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1. 发明申请

US20050171235A1 Water-absorbing polymer particles inhibiting the breakdown of body fluids, composites comprising the same and use thereof 有权
标题翻译：抑制体液分解的吸水性聚合物颗粒，包含其的复合材料及其用途
公开(公告)号：US20050171235A1
公开(公告)日：2005-08-04
申请号：US10512351
申请日：2003-04-23
申请人： Jorg Harren , Jorg Issberner , Harald Schmidt
发明人： Jorg Harren , Jorg Issberner , Harald Schmidt
IPC分类号： A61F13/53 , A61F13/15 , A61F13/472 , A61F13/49 , A61L15/24 , A61L15/46 , C08F2/44 , C08J3/24 , C08K3/10 , C08K3/28 , C08K5/00 , C08L101/00 , D06M13/332 , D06M15/267 , C08K3/00
CPC分类号： A61L15/46 , A61L15/24 , A61L2300/104 , A61L2300/404 , C08K3/28 , C08L33/06
摘要： Water-absorbing, antimicrobial polymer particles comprising from about 1 to about 500 ppm, based on the particles, of a silver ion based on a silver salt, wherein the silver salt has a solubility product of at least about 1×10−8 (mol/l)m+n; at least about 10 wt. %, based on the polymer particle, of a water-absorbing polymer based on: (α1) from about 50 to about 99.99 wt. % polymerized, ethylenically unsaturated, acid groups-containing monomers or salts thereof, (α2) 0 to about 40 wt. % polymerized, mono-ethylenically unsaturated monomers polymerizable with α1, (α3) from about 0.01 to about 5 wt. %, preferably from about 0.1 to about 3 wt. % of one or more crosslinkers, (α4) 0 to about 30 wt. % of a water soluble polymer and (α5) 0 to about 20 wt. % of auxiliaries, the concentration of the silver ion based on a silver salt in at most about 90 vol. % of the particles is less than about 0.01 ppm.
摘要翻译：包含基于颗粒的约1至约500ppm的基于银盐的银离子的吸水性抗微生物聚合物颗粒，其中所述银盐的溶解度积至少为约1×10 -8 （mol / l）m + n

2. 发明申请

US20080214740A1 Hydrolytically Stable Postcrosslinked Superabsorbents 失效
标题翻译：水解稳定的后交联超吸收剂
公开(公告)号：US20080214740A1
公开(公告)日：2008-09-04
申请号：US11885250
申请日：2006-02-24
申请人： Jorg Harren , Jorg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
发明人： Jorg Harren , Jorg Issberner , Mirko Walden , Rainer Teni , Franck Furno , Peter Werle , Hans-Peter Krimmer
IPC分类号： C08F8/30
CPC分类号： C08J3/24 , C08F220/06 , C08J2333/02
摘要： The present invention relates to a process for producing postcrosslinked water-absorbing polymeric formations, comprising the steps of contacting water-absorbing polymeric formations P1 obtained by polymerization of ethylenically unsaturated acid-functional monomers or salts thereof in the presence of a crosslinker with a fluid F1 comprising a postcrosslinker, heating the water-absorbing polymeric formations in contact with the fluid F1 to a temperature in a range from 40 to 300° C. to obtain postcrosslinked water-absorbing polymeric formations P2, the water-absorbing polymeric formations P1 having a thermal stability, as determined in accordance with the test method described herein, of less than 3.0%. The invention also relates to water-absorbing polymeric formations, to the water-absorbing polymeric formations obtainable by this process, to water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers, to a composite comprising water-absorbing polymeric formations and a substrate, to a process for producing a composite, to a composite obtainable by this process, to chemical products comprising water-absorbing polymeric formations or a composite, to the use of water-absorbing polymeric formations or of a composite in chemical products and also to the use of triallyl isocyanurate as an internal crosslinker in the production of water-absorbing polymeric formations based on crosslinked carboxyl-bearing monomers.
摘要翻译：本发明涉及一种生产后交联的吸水聚合物地层的方法，包括以下步骤：通过烯键式不饱和酸官能单体或其盐的聚合获得的吸水聚合物地层P 1 存在具有包含后交联剂的流体F 1 N的交联剂，将与流体F 1 1接触的吸水聚合物层加热到40〜 300℃以获得后交联的吸水聚合物组合物P 2，根据测试方法测定的具有热稳定性的吸水性聚合物组合物P 1 <1> 如本文所述，小于3.0％。本发明还涉及吸水聚合物地层，可通过该方法获得的吸水聚合物地层，基于交联的含羧基单体的吸水聚合物地层，包括吸水聚合物地层和基底的复合材料，涉及通过该方法可获得的复合材料的方法，涉及包含吸水聚合物结构或复合材料的化学产品，使用吸水聚合物结构或化学产品中的复合材料，以及使用的三烯丙基异氰脲酸酯作为内部交联剂在基于交联的含羧基单体的吸水性聚合物地层的生产中。

