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    • 1. 发明专利
    • Fuel-cell separator manufacturing method, fuel-cell separator, and fuel cell
    • 燃料电池分离器制造方法,燃料电池分离器和燃料电池
    • JP2008108687A
    • 2008-05-08
    • JP2007024417
    • 2007-02-02
    • Kobe Steel Ltd株式会社神戸製鋼所
    • SATO TOSHIKISUZUKI JUNFUKUDA MASATOYASHIKI TAKASHI
    • H01M8/02H01M8/00H01M8/10
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a fuel-cell separator manufacturing method that can manufacture a fuel-cell separator which is excellent in corrosion resistance, high in the adhesion of a noble-metal layer, low in contact resistance while being excellent in productivity, and made of Ti or a Ti-alloy. SOLUTION: The manufacturing method for a fuel-cell separator 1 includes a recessed-part forming step S1 in which a recessed part to form a gas channel 11 for circulating gas is formed at least at a part on the surface of a substrate 2 as a Ti or Ti-alloy made fuel-cell separator, a noble metal layer forming step S2 for employing a CVD method to form a noble metal layer 3 with a thickness of ≥2 nm which is composed by including at least one or more kinds of noble metals selected from among Ru, Rh, Pd, Os, Ir, Pt, and Au on the surface of the substrate 2 having the recessed part, and a heat-treatment step S3 for subjecting the substrate 2 having the noble-metal layer 3 in the noble-metal-layer forming step S2 to heat treatment at a prescribed heat-treatment temperature and under prescribed oxygen partial pressure. COPYRIGHT: (C)2008,JPO&INPIT
    • 解决问题的方案:提供一种燃料电池用隔板的制造方法,其能够制造耐腐蚀性优异,贵金属层的附着性高的接触电阻低的燃料电池隔板,同时优异 在生产率方面,由Ti或Ti合金制成。 解决方案:燃料电池隔板1的制造方法包括:凹部形成工序S1,在基板表面的至少一部分上至少形成有形成用于循环气体的气体流路11的凹部 2作为Ti或Ti合金制成的燃料电池隔板,使用CVD法形成厚度≥2nm的贵金属层3的贵金属层形成步骤S2,其包括至少一个或多个 在具有凹部的基板2的表面上从Ru,Rh,Pd,Os,Ir,Pt和Au中选出的贵金属种类,以及对具有贵金属的基板2进行处理的热处理工序S3 层3在贵金属层形成工序S2中,在规定的热处理温度和规定的氧分压下进行热处理。 版权所有(C)2008,JPO&INPIT
    • 2. 发明专利
    • Manufacturing method of fuel cell separator, fuel cell separator, and fuel cell
    • 燃料电池分离器,燃料电池分离器和燃料电池的制造方法
    • JP2008108685A
    • 2008-05-08
    • JP2007024415
    • 2007-02-02
    • Kobe Steel Ltd株式会社神戸製鋼所
    • SUZUKI JUNYANAGISAWA KAZUMISATO TOSHIKIYASHIKI TAKASHIFUKUDA MASATO
    • H01M8/02C22C14/00C23C18/42H01M8/10
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a fuel cell separator capable of maintaining contact resistance low and stable over a long period. SOLUTION: The manufacturing method of the separator for the fuel cell includes a formation process S1 in which recesses in order to form a gas flow passage 11 to make gas circulate are formed at least at one part of the surface of a substrate 2 as the fuel cell separator formed of Ti or a Ti alloy, an adhesion process S2 in which the substrate 2 on which the recesses are formed is impregnated into an acid solution containing at least one or more kinds of noble metals selected from Ru, Rh, Pd, Os, Ir, Pt, and Au, and noble metal particles are precipitated and adhered to the surface of the substrate 2, and a heat treatment process S3 in which by heat treating the substrate 2 to which the particles are adhered, island-form crystals 3 containing the noble metals are formed on the surface of the substrate 2. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种能够使接触电阻保持较低且长时间稳定的燃料电池隔板的制造方法。 解决方案:用于燃料电池的隔板的制造方法包括:形成工序S1,在基板2的表面的至少一部分上形成有用于形成气体流路11以使气体循环的凹部 作为由Ti或Ti合金形成的燃料电池隔板,将其上形成有凹部的基板2浸渍到含有选自Ru,Rh中的至少一种贵金属的酸溶液中的粘合工艺S2, Pd,Os,Ir,Pt和Au,并且贵金属颗粒沉淀并附着到基板2的表面,并且通过热处理附着有颗粒的基板2的热处理工艺S3, 形成含有贵金属的晶体3在基板2的表面上形成。版权所有(C)2008,JPO&INPIT
