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1. 发明授权

US5627151A Use of vinylpyrrolidone copolymers as detergent additives, novel polymers of vinylpyrrolidone, and preparation thereof 失效
标题翻译：使用乙烯基吡咯烷酮共聚物作为洗涤剂添加剂，乙烯基吡咯烷酮的新型聚合物及其制备
公开(公告)号：US5627151A
公开(公告)日：1997-05-06
申请号：US325177
申请日：1995-04-21
申请人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
发明人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
IPC分类号： C08F2/10 , C08F26/00 , C08F26/10 , C08F226/06 , C08F226/10 , C08F289/00 , C11D3/00 , C11D3/37 , C11D3/28
CPC分类号： C11D3/3776 , C08F289/00 , C11D3/0021 , C11D3/3788
摘要： There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising(a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinylimidazole or mixtures thereof,(b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally(c) up to 20% by weight of other monoethylenically unsaturated monomers,as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally(b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or(c) other monoethylenically unsaturated monomers,in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.
摘要翻译： PCT No.PCT / EP93 / 02851 Sec。 371日期1995年04月21日 102（e）日期1995年4月21日PCT 1993年10月15日PCT公布。公开号WO94 / 10281 日本1994年5月11日描述了通过自由基引发的单体混合物共聚获得的共聚物的用途，所述共聚物包含（a）60-99重量％的1-乙烯基吡咯烷酮，1-乙烯基咪唑或其混合物，（b）1-40重量％重量的游离碱形式的含氮碱性烯键式不饱和单体，以盐形式或季铵化形式，和任选地（c）最多20％重量的其它单烯属不饱和单体作为洗涤剂添加剂，用作（a）1-乙烯基吡咯烷酮，1-乙烯基咪唑，1-乙烯基咪唑鎓化合物或其混合物，和任选地（b）可通过自由基引发的聚合获得的聚合物，在盐水介质中以盐形式或季铵化形式的其它含氮的碱性烯属不饱和单体，和/或（c）其它单烯属不饱和单体在水溶性蛋白质存在下，通过在水溶性蛋白质的存在下在水溶性介质中聚合单体（a）和任选地（b）和/或（c））来制备聚合物的方法，使用相对于聚合中使用的单体100重量份，为0.5〜400重量份的蛋白质。

2. 发明授权

US5846924A Use of vinylpyrrolidone and vinylimidazole copolymers as detergent additives, novel polymers of vinylpyrrolidone and of vinylimidazole, and preparation thereof 失效
标题翻译：使用乙烯基吡咯烷酮和乙烯基咪唑共聚物作为洗涤剂添加剂，乙烯基吡咯烷酮和乙烯基咪唑的新型聚合物及其制备
公开(公告)号：US5846924A
公开(公告)日：1998-12-08
申请号：US694023
申请日：1996-08-08
申请人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
发明人： Juergen Detering , Christian Schade , Wolfgang Trieselt , Juergen Tropsch
IPC分类号： C08F2/10 , C08F26/00 , C08F26/10 , C08F226/06 , C08F226/10 , C08F289/00 , C11D3/00 , C11D3/37 , C11D3/28
CPC分类号： C11D3/3776 , C08F289/00 , C11D3/0021 , C11D3/3788
摘要： There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising (a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinyl-imidazole or mixtures thereof, (b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally (c) up to 20% by weight of other monoethylenically unsaturated monomers, as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally (b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or (c) other monoethylenically unsaturated monomers, in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.
摘要翻译：描述了通过自由基引发的单体混合物共聚获得的共聚物的用途，所述单体混合物包含（a）60-99重量％的1-乙烯基吡咯烷酮，1-乙烯基 - 咪唑或其混合物，（b）1-40重量％的游离碱形式的含氮碱性烯键式不饱和单体，以盐形式或季铵化形式，以及任选地（c）至多20重量％的其它单烯属不饱和单体作为抑制染料的洗涤剂添加剂在洗涤期间的转移，含有这种聚合物的洗涤剂，以及可通过（a）1-乙烯基吡咯烷酮，1-乙烯基咪唑，1-乙烯基咪唑鎓化合物或其混合物和任选的（b）其他氮气的自由引发聚合而获得的聚合物含有游离碱形式的碱性烯属不饱和单体，以盐形式或季铵化形式，和/或（c）其它单烯键式不饱和单体，在预混物的水性介质中 ce的水溶性蛋白质的制备方法和通过在水溶性蛋白质的存在下在水溶液中使单体（a）和任选地（b）和/或（c）聚合而制备聚合物的方法，使用0.5至400 每100重量份聚合中使用的单体重量份蛋白质。

