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1. 发明授权

US08937301B2 Photocurable polymeric dielectrics containing 6-substituted coumarin moieties and methods of preparation and use thereof 有权
标题翻译：含有6-取代香豆素部分的光固化聚合物电介质及其制备方法及用途
公开(公告)号：US08937301B2
公开(公告)日：2015-01-20
申请号：US13128961
申请日：2009-11-20
申请人： Jordan Quinn , He Yan , Yan Zheng , Christopher Newman , Silke Annika Koehler , Antonio Facchetti , Thomas Breiner
发明人： Jordan Quinn , He Yan , Yan Zheng , Christopher Newman , Silke Annika Koehler , Antonio Facchetti , Thomas Breiner
IPC分类号： H01L29/786 , H01L51/05 , H01L51/00 , C08G61/02
CPC分类号： H01L51/052 , B05D3/06 , C08F12/22 , C08F12/24 , C08F112/14 , C08F118/12 , C08F212/14 , C08F216/10 , C08G61/02 , C09D125/18 , H01B3/442 , H01B3/447 , H01L51/004 , H01L51/0043 , H01L51/0073 , Y10T428/31938 , C08F220/14 , C08F212/32
摘要： Disclosed are polymer-based dielectric compositions (e.g., formulations) and materials (e.g. films) and associated devices. The polymers generally include photocrosslinkable pendant groups; for example, the polymers can include one or more coumarin-containing pendant groups.
摘要翻译：公开了基于聚合物的电介质组合物（例如制剂）和材料（例如膜）和相关装置。聚合物通常包括可光致交联的侧基; 例如，聚合物可以包括一种或多种含香豆素的侧基。

2. 发明申请

US20110215334A1 PHOTOCURABLE POLYMERIC DIELECTRICS AND METHODS OF PREPARATION AND USE THEREOF 有权
标题翻译：可光聚合电介质及其制备和使用方法
公开(公告)号：US20110215334A1
公开(公告)日：2011-09-08
申请号：US13128961
申请日：2009-11-20
申请人： Jordan Quinn , He Yan , Yan Zheng , Christopher Newman , Silke Annika Koehler , Antonio Facchetti , Thomas Breiner
发明人： Jordan Quinn , He Yan , Yan Zheng , Christopher Newman , Silke Annika Koehler , Antonio Facchetti , Thomas Breiner
IPC分类号： H01L29/786 , C08F118/12 , C08F216/10 , C08F8/14 , B05D5/00 , B05D3/06 , B05D3/02
CPC分类号： H01L51/052 , B05D3/06 , C08F12/22 , C08F12/24 , C08F112/14 , C08F118/12 , C08F212/14 , C08F216/10 , C08G61/02 , C09D125/18 , H01B3/442 , H01B3/447 , H01L51/004 , H01L51/0043 , H01L51/0073 , Y10T428/31938 , C08F220/14 , C08F212/32
摘要： Disclosed are polymer-based dielectric compositions (e.g., formulations) and materials (e.g. films) and associated devices. The polymers generally include photocrosslinkable pendant groups; for example, the polymers can include one or more coumarin-containing pendant groups.
摘要翻译：公开了基于聚合物的电介质组合物（例如制剂）和材料（例如膜）和相关装置。聚合物通常包括可光致交联的侧基; 例如，聚合物可以包括一种或多种含香豆素的侧基。

3. 发明授权

US08404844B2 Perylene semiconductors and methods of preparation and use thereof 有权
标题翻译：苝半导体及其制备方法及用途
公开(公告)号：US08404844B2
公开(公告)日：2013-03-26
申请号：US12866331
申请日：2009-02-05
申请人： Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler , He Yan , Antonio Facchetti , Shaofeng Lu , Yan Zheng
发明人： Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler , He Yan , Antonio Facchetti , Shaofeng Lu , Yan Zheng
IPC分类号： C07D471/08 , H01L51/50 , H01L29/02
CPC分类号： C07D471/06 , C09B5/62 , H01L51/0053 , H01L51/0541 , H01L51/0545 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： The present invention relates to semiconducting compounds, materials prepared from such compounds, methods of preparing such compounds and semiconductor materials, as well as various compositions, composites, and devices that incorporate the compounds and semiconductor materials. The semiconducting compounds can have higher electron-transport efficiency and higher solubility in common solvents compared to related representative compounds.
摘要翻译：本发明涉及半导体化合物，由这些化合物制备的材料，制备这种化合物和半导体材料的方法，以及掺入化合物和半导体材料的各种组合物，复合材料和器件。与相关的代表性化合物相比，半导体化合物可以具有较高的电子传输效率和较高的溶解度。