    • 3. 发明专利
    • Titanium material for electrode and its manufacturing method
    • 电极用钛材料及其制造方法
    • JP2006190643A
    • 2006-07-20
    • JP2005260864
    • 2005-09-08
    • Kobe Steel Ltd株式会社神戸製鋼所
    • SAKASHITA SHINJISATO TOSHIKIYASHIKI TAKASHIFUKUDA MASATO
    • H01B13/00C22C14/00H01M8/02H01M8/10
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a titanium material for an electrode which hardly has deterioration of conductivity due to increase of a contact resistance and its manufacturing method. SOLUTION: (1) This is a manufacturing method of a titanium material for electrode in which a titanium alloy containing one kind or two kinds or more of element selected from a platinum group system element (Pb, Pt, Ir, Ru, Rh, Os), and Au, Ag is immersed in a solution containing an non-oxidizing acid ( hydrogen fluoride: 0.01-3.0 mass%, hydrochloric acid : 1.0-30 mass%, sulfuric acid 1.0-30 mass%, phosphoric acid 10-50 mass%, formic acid: 10-40 mass%, oxalic acid: 10-30 mass% etc.) and a layer of the element with a concentration : total 40-100 atomic% is formed on the surface of the titanium alloy. (2) A manufacturing method in which in the above method, the solution for immersing the titanium alloy contains an oxidizing acid is provided, and (3) a titanium material for electrode or the like obtained by the above manufacturing method is provided. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种由于接触电阻的增加而导致的导电性几乎不劣化的电极用钛材料及其制造方法。 (1)这是一种用于电极的钛材料的制造方法,其中含有选自铂族系元素(Pb,Pt,Ir,Ru等)中的一种或两种以上的元素的钛合金, Rh,Os)和Au,Ag浸渍在含有非氧化性酸(氟化氢:0.01-3.0质量%,盐酸:1.0〜30质量%,硫酸1.0〜30质量%,磷酸10 -50质量%,甲酸:10〜40质量%,草酸:10〜30质量%等),并且在钛合金的表面上形成浓度为40〜100原子%的元素层 。 (2)在上述方法中,提供了用于浸渍钛合金的溶液含有氧化性酸的制造方法,(3)提供通过上述制造方法获得的用于电极等的钛材料。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • MANUFACTURE OF WHEEL MADE OF TITANIUM
    • JPH0270340A
    • 1990-03-09
    • JP22215188
    • 1988-09-05
    • KANAI MOTOR WHEELKOBE STEEL LTD
    • ASAHINA YOSHIBUMIHIROMATSU MUTSUOFUKUDA MASATO
    • B60B21/00B21D53/30
    • PURPOSE:To obtain a wheel with high quality by shaping a strip of titanium to a pipe and forming a blank pipe by applying TIG welding, forming a rim use blank pipe by cutting it to desired length, and forming a rim by a rim forming working machine, thereafter, assembling it as a wheel. CONSTITUTION:From a strip 1 made of titanium (alloy), a blank pipe is shaped by a pipe shaping device (a) constituted of a forming roll 2 and a hydro-roll 3, etc. Subsequently, a butt part of the blank pipe is welded by a TIG welding machine 4, and by bringing it to cutting working to a necessary length, a rim use blank pipe 5 is formed. After forming and cooling, said pipe is carried into a multistage type rim forming working machine 6 installed in the next position of a flash butt or D.C but welding machine in a wheel manufacturing equipment A, and a rim R is formed. Next, by assembling a disk D and the rim R and painting them, a wheel W is obtained. In this regard, it is also allowed that the rim forming is facilitated by executing stress relief annealing after forming the blank pipe. In such a way, the blank pipe whose roundness is excellent is shaped, and a wheel of a high quality having a characteristic of a weld zone whose corrosion resistance, strength and fatigue characteristic are the same as those of a base metal can be obtained.