3. 发明授权

US5677384A Grafted polyamidoamines and grafted polyethyleneimines, preparation thereof, and use thereof as detergent additives 失效
标题翻译：接枝聚酰胺胺和接枝聚乙烯亚胺，其制备及其用作洗涤剂添加剂
公开(公告)号：US5677384A
公开(公告)日：1997-10-14
申请号：US513800
申请日：1995-09-07
申请人： Juergen Detering , Christian Schade , Knut Oppenlaender , Michael Zirnstein , Guenter Scherr , Wolfgang Trieselt , Volker Schwendemann
发明人： Juergen Detering , Christian Schade , Knut Oppenlaender , Michael Zirnstein , Guenter Scherr , Wolfgang Trieselt , Volker Schwendemann
IPC分类号： C08F226/06 , C08F283/00 , C08F283/04 , C08G73/02 , C11D3/37 , C08L77/00
CPC分类号： C11D3/3788 , C08F283/00 , C08G73/0206 , C08G73/0213 , C08G73/028
摘要： Grafted polyamidoamines and grafted polyethyleneimines obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinyltriazole, 1-vinylimidazoles, mixtures of said monomers or mixtures of at least one of said monomers with up to 20% by weight of other monoethylenically unsaturated monomers in the presence of (b) water-soluble or -dispersible polyamidoamines, polyethyleneimines or mixtures thereof in a weight ratio of (a):(b) from 5:95 to 95:5, are useful as dye transfer inhibitors in surfactant-based detergents when included therein in an amount from 0.05 to 10% by weight.
摘要翻译： PCT No.PCT / EP94 / 01801 Sec。 371 1995年9月7日第 102（e）1995年9月7日PCT PCT 1994年6月3日PCT公布。第WO94 / 29422号公报日期1994年12月22日通过（a）1-乙烯基吡咯烷酮，1-乙烯基三唑，1-乙烯基咪唑，所述单体的混合物或至少一种所述单体的混合物自由引发聚合得到的接枝聚酰亚胺和接枝聚乙烯亚胺与多达20个在（b）水溶性或可分散的聚酰胺胺，聚乙烯亚胺或其混合物（重量比为（a）：（b））5:95至95:5的存在下，其它单烯属不饱和单体的重量百分数是有用的作为基于表面活性剂的洗涤剂中的染料转移抑制剂，当其中包含0.05至10重量％的量时。

