,所述羧酸选自羟基羧酸和多元羧酸。 根据本发明的乙酸乙烯酯聚合物的制造方法,通过乙酸乙烯酯聚合物的皂化而产生的废液中的可溶性物质的量减少,在用于制备乙酸乙烯酯聚合物溶液的溶剂中,不溶物的量降低 通过乙酸乙烯酯聚合物皂化获得的乙烯醇聚合物,通过乙酸乙烯酯聚合物皂化得到的乙烯醇聚合物的溶液的透明度得到改善,并且乙酸乙烯酯聚合物皂化获得的乙烯醇聚合物的气味 减少。