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    • 1. 发明申请
    • WATER-SENSITIVE FILM CONTAINING AN OLEFINIC ELASTOMER
    • 含有烯烃弹性体的水敏膜
    • WO2009138886A3
    • 2010-01-07
    • PCT/IB2009051331
    • 2009-03-30
    • KIMBERLY CLARK COSHI BOWANG JAMES HWIDEMAN GREGORY J
    • SHI BOWANG JAMES HWIDEMAN GREGORY J
    • C08J5/18A61F13/15B29D7/01C08L23/00C08L29/04
    • C08J5/18C08J2329/04C08K5/0016C08K5/053C08L1/284C08L23/08C08L23/0815C08L29/04C08L53/02C08L67/02C08L2666/24C08L2666/04
    • A film that is both elastic and water-sensitive (e.g., water-soluble, water-dispersible, etc.) in that it loses its integrity over time in the presence of water is provided. To achieve these dual attributes, the film contains an olefinic elastomer and a water-soluble polymer. Although these polymers are normally chemically incompatible due to their different polarities, the present inventors have discovered that phase separation may be minimized by selectively controlling certain aspects of the film, such as the nature of the polyolefin, water-soluble polymer, and other film components, the relative amount of the film components, and so forth. For example, certain water-soluble polymers may be selected that have a low molecular weight and viscosity to enhance their melt compatibility with nonpolar polyolefins. This, in turn, may result in a film that is generally free of separate phases, which would otherwise limit the ability of the water-soluble polymer to contact water and disperse.
    • 提供了具有弹性和水敏性(例如水溶性,水分散性等)的膜,因为它在水的存在下随时间失去其完整性。 为了实现这些双重属性,膜含有烯烃弹性体和水溶性聚合物。 虽然这些聚合物由于其极性不同而通常是化学上不相容的,但是本发明人已经发现,通过选择性地控制膜的某些方面,例如聚烯烃,水溶性聚合物和其它膜组分的性质,可以使相分离最小化 ,膜成分的相对量等。 例如,可以选择某些具有低分子量和粘度的水溶性聚合物,以提高它们与非极性聚烯烃的熔融相容性。 这又可能导致通常没有分离相的膜,否则这将限制水溶性聚合物与水接触并分散的能力。
    • 4. 发明申请
    • INJECTION MOLDING MATERIAL CONTAINING STARCH AND PLANT PROTEIN
    • 注射成型材料含有淀粉和植物蛋白
    • WO2010070470A3
    • 2010-10-28
    • PCT/IB2009054733
    • 2009-10-26
    • KIMBERLY CLARK COWANG JAMES HWIDEMAN GREGORY JSHI BOFUNK SARA A
    • WANG JAMES HWIDEMAN GREGORY JSHI BOFUNK SARA A
    • C08L3/02B29C45/00C08L89/00C08L101/00
    • C08L23/06B29C45/0001B29K2105/16B29K2711/00B29K2995/006C08L1/00C08L3/00C08L3/02C08L23/02C08L23/04C08L23/10C08L89/00C08L2205/02C08L2207/066Y10T428/1348Y10T428/1352C08L2666/06C08L2666/26
    • An injection molding material that includes a renewable resin containing a combination of renewable polymers (e.g., starch and plant protein) and a plasticizer is provided. Although such compounds are normally difficult to process into thermoplastics, the present inventors have discovered that injection molding materials may nevertheless be formed by melt blending the renewable resin with a synthetic resin (e.g., polyolefin) while selectively controlling the nature of the resins and their relative concentrations. In this manner, a morphology may be achieved in which the renewable resin is present as a discontinuous phase that is dispersed within a continuous phase of the synthetic resin (e.g., "island-in-the-sea" morphology). The discontinuous and continuous phases may each constitute from about 30 vol.% to about 70 vol.%, and in some embodiments, from about 40 vol.% to about 60 vol.%. With such a morphology, the continuity of the synthetic resin can minimize the aggregate properties of the renewable resin such that the molding material possesses melt properties similar to that of the synthetic resin. Further, this morphology may also minimize the need to use different molding tools as the shrinkage properties of the overall composition may be substantially similar to that of the synthetic resin.