3. 发明授权

US06623848B2 Water-absorbing polymers having interstitial compounds, a process for their production, and their use 失效
标题翻译：具有间隙化合物的吸水性聚合物，其制备方法及其用途
公开(公告)号：US06623848B2
公开(公告)日：2003-09-23
申请号：US10076768
申请日：2002-02-14
申请人： Helmut Brehm , Jorg Harren , Jorg Issberner , Richard Mertens
发明人： Helmut Brehm , Jorg Harren , Jorg Issberner , Richard Mertens
IPC分类号： A61F1315
CPC分类号： C08L5/16 , A61L15/18 , A61L15/20 , A61L15/46 , A61L15/60 , A61L2300/232 , B01J20/26 , B01J20/321 , B01J20/3219 , B01J20/3238 , B01J20/3274 , B01J20/3278 , C08K7/26 , C08L33/02 , Y10T428/254 , Y10T428/256 , Y10T428/257 , C08L2666/02 , C08L2666/26
摘要： The invention relates to absorvents for water and aqueous liquids, which are vased on water-swell-able, yet water-insoluble polymers wherein cyclodextrin or cyclodextrin derivatives and zeolites high in silicon have been incorporated ionically, covalently and/or as a result of mechanical inclusion.
摘要翻译：本发明涉及用于水和含水液体的吸收剂，其被水溶胀，但水不溶性的聚合物，其中环糊精或环糊精衍生物和高硅的沸石已被离子地，共价地和/或由于机械包含。

4. 发明申请

US20070065503A1 Active substance-doped absorbing polymer particles, composition comprising polycondensate matrix and absorbant polymer for release of a wound treatment substance 审中-公开
标题翻译：活性物质掺杂吸收聚合物颗粒，包含缩聚物基质和用于释放伤口处理物质的吸收性聚合物的组合物
公开(公告)号：US20070065503A1
公开(公告)日：2007-03-22
申请号：US10563747
申请日：2004-07-01
申请人： Jorg Harren , Ursula Nielinger , Dieter Oppenberg , Harald Schmidt
发明人： Jorg Harren , Ursula Nielinger , Dieter Oppenberg , Harald Schmidt
IPC分类号： C08F8/30 , A61K9/66
CPC分类号： A61L15/60 , A61L15/44 , A61L2300/412 , A61L2300/428 , A61L2300/602
摘要： A water-absorbing composition, a process for producing a water-absorbing composition, a composite comprising a water-absorbing composition, and the use of a water-absorbing composition for releasing an active substance (e.g., a wound treatment substance, a care substance, or combinations thereof) are disclosed. A water-absorbing composition can include active substance-doped water-absorbing polymer particles comprising: Φ1.) an active substance in a quantity in the range from about 0.001 to about 30 wt. %; and Φ2.) an absorber matrix in a quantity in the range from about 70 to about 99.999 wt. %. Also, a hygiene article and a wound treatment means, including a water-absorbing composition, are disclosed.
摘要翻译：吸水性组合物，吸水性组合物的制造方法，含有吸水性组合物的复合体，以及使用活性物质释放用吸水性组合物（例如伤口处理物质，护理物质，或其组合）。吸水组合物可以包括活性物质掺杂的吸水聚合物颗粒，其包含：Phi1。）活性物质的量在约0.001至约30wt。％; 和Phi2。）吸收剂基质，其量为约70-约99.999wt。％。此外，还公开了一种卫生制品和包含吸水组合物的伤口处理装置。

5. 发明授权

US08658146B2 Superabsorbent composition with tannins for odor control 有权
标题翻译：超吸收剂组合物，含有单宁，用于气味控制
公开(公告)号：US08658146B2
公开(公告)日：2014-02-25
申请号：US12679631
申请日：2008-09-24
申请人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
发明人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
IPC分类号： A61L101/34 , A61K31/78
CPC分类号： C08F220/06 , A61L15/46 , A61L15/60 , A61L2300/216 , A61L2300/30 , A61L2300/622 , C08F220/40 , C08J3/128 , C08J3/245 , C08J2300/14 , C08J2333/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品，例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

6. 发明申请

US20100209379A1 SUPERABSORBENT COMPOSITION WITH TANNINS FOR ODOR CONTROL 有权
标题翻译：用于气味控制的鞣剂的超吸收组合物
公开(公告)号：US20100209379A1
公开(公告)日：2010-08-19
申请号：US12679631
申请日：2008-09-24
申请人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
发明人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
IPC分类号： A61L9/01 , C09K3/00
CPC分类号： C08F220/06 , A61L15/46 , A61L15/60 , A61L2300/216 , A61L2300/30 , A61L2300/622 , C08F220/40 , C08J3/128 , C08J3/245 , C08J2300/14 , C08J2333/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品，例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