4. 发明授权

US5622926A Vinylpyrrolidone and vinylimidazole copolymers, their preparation and their use in detergents 失效
标题翻译：乙烯基吡咯烷酮和乙烯基咪唑共聚物，它们的制备及其在洗涤剂中的应用
公开(公告)号：US5622926A
公开(公告)日：1997-04-22
申请号：US454173
申请日：1995-06-21
申请人： Christian Schade , Juergen Detering , Wolfgang Trieselt
发明人： Christian Schade , Juergen Detering , Wolfgang Trieselt
IPC分类号： C08F279/00 , C08F279/02 , C08F283/00 , C08F283/01 , C08F283/12 , C08F290/00 , C08F290/04 , C08F290/06 , C08F291/00 , C08L25/08 , C08L39/00 , C08L39/06 , C08L51/00 , C08L51/04 , C08L51/08 , C08L55/00 , C11D3/00 , C11D3/37 , C11D1/94 , C11D3/28
CPC分类号： C11D3/0021 , C08F279/02 , C08F283/01 , C08F283/122 , C08F290/04 , C08F290/06 , C08F291/00 , C11D3/3776
摘要： Copolymers which are obtainable by free radical copolymerization of a mixture of(a) from 20 to 95% by weight of 1-vinylpyrrolidone, a 1-vinylimidazole or a mixture of 1-vinylpyrrolidone and/or 1-vinylimidazoles which may contain up to 20% by weight of other monoethylenically unsaturated monomers and(b) from 5 to 80% by weight of water-insoluble polymers which contain at least one ethylenically unsaturated double bond and/or one mercapto group in the molecule, processes for the preparation of the copolymers by copolymerization of the compounds of groups (a) and (b) in the abovementioned amounts in water, an alcohol, an ester or a ketone in the presence of free radical initiators, and the use of the copolymers thus obtainable and of copolymers of from 20 to 95% by weight of 1-vinylpyrrolidone or a mixture of 1-vinylpyrrolidone with up to 20% by weight of other monoethylenically unsaturated monomers andfrom 10 to 80% by weight of styrene as additives for detergents for inhibiting the dye transfer during the wash process, and detergents which contain the stated copolymers.
摘要翻译： PCT No.PCT / EP93 / 03598 Sec。 371日期：1995年6月21日 102（e）1995年6月21日日期PCT 1993年12月17日PCT PCT。出版物WO94 / 14861 日期1994年7月7日共聚物可以通过（a）20至95重量％的1-乙烯基吡咯烷酮，1-乙烯基咪唑或1-乙烯基吡咯烷酮和/或1-乙烯基咪唑的混合物的混合物的自由基共聚获得，可含有至多20重量％的其它单烯属不饱和单体和（b）5至80重量％的在分子中含有至少一个烯属不饱和双键和/或一个巯基的水不溶性聚合物，通过在自由基引发剂的存在下，在水，醇，酯或酮中将上述量的基团（a）和（b）的化合物共聚制备共聚物，以及由此获得的共聚物的用途以及20至95重量％的1-乙烯基吡咯烷酮或1-乙烯基吡咯烷酮与至多20重量％的其它单烯属不饱和单体和10至80重量％苯乙烯的混合物的共聚物，作为洗涤剂的添加剂在洗涤过程中抑制染料转移，以及含有所述共聚物的洗涤剂。

5. 发明授权

US5578684A Preparation of polyvinylpyridine N-oxides 失效
标题翻译：聚乙烯吡啶N-氧化物的制备
公开(公告)号：US5578684A
公开(公告)日：1996-11-26
申请号：US507237
申请日：1995-08-24
申请人： Christian Schade , Dieter Boeckh , Juergen Detering
发明人： Christian Schade , Dieter Boeckh , Juergen Detering
IPC分类号： C08F8/06 , C08F26/08 , C08F8/42
CPC分类号： C08F8/06
摘要： Polyvinylpyridine N-oxides are prepared by oxidizing polyvinyl-pyridines with aqueous solutions of hydrogen peroxide in the presence of acids and oxides or acids of elements of Groups 5b, 6b, 7b and 8 of the Periodic Table or of salts of these acids as catalyst, it also being possible for the oxidation to take place in the absence of the catalysts when from 40 to 80% strength aqueous solutions of at least dibasic carboxylic acids or of polymers of monoethylenically unsaturated carboxylic acids are used as solvent.
摘要翻译： PCT No.PCT / EP94 / 00490 Sec。 371日期1995年8月24日 102（e）日期1995年8月24日PCT 1995年2月21日提交PCT公布。出版物WO94 / 20549 日期1994年9月15日聚乙烯基吡啶N-氧化物是通过在酸和氧化物的存在下用水过氧化氢水溶液氧化聚乙烯吡啶而制备的，其中元素周期表第5b，6b，7b和8族的元素，或这些酸作为催化剂，当使用40-80％强度的至少二元羧酸的水溶液或单烯属不饱和羧酸的聚合物作为溶剂时，也可以在不存在催化剂的情况下进行氧化。

6. 发明申请

US20120080120A1 METHOD FOR PASSIVATING A METALLIC SURFACE 审中-公开
标题翻译：用于钝化金属表面的方法
公开(公告)号：US20120080120A1
公开(公告)日：2012-04-05
申请号：US13251672
申请日：2011-10-03
申请人： Achim Feßenbecker , Jens Haas , Frank Richter , Walter Bertkau , Christian Schade , Helmut Witteler
发明人： Achim Feßenbecker , Jens Haas , Frank Richter , Walter Bertkau , Christian Schade , Helmut Witteler
IPC分类号： C23C22/48 , B32B15/08 , C09D139/02 , C09D143/02 , C09D139/04 , C23C22/50 , C09D7/12
CPC分类号： C09D5/12 , C09D133/02
摘要： The present invention relates to a method for passivating metallic surfaces, wherein the metal surface is contacted with an aqueous composition comprising at least one water-soluble polymer (X) comprising acidic groups and with at least one polyamine (P), the pH of the composition being in the range from 0.5 to 2.
摘要翻译：本发明涉及一种钝化金属表面的方法，其中金属表面与包含至少一种包含酸性基团和至少一种多胺（P）的至少一种水溶性聚合物（X）的水性组合物接触，组合物在0.5至2的范围内。