    • 提供了一种注射成型材料,其包括含有可再生聚合物(例如淀粉和植物蛋白)和增塑剂的组合的可再生树脂。 虽然这些化合物通常难以加工成热塑性塑料,但是本发明人已经发现,注射成型材料可以通过将可再生树脂与合成树脂(例如聚烯烃)熔融共混而形成,同时选择性地控制树脂的性质及其相对 浓度。 以这种方式,可以实现其中可再生树脂作为分散在合成树脂的连续相中的不连续相(例如“海岛”形态)存在的形态。 不连续和连续相可以各自构成约30体积%至约70体积%,在一些实施方案中为约40体积%至约60体积%。 通过这种形态,合成树脂的连续性可以使可再生树脂的聚集性能最小化,使得成型材料具有与合成树脂类似的熔体性质。 此外,由于整个组合物的收缩性能可以基本上类似于合成树脂的收缩特性,所以这种形态还可以最小化使用不同的模制工具的需要。
    • 6. 发明申请
    • FIBERS FORMED FROM A BLEND OF A MODIFIED ALIPHATIC-AROMATIC COPOLYESTER AND THERMOPLASTIC STARCH
    • 由改性的芳香族芳族共聚物和热塑性淀粉的混合物形成的纤维
    • WO2009147544A2
    • 2009-12-10
    • PCT/IB2009051555
    • 2009-04-14
    • KIMBERLY CLARK COSHI BOWANG JAMES HHE AIMIN
    • SHI BOWANG JAMES HHE AIMIN
    • D01F6/84D01F6/78D04H1/42
    • D01F6/84D01D5/08D01D5/12D01F6/92D04H1/435D04H1/4382Y10T428/2913Y10T442/60
    • A fiber formed from a thermoplastic composition that contains a thermoplastic starch and an aliphatic-aromatic copolyester is provided. The copolyester enhances the strength of the starch-containing fibers and also facilitates the ability of the starch to be melt processed. Due to its relatively low melting point, the aliphatic-aromatic copolyester may also be extruded with the thermoplastic starch at a temperature that is low enough to avoid substantial removal of the moisture found in the starch. Furthermore, the aliphatic-aromatic copolyester is also modified with an alcohol so that it contains one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the conditions of the alcoholysis reaction (e.g., alcohol and copolymer concentrations, temperature, etc.), the resulting modified aliphatic-aromatic copolyester may have a molecular weight that is relatively low. Such low molecular weight polymers have the combination of a higher melt flow index and lower apparent viscosity, which is useful in a wide variety of fiber forming applications, such as in the meltblowing of nonwoven webs.
    • 提供由含有热塑性淀粉和脂肪族 - 芳香族共聚酯的热塑性组合物形成的纤维。 共聚酯增强了含淀粉纤维的强度,并且促进了淀粉熔融加工的能力。 由于其相对低的熔点,脂肪族 - 芳族共聚酯也可以在足够低的温度下与热塑性淀粉一起挤出,以避免显着除去在淀粉中发现的水分。 此外,脂族 - 芳族共聚酯也用醇改性,使得其含有一个或多个羟烷基或烷基端基。 通过选择性地控制醇解反应的条件(例如醇和共聚物浓度,温度等),所得改性的脂肪族 - 芳族共聚酯的分子量可以相对较低。 这种低分子量聚合物具有更高的熔体流动指数和较低的表观粘度的组合,其可用于各种各样的纤维形成应用中,例如在非织造纤维网的熔喷中。
    • 8. 发明申请
    • BIODEGRADABLE AND FLUSHABLE MULTI-LAYERED FILM
    • 可生物降解和可冲洗的多层膜
    • WO2012066436A3
    • 2012-07-12
    • PCT/IB2011054597
    • 2011-10-17
    • KIMBERLY CLARK COWANG JAMES HSHI BOLORTSCHER PETER SHAWN
    • WANG JAMES HSHI BOLORTSCHER PETER SHAWN
    • A61F13/53A61F13/511A61F13/514A61L15/28A61L15/62B32B27/00
    • A61F13/51478B23B5/04B32B3/266B32B5/022B32B5/04B32B5/26B32B25/10B32B27/12B32B2555/02Y10T428/1334Y10T442/678
    • A film that is both biodegradable and flushable, and yet can still act as a barrier to water or other fluids during use, is provided. More particularly, the film contains a water-dispersible core layer that helps the film to lose its integrity after being flushed, as well as a water-barrier skin layer that helps maintain the integrity of the film during use. The nature and relative concentration of the components in the water-barrier layer are selectively controlled to achieve a combination of different functions. That is, the majority of the polymers employed in the water- barrier layer are biodegradable polymers that can be degraded by microorganisms while in an aqueous environment (e.g., septic tank, water treatment facility, etc.). To even further enhance the overall renewability of the layer, a relatively high amount of the biodegradable polymers are starch polymers, which are also renewable. The starch polymers can also minimize the degree of stickiness in the film, which can sometimes result from certain types of synthetic polymers. Even at a high starch content, the present inventors have discovered that films may still be readily formed by using synthetic biodegradable polyesters in combination with the starch to facilitate melt processing.
    • 提供既可生物降解又可冲洗但仍可用作对使用过程中的水或其他流体的屏障的薄膜。 更特别地,该膜含有帮助膜在冲洗后失去其完整性的水分散性芯层,以及有助于在使用期间保持膜完整性的防水表层。 有选择地控制隔水层中组分的性质和相对浓度以实现不同功能的组合。 也就是说,防水层中使用的大多数聚合物是可生物降解的聚合物,其在水性环境(例如化粪池,水处理设施等)中时可被微生物降解。 为了进一步增强该层的整体可更新性,相对大量的生物可降解聚合物是淀粉聚合物,其也是可再生的。 淀粉聚合物还可以使薄膜中的粘性程度最小化,这有时可以由某些类型的合成聚合物产生。 即使在高淀粉含量下,本发明人已经发现,通过使用合成的可生物降解聚酯与淀粉结合以促进熔融加工,膜仍然可以容易地形成。