7. 发明授权

US09737874B2 Water-absorbing polymer having a high absorption rate 有权
公开(公告)号：US09737874B2
公开(公告)日：2017-08-22
申请号：US14110579
申请日：2012-04-03
申请人： Laurent Wattebled , Christoph Loick , Jorg Harren , Stefan Leininger
发明人： Laurent Wattebled , Christoph Loick , Jorg Harren , Stefan Leininger
IPC分类号： B01J20/28 , B01J20/30 , C08F220/06 , A61L15/42 , A61L15/60 , C08F2/16 , B01J20/18 , B01J20/20 , B01J20/26 , C08J3/12 , C08J3/24 , B01J20/04 , C08F2/44
CPC分类号： B01J20/28045 , A61L15/425 , A61L15/60 , B01J20/043 , B01J20/18 , B01J20/20 , B01J20/264 , B01J20/267 , B01J20/28004 , B01J20/28023 , B01J20/28028 , B01J20/28033 , B01J20/3014 , B01J20/3021 , B01J20/3028 , B01J2220/68 , C08F2/16 , C08F2/44 , C08F220/06 , C08J3/12 , C08J3/24 , C08J2333/00 , C08F2222/1013
摘要： A process for producing a water-absorbing polymer composition, comprising the process steps of (i) mixing (α1) 0.1 to 99.999% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof (α2) 0 to 70% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001 to 10% by weight of one or more crosslinkers, (α4) 0 to 30% by weight of water-soluble polymers, and (α5) 0 to 20% by weight of one or more assistants, where the sum of their weights (α1) to (α5) is 100% by weight, (ii) free-radical polymerization with crosslinking to form a water-insoluble aqueous untreated hydrogel polymer, and surface postcrosslinking the ground hydrogel polymer wherein blowing agents having a particle size of 100 μm to 900 μm are added to the aqueous monomer solution prior to the addition of the initiator and the start of the free-radical polymerization.

8. 发明申请

US20140312273A1 SUPERABSORBING POLYMERS WITH RAPID ABSORPTION PROPERTIES AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：具有快速吸收性能的超吸收聚合物及其制造方法
公开(公告)号：US20140312273A1
公开(公告)日：2014-10-23
申请号：US14352091
申请日：2012-11-12
申请人： Laurent Wattebled , Jorg Harren , Matthias Naumann , Franck Furno , Matthias Lobert , Rainer Teni
发明人： Laurent Wattebled , Jorg Harren , Matthias Naumann , Franck Furno , Matthias Lobert , Rainer Teni
IPC分类号： A61L15/22 , B01J20/30 , B01J20/26
CPC分类号： A61L15/225 , A61L15/24 , A61L15/60 , B01J20/267 , B01J20/3064 , C08F216/1416 , C08F220/06 , C08F222/1006 , C08J3/245 , C08J2333/02 , C08L33/02
摘要： This invention relates to a method for producing a water-absorbing polymer, including the following steps: (i) mixing (α1) 0.1 to 99.999 wt % polymerizable, ethylenically unsaturated, acid-group-containing monomers; (α2) 0 to 70 wt % polymerized ethylenically unsaturated, monomers copolymerizable with (α1); (α3) 0.00 1 to 10 wt %, cross-linking agent(s); (α4) 0 to 30 wt % water-soluble polymers; and (α5) 0 to 20 wt % additive(s), wherein the total quantity by weight of (α1) to (α5) amounts to 100 wt %, (ii) radical polymerization while cross-linking, in order to form a hydrogel polymer, (iii) drying the hydrogel polymer, (iv) grinding and sifting the water-absorbing polymer, (v) surface post-cross-linking the hydrogel polymer, and (vi) drying and processing the polymer, wherein, before the admixture of the initiator and the start of radical polymerization, 0.01 to 5 wt % of a surfactant, relative to acrylic acid, 0.01 to 5 wt % foaming agent, are added.
摘要翻译：本发明涉及一种吸水性聚合物的制造方法，包括以下步骤：（i）将（α1）0.1〜99.999重量％的可聚合的烯属不饱和的含酸基单体混合; （α2）0-70重量％聚合的烯属不饱和单体，可与（α1）共聚的单体; （α3）0.001-10重量％，交联剂; （α4）0〜30重量％水溶性聚合物; 和（α5）0〜20重量％的添加剂，其中（α1）〜（α5）的总量为100重量％，（ii）交联时的自由基聚合，以形成水凝胶聚合物，（iii）干燥水凝胶聚合物，（iv）研磨和筛选吸水聚合物，（v）表面后交联水凝胶聚合物，和（vi）干燥和加工聚合物，其中在混合物的引发剂和自由基聚合的开始，添加相对于丙烯酸的0.01〜5重量％的表面活性剂，0.01〜5重量％的发泡剂。