7. 发明申请

US20110226723A1 HOLLOW BODY WITH IMPROVED BARRIER ACTION 审中-公开
标题翻译：带有改进障碍物的中空身体
公开(公告)号：US20110226723A1
公开(公告)日：2011-09-22
申请号：US13048352
申请日：2011-03-15
申请人： Christian Schade , Hans-Jürgen Renner , Stefan Burgdörfer , Klaus Wendel
发明人： Christian Schade , Hans-Jürgen Renner , Stefan Burgdörfer , Klaus Wendel
IPC分类号： B65D90/02 , B32B25/16 , B32B1/02 , B29C49/06
CPC分类号： B32B27/08 , B29B11/08 , B29B11/14 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14113 , B29B2911/1412 , B29B2911/1414 , B29B2911/14146 , B29B2911/14666 , B29B2911/1498 , B29C49/06 , B29K2009/06 , B29K2023/0633 , B29K2023/065 , B29K2023/12 , B29K2025/00 , B29K2995/0067 , B29L2031/7158 , B32B25/16 , B32B27/30 , B32B27/302 , B32B27/32 , B32B2274/00 , B32B2307/50 , B32B2307/514 , B32B2307/54 , B32B2307/7246 , B32B2307/75 , B32B2439/40 , B32B2439/70 , B65D1/0215 , Y10T428/1379
摘要： The present invention relates to hollow bodies with improved barrier action, where the hollow bodies are composed of a three-layer sandwich structure with a shell made of polystyrene and with a middle layer as vapor barrier.
摘要翻译：本发明涉及具有改进的屏障作用的中空体，其中中空体由具有由聚苯乙烯制成的壳体和中间层作为阻气层的三层夹心结构构成。

8. 发明申请

US20100168348A1 ANIONIC SPRAY POLYMERIZATION OF STYRENE 审中-公开
标题翻译：苯乙烯的阴离子喷涂聚合
公开(公告)号：US20100168348A1
公开(公告)日：2010-07-01
申请号：US12063166
申请日：2006-08-01
申请人： Wolfgang Loth , Volker Seidl , Stefan Bruhns , Klaus-Dieter Hungenberg , Juergen Koch , Christian Schade , Claudius Schwittay
发明人： Wolfgang Loth , Volker Seidl , Stefan Bruhns , Klaus-Dieter Hungenberg , Juergen Koch , Christian Schade , Claudius Schwittay
IPC分类号： C08L25/06 , C08F2/00
CPC分类号： C08F112/08 , C08F2/00
摘要： The invention relates to a process for continuously preparing styrene polymers by anionic spray polymerization, which comprises i) styrene and the initiator solution being mixed in a dynamic or static mixer and then the mixture being sprayed, ii) the resultant droplets passing from the liquid monomer state to the melted polymer state during their free fall in the spraying tower, iii) the melt droplets being collected as a melt at the foot of the tower, the melt having a monomer content of below 1%, preferably below 0.1% (
摘要翻译：本发明涉及通过阴离子喷雾聚合连续制备苯乙烯聚合物的方法，该方法包括i）苯乙烯和引发剂溶液在动态或静态混合器中混合，然后混合物喷雾，ii）从液体单体在熔融聚合物状态下在熔融聚合物状态下自由落体在喷雾塔中，iii）熔体液滴在塔的底部作为熔体收集，熔体的单体含量低于1％，优选低于0.1％（<1000 ppm），并通过合适的方式排出。

