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    • 4. 发明授权
    • Process for preparation of zeolite OE having an offretite type structure
    • 制备具有偏色结构的沸石OE的方法
    • US4687653A
    • 1987-08-18
    • US795863
    • 1985-11-07
    • Junji ArikaKazushige IgawaKeiji Itabashi
    • Junji ArikaKazushige IgawaKeiji Itabashi
    • C01B33/26C01B39/30C01B33/28
    • C01B33/26C01B39/30Y10S423/38
    • Disclosed is a zeolite having a composition of the following formula: xM.sub.2/n O.Al.sub.2 O.sub.3.(5-10)SiO.sub.2.yH.sub.2 O wherein M is at least one cation having a valency of n, and x is 0.8-2 and y is 0-10, and exhibiting an X-ray powder diffraction pattern shown in Table 1. This zeolite is prepared by a process wherein a reaction mixture comprising a silica source, an alumina source, an alkali source, a potassium source and water and having a composition satisfying the following molar ratios: SiO.sub.2 /Al.sub.2 O.sub.3 =6-40, OH/SiO.sub.2 =0.3-1, K.sub.2 O/M.sub.2 O=0.1-0.9 (M: the total of alkali metals), and H.sub.2 O/SiO.sub.2 =10-70, is crystallized at 120.degree. to 200.degree. C. with stirring. The zeolite is also prepared by a process wherein a granular amorphous aluminosilicate containing aluminum in an amount of 4 to 22 wt. % as Al.sub.2 O.sub.3 (on the anhydrous base), which is obtained by reacting an aqueous alkali metal silicate solution with an aqueous aluminum-containing solution, is incorporated in an aqueous alkali metal hydroxide solution and/or an aqueous alkali metal silicate solution, to form a mixture having a composition defined by the above-mentioned molar ratios, and the mixture is crystallized with stirring.
    • 公开了具有下式的组成的沸石:xM2 / nO.Al2O3。(5-10)SiO2.yH2O其中M是至少一个化合价为n的阳离子,x为0.8-2,y为0- 并表现出如表1所示的X射线粉末衍射图。该沸石是通过以下方法制备的,其中包括二氧化硅源,氧化铝源,碱源,钾源和水的反应混合物,其组成满足 以下摩尔比:SiO 2 / Al 2 O 3 = 6-40,OH / SiO 2 = 0.3-1,K 2 O / M 2 O = 0.1-0.9(M:碱金属的总量)和H 2 O / SiO 2 = 10-70, 120〜200℃搅拌。 沸石也可以通过以下方法制备:其中含有4〜22重量%的铝的粒状无定形硅铝酸盐 通过使碱金属硅酸盐水溶液与含水铝水溶液反应而获得的Al 2 O 3(在无水基底上)加入碱金属氢氧化物水溶液和/或碱金属硅酸盐水溶液中形成 具有由上述摩尔比定义的组成的混合物,并将混合物在搅拌下结晶。
    • 6. 发明授权
    • Process for preparation of faujasite zeolite
    • 八面沸石的制备方法
    • US4678651A
    • 1987-07-07
    • US753998
    • 1985-07-11
    • Hiroshi MiyazakiJunji ArikaMichiyuki Aimoto
    • Hiroshi MiyazakiJunji ArikaMichiyuki Aimoto
    • C01B39/20C01B39/28C01B33/28
    • C01B39/20Y10S423/21
    • A faujasite zeolite of a high purity and a desired silica/alumina ratio is prepared by crystallizing at an elevated temperature a reaction mixture comprising a silica source, an alumina source, and an alkali metal source, wherein a transparent faujasite germ solution obtained by mixing and aging aqueous alkali metal silicate solution, an aqueous alkali metal aluminate solution and an aqueous alkali metal hydroxide solution is made present in the reaction mixture. The faujasite germ solution has an oxide molar composition represented by the following molar ratios:SiO.sub.2 /Al.sub.2 O.sub.3 =8 to 14,M.sub.2 O/Al.sub.2 O.sub.3 =7 to 30,andH.sub.2 O/M.sub.2 O=10 to 14,wherein M represents an alkali metal.The amount of the faujasite germ solution is 1 to 30 wt. % as Al.sub.2 O.sub.3 based on the faujasite zeolite.
    • 通过在高温下结晶包含二氧化硅源,氧化铝源和碱金属源的反应混合物来制备高纯度和所需二氧化硅/氧化铝比的八面沸石沸石,其中通过混合获得的透明八面沸石细菌溶液 老化碱金属硅酸盐水溶液,碱金属铝酸盐水溶液和碱金属氢氧化物水溶液存在于反应混合物中。 八面沸石细菌溶液具有由以下摩尔比表示的氧化物摩尔组成:SiO 2 / Al 2 O 3 = 8〜14,M 2 O / Al 2 O 3 = 7〜30,H 2 O / M 2 O = 10〜14,其中,M表示碱金属。 八面沸石菌溶液的量为1〜30重量% %为基于八面沸石的Al 2 O 3。
    • 8. 发明授权
    • Zeolite powder having high flowability, process for preparing same and
detergent composition containing same
    • 具有高流动性的沸石粉末,其制备方法和含有它的洗涤剂组合物
    • US4405484A
    • 1983-09-20
    • US291073
    • 1981-08-07
    • Hiroshi MiyazakiJunji Arika
    • Hiroshi MiyazakiJunji Arika
    • C01B39/02C11D3/12C01B33/28
    • C11D3/128C01B39/026
    • A finely divided zeolite powder of high flowability is provided. This zeolite powder is represented by the formula: Na.sub.2 O.Al.sub.2 O.sub.3.nSiO.sub.2.wH.sub.2 O (n=1.8.about.3.0 and w=1.about.6) and comprises at least 99 weight % of particles having a particle size of 1-5 microns and has an aerated bulk density of from 0.3 to about 0.5 g/cc, a degree of cohesiveness of not larger than 56%, and a general flow index (expressed as the sum of indexes of the repose angle, spatula angle, compressibility and degree of cohesiveness) of from 30 to about 50. The zeolite powder is prepared by adding an alkali metal aluminate to an aqueous zeolite slurry containing 3052 wt. % of zeolite (an anhydride) and having pH of not higher than 12.8; adjusting the pH of the slurry to a value not higher than 11; and then, drying the slurry. The zeolite powder is useful as a builder for detergent.
    • 提供了高流动性的细分沸石粉末。 该沸石粉末由下式表示:Na 2 O·Al 2 O 3·nSiO 2·w·H 2 O(n = 1.8分差3.0和w = 1分数6),并且包含至少99重量%的粒度为1-5微米的颗粒, 充气体积密度为0.3〜0.5g / cc,凝聚度为56%以下,通用流动指数(表示为休止角,刮刀角度,压缩性和内聚度的指标之和) 沸石粉末通过将碱金属铝酸盐添加到含有3052重量%的水性沸石浆料中来制备。 %的沸石(酸酐),pH值不高于12.8; 将浆料的pH调节至不高于11的值; 然后干燥浆料。 沸石粉末可用作洗涤剂的助洗剂。