9. 发明授权

US08859701B2 Process for producing improved absorbent polymers by means of cryogenic grinding 有权
标题翻译：通过低温研磨生产改进的吸收性聚合物的方法
公开(公告)号：US08859701B2
公开(公告)日：2014-10-14
申请号：US13876736
申请日：2011-10-05
申请人： Christoph Loick , Dominik Gartz , Laurent Wattebled , Jorg Harren
发明人： Christoph Loick , Dominik Gartz , Laurent Wattebled , Jorg Harren
IPC分类号： C08J9/36 , C08F20/06 , C08J3/12 , A61L15/60 , A61L15/22 , C08F6/00 , C08J3/24 , B01J20/26
CPC分类号： B01J20/267 , A61L15/22 , A61L15/60 , C08F6/008 , C08J3/12 , C08J3/245 , C08J2300/14 , C08J2333/00 , C08L33/00
摘要： A process for producing a water-absorbing polymer comprises: (i) mixing (α1) 0.1-99.99% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof, or ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, (α2) 0-70% by weight of ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001-10% by weight of one or more crosslinkers, (α4) 0-30% by weight of water-soluble polymers, and (α5) 0-20% by weight of one or more assistants, where the sum of the weights (α1) to (α5) is 100%; (ii) free-radical polymerization with crosslinking to form an untreated hydrogel polymer; (iii) coarse comminution of the untreated hydrogel polymer to give pieces having a diameter from 0.1 mm to 5.0 cm; (iv) cooling and grinding the untreated hydrogel polymer; (v) drying the untreated hydrogel polymer after grinding at a temperature from 85° C. to 260° C.; (vi) postcrosslinking the hydrogel polymer and (vii) drying the water-absorbing polymer.
摘要翻译：制备吸水性聚合物的方法包括：（i）将（α1）0.1-99.99重量％的含有酸基团的烯属不饱和单体或包含质子化或季铵化的氮的烯属不饱和单体或其混合物，（α2）0-70重量％的可与（α1），（α3）0.001-10重量％的一种或多种交联剂共聚的烯属不饱和单体，（α4）0-30重量％的水溶性聚合物，和（α5）0-20重量％的一种或多种助剂，其中权重（α1）至（α5）之和为100％; （ii）通过交联进行自由基聚合以形成未处理的水凝胶聚合物; （iii）未经处理的水凝胶聚合物的粗粉碎，得到直径为0.1mm至5.0cm的片; （iv）冷却和研磨未处理的水凝胶聚合物; （v）在85℃至260℃的温度下研磨后将未处理的水凝胶聚合物干燥; （vi）将水凝胶聚合物后交联，和（vii）干燥吸水聚合物。

10. 发明申请

US20120202951A1 PROCESS FOR THE PRODUCTION OF A SUPERABSORBENT POLYMER 有权
标题翻译：制备超吸收聚合物的方法
公开(公告)号：US20120202951A1
公开(公告)日：2012-08-09
申请号：US13446411
申请日：2012-04-13
申请人： Herbert Gartner , Jorg Harren , Marc Hager , Harald Plochinger , Daniel Fricker , Hans-Peter Kohler , Sabine Auerning
发明人： Herbert Gartner , Jorg Harren , Marc Hager , Harald Plochinger , Daniel Fricker , Hans-Peter Kohler , Sabine Auerning
IPC分类号： C08F220/10
CPC分类号： C08F2/10 , C08F4/40 , C08F220/06 , C08K5/092 , C08K5/175
摘要： The present invention relates to superabsorbent polymer comprising the comprising the free radical polymerization product of an aqueous monomer mixture containing at least one α,β-ethylenically unsaturated monomer; at least one monomer having at least two α,β-ethylenically unsaturated groups; a crosslinking agent having at least two polymerizable double bonds; iron ions in an amount of from about 0.1 to about 3 wppm based on the total weight of the aqueous monomer mixture; and at least one chelating agent in an amount to provide a molar ratio of chelating agent to iron ion of from about 0.8 to about 4.0.
摘要翻译：本发明涉及超吸收聚合物，其包含含有至少一种α，β-烯属不饱和单体的含水单体混合物的自由基聚合产物; 至少一种具有至少两个α，β-烯属不饱和基团的单体; 具有至少两个可聚合双键的交联剂; 相对于含水单体混合物的总重量，铁离子的量为约0.1至约3wppm; 和至少一种螯合剂，其量使得螯合剂与铁离子的摩尔比为约0.8至约4.0。

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