4. 发明授权

US09219233B2 Semiconductor materials prepared from rylene-(π-acceptor)copolymers 有权
标题翻译：由Rylene - （＆amp;受体）共聚物制备的半导体材料
公开(公告)号：US09219233B2
公开(公告)日：2015-12-22
申请号：US12865031
申请日：2009-02-05
申请人： Antonio Facchetti , Zhihua Chen , He Yan , Shaofeng Lu , Tobin J. Marks , Yan Zheng , Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler
发明人： Antonio Facchetti , Zhihua Chen , He Yan , Shaofeng Lu , Tobin J. Marks , Yan Zheng , Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler
IPC分类号： H01L51/46 , H01B1/12 , C08G61/12 , C08G61/10 , H05B33/14 , C09K11/06 , H01L51/00 , H01L51/05
CPC分类号： H01L51/0043 , C08G61/10 , C08G61/12 , C09B5/62 , C09B69/102 , C09B69/105 , C09B69/106 , C09K11/06 , C09K2211/1458 , C09K2211/1483 , H01B1/127 , H01L51/0036 , H01L51/0053 , H01L51/0094 , H01L51/0541 , H01L51/0545 , H05B33/14 , Y02E10/549 , Y02P70/521
摘要： Disclosed are new semiconductor materials prepared from rylene-(π-acceptor) copolymers. Such copolymers can exhibit high n-type carrier mobility and/or good current modulation characteristics. In addition, the polymers of the present teachings can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.
摘要翻译：公开了由二烯 - （＆amp;受体）共聚物制备的新的半导体材料。这种共聚物可表现出高的n型载流子迁移率和/或良好的电流调制特性。此外，本教导的聚合物可以具有某些加工优点，例如在环境条件下的溶液加工性和/或良好的稳定性。

5. 发明申请

US20110120558A1 SEMICONDUCTOR MATERIALS PREPARED FROM RYLENE-(PI-ACCEPTOR)COPOLYMERS 有权
标题翻译：由RYLENE（PI-ACCEPTOR）共聚物制备的半导体材料
公开(公告)号：US20110120558A1
公开(公告)日：2011-05-26
申请号：US12865031
申请日：2009-02-05
申请人： Antonio Facchetti , Zhihua Chen , He Yan , Shaofeng Lu , Tobin J. Marks , Yan Zheng , Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler
发明人： Antonio Facchetti , Zhihua Chen , He Yan , Shaofeng Lu , Tobin J. Marks , Yan Zheng , Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler
IPC分类号： H01L51/46 , C08F228/06 , H01B1/12 , C08F26/06 , H01L51/30 , H01L51/54 , H01L51/40 , H01L51/48 , H01L51/56
CPC分类号： H01L51/0043 , C08G61/10 , C08G61/12 , C09B5/62 , C09B69/102 , C09B69/105 , C09B69/106 , C09K11/06 , C09K2211/1458 , C09K2211/1483 , H01B1/127 , H01L51/0036 , H01L51/0053 , H01L51/0094 , H01L51/0541 , H01L51/0545 , H05B33/14 , Y02E10/549 , Y02P70/521
摘要： Disclosed are new semiconductor materials prepared from rylene-(π-acceptor) copolymers. Such copolymers can exhibit high n-type carrier mobility and/or good current modulation characteristics. In addition, the polymers of the present teachings can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.
摘要翻译：公开了由二烯 - （＆amp;受体）共聚物制备的新的半导体材料。这种共聚物可表现出高的n型载流子迁移率和/或良好的电流调制特性。此外，本教导的聚合物可以具有某些加工优点，例如在环境条件下的溶液加工性和/或良好的稳定性。