9. 发明授权

US06444767B1 Method for retarded anionic polymerization 失效
标题翻译：延迟阴离子聚合法
公开(公告)号：US06444767B1
公开(公告)日：2002-09-03
申请号：US09622174
申请日：2000-08-14
申请人： Christian Schade , Wolfgang Fischer , Hermann Gausepohl , Rainer Klostermann , Volker Warzelhan , Michel Fontanille , Alain Deffieux , Philippe Desbois
发明人： Christian Schade , Wolfgang Fischer , Hermann Gausepohl , Rainer Klostermann , Volker Warzelhan , Michel Fontanille , Alain Deffieux , Philippe Desbois
IPC分类号： C08F452
CPC分类号： C08F12/04 , C08F236/10 , C08F4/52
摘要： In a process for the homopolymerization of vinylaromatic monomers or the copolymerization of vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl, at least one magnesium organyl and at least one aluminum organyl. The invention also provides an initiator composition for carrying out the process.
摘要翻译：在乙烯基芳族单体的均聚或乙烯基芳族单体和二烯的共聚合的方法中，单体在至少一种碱金属有机基团，至少一种镁有机基团和至少一种铝有机基团的存在下聚合。本发明还提供了用于进行该方法的引发剂组合物。

10. 发明授权

US06329483B1 Copolymers of carboxylic acids and quaternary ammonium compounds and the use thereof as thickeners of dispersants 失效
标题翻译：羧酸和季铵化合物的共聚物及其作为分散剂增稠剂的用途
公开(公告)号：US06329483B1
公开(公告)日：2001-12-11
申请号：US08313175
申请日：1994-09-29
申请人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
发明人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
IPC分类号： C08F22204
CPC分类号： A61Q19/00 , A61K8/817 , A61K2800/48 , C08F220/04 , C08F222/00
摘要： A copolymer obtainable by free-radical polymerization of A) 50-99.99% by weight of an olefinically unsaturated C3-C5 monocarboxylic acid, of an olefinically unsaturated C4-C8 dicarboxylic acid or the anhydride thereof or a mixture of such carboxylic acids or anhydrides with B) 0.01-50% by weight of an olefinically unsaturated quaternary ammonium compound of the formula I or II where R1 is C6-C20-alkyl, C6-C20-alkenyl, C5-C8-cycloalkyl, phenyl, phenyl(C1-C12-alkyl) or (C1-C12-alkyl)phenyl, R2 is hydrogen, methyl or phenyl, R3 and R4 are each H or C1-C4-alkyl, X is halogen, C1-C4-alkoxysulfonyloxy or C1-C4-alkanesulfonate, it also being possible for the latter to occur as R3 or R4 with the formation of a betaine structure, Y is O or NH, and A is C1-C6-alkylene, or a mixture of such ammonium compounds, C) 0 to 49.99% by weight of an acrylate or methacrylate of the formula III where R1, R2 and Y have the abovementioned meanings, R5 is hydrogen, methyl or ethyl, and n is a number from 0 to 25, D) 0-49.99% by weight of other copolymerizable monomers and E) 0-5% by weight of one or more compounds with at least two olefinically unsaturated groups in the molecule as crosslinker. The copolymers are suitable as thickeners and dispersants, especially in cosmetic compositions.
摘要翻译：可通过自由基聚合得到的共聚物，A）50-99.99重量％的烯属不饱和C 3 -C 5单羧酸，烯属不饱和C 4 -C 8二羧酸或其酸酐或这些羧酸或酸酐与B）的混合物， 0.01-50重量％的式I或II的烯属不饱和季铵化合物，其中R 1是C 6 -C 20 - 烷基，C 6 -C 20 - 烯基，C 5 -C 8 - 环烷基，苯基，苯基（C 1 -C 12 - 烷基）或（C 1 -C 12 - 烷基）苯基，R 2是氢，甲基或苯基，R 3和R 4各自为H或C 1 -C 4烷基，X为卤素，C 1 -C 4烷氧基磺酰氧基或C 1 -C 4烷基磺酸盐，也是可能的后者以R3或R4形成甜菜碱结构，Y为O或NH，A为C 1 -C 6亚烷基，或这些铵化合物的混合物，C）0至49.99重量％的丙烯酸酯或甲基丙烯酸酯，其中R 1，R 2和Y具有上述含义，R 5是氢，甲基或乙基，n是0至25的数，D）0-4 9.99重量％的其它可共聚单体和E）0-5重量％的一种或多种在分子中具有至少两个烯属不饱和基团的化合物作为交联剂。该共聚物适合用作增稠剂和分散剂，特别是在化妆品组合物中。

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