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    • 4. 发明公开
    • Polyamide composition
    • Polyamidzusammensetzung
    • EP1262525A1
    • 2002-12-04
    • EP02011236.3
    • 2002-05-21
    • Kuraray Co., Ltd.
    • Uchida, KoichiHara, Tetsuya
    • C08L77/06
    • C08L77/00C08L77/02C08L77/06C08L81/04C08L81/00
    • Provided is a polyamide composition comprising 50 to 90 parts by weight of (A) semiaromatic polyamides having dicarboxylic acid units containing 60 to 100 mole % of terephthalic acid units and diamine units containing 60 to 100 mole %, in total, of 1,9-nonanediamine units and/or 2-methyl-1,8-octanediamine units, and 50 to 10 parts by weight of (B) aliphatic polyamides in which the average of total carbon atoms of dicarboxylic acid units and diamine units per one amide group is 7 to 12; having excellent moldability, toughness, light-weightness, hot water and steam resistance, heat resistance, mechanical characteristics, low water absorption, chemical resistance and melt stability; and are applicable for molding at low temperature with a conventional steam-heating or a conventional hot-water-heating type mold to give molded articles having sufficient heat resistance, rigidity at high temperature and dimensional stability.
    • 提供一种聚酰胺组合物,其包含50〜90重量份的(A)具有含有60〜100摩尔%对苯二甲酸单元的二羧酸单元和含有60〜100摩尔%的二胺单元的(A)半芳族聚酰胺, 壬二胺单元和/或2-甲基-1,8-辛二胺单元和50〜10重量份的(B)脂肪族聚酰胺,其中每个酰胺基团的二羧酸单元和二胺单元的总碳原子的平均值为7 到12; 具有优异的成型性,韧性,重量轻,耐热水和耐蒸汽性,耐热性,机械特性,低吸水性,耐化学性和熔体稳定性; 并且适用于用常规蒸汽加热或常规热水加热型模具在低温下成型,以提供具有足够的耐热性,高温刚性和尺寸稳定性的模塑制品。
    • 6. 发明公开
    • Copolyesters, molded articles from the same and aromatic triols used for producing the same
    • 共聚酯,含有它们的制备成型制品和芳族三醇这些聚合物
    • EP0725051A2
    • 1996-08-07
    • EP96710001.7
    • 1996-01-30
    • KURARAY CO., LTD.
    • Tai, ShinjiKageyu, AkiraHara, TetsuyaKashimura, Tsugunori
    • C07C33/26C07C43/295C07C49/84C07C317/22C08G63/133C08G63/688
    • C07C49/84C07C43/23C07C317/22C08G63/668Y10T428/1352
    • A copolyester consisting essentially of ethylene terephthalate units and further comprising 0.01 to 1 mole % based on the sum of the moles of total diol units and the moles of triol units of a triol unit represented by the following formula (I) and/or a triol unit represented by the following formula (II).


      wherein A is a group represented by formula -CH 2 CH 2 - or formula -CH(CH 3 )CH 2 -, B is a divalent hydrocarbon group, -CO-, -SO 2 -, -O- or a direct bond (-), and p, q, r, s, t and u are each an integer of 1 to 8. A process for producing the same and molded articles (in particular extrusion blow molded articles) therefrom. The copolyesters of the present invention are applicable to melt moldings accompanying melt extrusion, in particular extrusion blow molding, where parisons therefrom have good draw-down tendency and blow moldability. The copolyesters can give, without causing troubles on molding, molded articles, in particular extrusion blow molded articles, having excellent transparency, heat resistance, moisture resistance and like properties. Aromatic triols usable for producing the above copolyesters are also provided.
    • 的共聚酯基本上由对苯二甲酸乙二醇酯单元和基于总二醇单元的摩尔数和的由下式(I)表示的三元醇单元的三醇单元的摩尔数的总和,还包括0点01分〜1摩尔%,和/或三醇 单元由下式(II)表示。 worin A是由式-CH 2 CH 2或式CH所示的基团(CH 3)CH 2,B是二价烃基,-CO - , - SO 2 - , - O-或直接键( - )和p,q,R,S,T和U各自为1至8,一种生产相同和模塑制品过程整数(尤其是挤出吹塑制品)从那里。 本发明的共聚聚酯也适用于熔融模制品伴随熔融挤出,特别是挤出吹塑,型坯在有从具有良好的垂伸倾向和吹塑成型性。 所述共聚酯可以给,而对成型曹景伟麻烦,模塑制品,特别是挤出吹塑制品,具有优异的透明性,耐热性,耐湿性等性能。 因此,提供可用于制造上述共聚酯芳族三醇。