6. 发明申请

US20100319778A1 PERYLENE SEMICONDUCTORS AND METHODS OF PREPARATION AND USE THEREOF 有权
标题翻译： PERYLENE SEMICONDUCTORS及其制备和使用方法
公开(公告)号：US20100319778A1
公开(公告)日：2010-12-23
申请号：US12866331
申请日：2009-02-05
申请人： Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler , He Yan , Antonio Facchetti , Shaofeng Lu , Yan Zheng
发明人： Marcel Kastler , Subramanian Vaidyanathan , Florian Doetz , Silke Annika Koehler , He Yan , Antonio Facchetti , Shaofeng Lu , Yan Zheng
IPC分类号： H01L51/46 , C07D471/06 , H01L51/30 , H01L51/40
CPC分类号： C07D471/06 , C09B5/62 , H01L51/0053 , H01L51/0541 , H01L51/0545 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： The present teachings provide semiconducting compounds, materials prepared from such compounds, methods of preparing such compounds and semiconductor materials, as well as various compositions, composites, and devices that incorporate the compounds and semiconductor materials. Specifically, compounds of the present teachings can have higher electron-transport efficiency and higher solubility in common solvents compared to related representative compounds.
摘要翻译：本发明提供半导体化合物，由这些化合物制备的材料，制备这种化合物和半导体材料的方法，以及掺入化合物和半导体材料的各种组合物，复合材料和器件。具体而言，与相关的代表性化合物相比，本发明的化合物可具有较高的电子传输效率和较高的溶解度。

7. 发明申请

US20120289672A1 DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER 有权
公开(公告)号：US20120289672A1
公开(公告)日：2012-11-15
申请号：US13511890
申请日：2010-11-29
申请人： Marcel Kastler , Silke Annika Koehler , Klaus Muellen , Ralph Rieger
发明人： Marcel Kastler , Silke Annika Koehler , Klaus Muellen , Ralph Rieger
IPC分类号： C08G75/00 , H01L51/40 , H01B1/12
CPC分类号： H01L51/0043 , C08G61/126 , C08G2261/124 , C08G2261/3223 , C08G2261/3243 , C08G2261/414 , C08G2261/92 , H01L51/0036 , H01L51/0558 , Y02E10/549
摘要： Dithienobenzo-thieno[3,2-b]thiophene-copolymers of the formula (I) wherein: pi is a monocyclic or polycyclic moiety optionally substituted with 1-4 Ra groups, wherein Ra, at each occurrence, is independently hydrogen or a) a halogen, b) —(CN, c) —NO2, d) oxo, e) —OH, f) ═C(Rb)2; g) a C1-20 alkyl group, h) a C2-20 alkenyl group, i) a C2-20 alkynyl group, j) a C1-20 alkoxy group, k) a C1-20 alkylthio group, l) a C1-20 haloalkyl group, m) a —Y—C3-10 cycloalkyl group, n) a —Y—C6-14 aryl group, o) a —Y-3-12 membered cycloheteroalkyl group, or p) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl or haloaryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 Rb groups; Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and R1, R2, R3, at each occurrence, are independently H, a halogen, CN, a C1-30 alkyl group, a C2-30 alkenyl group, a C1-30 haloalkyl group, a C2-30 alkynyl group, a C1-30 alkoxy group, a C(O)—C1-20 alkyl group, a C(O)—OC1-20 alkyl group, a Y—C3-10 cycloalkyl group, a —Y-3-12 membered cycloheteroalkyl group, each optionally substituted with 1-5 substituents selected from a halogen, —CN, a C1-6 alkyl group, a C1-6 alkoxy group, and a C1-6 haloalkyl group, -L-Ar1, -L-Ar1-—Ar1, -L-Ar1—R4, or -L-Ar1—Ar1—R4 and Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; n=0, 1, 2; and o=1-1000.

8. 发明授权

US08853820B2 Crosslinkable dielectrics and methods of preparation and use thereof 有权
标题翻译：可交联电介质及其制备方法及用途
公开(公告)号：US08853820B2
公开(公告)日：2014-10-07
申请号：US13322252
申请日：2010-05-20
申请人： Marcel Kastler , Silke Annika Koehler
发明人： Marcel Kastler , Silke Annika Koehler
IPC分类号： H01L29/78 , H01L51/30 , H01L51/05 , H01L23/498 , H01G4/18 , H01G4/33
CPC分类号： H01L51/052 , H01G4/18 , H01G4/33 , H01L23/49894 , H01L51/0043 , H01L51/0545 , H01L2251/308 , H01L2924/0002 , H01L2924/00
摘要： The present invention relates to an electronic device comprising at least one dielectric layer, said dielectric layer comprising a crosslinked organic compound based on at least one compound which is radically crosslinkable and a method of making the electronic device.
摘要翻译：本发明涉及包含至少一个电介质层的电子器件，所述电介质层包含基于至少一种可自由交联的化合物的交联有机化合物和制备该电子器件的方法。

9. 发明申请

US20120088900A1 PROCESS FOR PREPARING REGIOREGULAR POLY-(3-SUBSTITUTED) THIOPHENES, SELENOPHENES, THIAZOLES AND SELENAZOLES 失效
标题翻译：制备邻苯二酚（3-取代的）噻吩，苯丙烯，噻唑和精油的方法
公开(公告)号：US20120088900A1
公开(公告)日：2012-04-12
申请号：US13378069
申请日：2010-06-14
申请人： Marcel Kastler , Silke Annika Koehler
发明人： Marcel Kastler , Silke Annika Koehler
IPC分类号： C08G75/00
CPC分类号： H01B1/127 , C08G61/123 , C08G61/126 , C08G2261/3223 , C08G2261/3225 , C08G2261/3229 , C08G2261/323 , C08G2261/416 , C08G2261/417 , H01L51/0036
摘要： A process for preparing a regioregular homopolymer or copolymer of 3-substituted thiophene, 3-substituted selenophene, 3-substituted thiazol or 3-substituted selenazol by a) reacting a 3-substituted 2,5-dihalothiophene, 2,5-dihaloselenophene, 2,5-dihalothiazol or 2,5-dihaloselenazol with reactive zinc, magnesium and/or an organomagnesium halide to give an organozinc or organomagnesium intermediate containing one halozinc or one halomagnesium group, b) bringing the organozinc or the organomagnesium intermediate into contact with a Ni(II), Ni(O), Pd(II) or Pd(O) catalyst to initiate the polymerization reaction, and c) polymerizing the organozinc or the organomagnesium intermediate to give a regioregular head-to-tail homopolymer or copolymer of 3-substituted thiophene, 3-substituted selenophene, 3-substituted thiazol or 3-substituted selenazol characterized in that the polymerization reaction is carried out at a temperature rising from a lower temperature T1 to a higher temperature T2 during a time t1, wherein T1 is in the range of from −40 to 5 ° C. and T2 is in the range of from −20 to 40 ° C., wherein T2−T1 is at least 10 ° C. and the average rate of increase (T2−T1)/t1 is in the range of from 0.05 ° C/min to 1 ° C/min.
摘要翻译：制备3-取代噻吩，3-取代的硒吩，3-取代的噻唑或3-取代的硒吩的区域性均聚物或共聚物的方法，通过以下步骤a）使3-取代的2,5-二卤代噻吩，2,5-二卤代硒吩，2 ，5-二卤噻唑或2,5-二卤代硒唑与反应性锌，镁和/或有机卤化镁反应，得到含有一个卤素或一个卤代镁基团的有机锌或有机镁中间体，b）使有机锌或有机镁中间体与Ni （II），Ni（O），Pd（II）或Pd（O）催化剂以引发聚合反应，以及c）使有机锌或有机镁中间体聚合，得到区域性的头 - 尾均聚物或3- 取代噻吩，3-取代硒吩，3-取代噻唑或3-取代硒吩，其特征在于聚合反应在从较低温度T1升高至更高温度T2 dur的温度下进行时间t1，其中T1在-40至5℃的范围内，T2在-20至40℃的范围内，其中T2-T1至少为10℃，平均值为增加率（T2-T1）/ t1在0.05℃/分钟至1℃/分钟的范围内。

10. 发明授权

US08653227B2 Process for preparing regioregular poly-(3-substituted) thiophenes, selenophenes, thiazoles and selenazoles 失效
标题翻译：制备区域性聚（3-取代）噻吩，硒吩，噻唑和硒唑的方法
公开(公告)号：US08653227B2
公开(公告)日：2014-02-18
申请号：US13378069
申请日：2010-06-14
申请人： Marcel Kastler , Silke Annika Koehler
发明人： Marcel Kastler , Silke Annika Koehler
IPC分类号： C08G75/00
CPC分类号： H01B1/127 , C08G61/123 , C08G61/126 , C08G2261/3223 , C08G2261/3225 , C08G2261/3229 , C08G2261/323 , C08G2261/416 , C08G2261/417 , H01L51/0036
摘要： A process for preparing a regioregular homopolymer or copolymer of 3-substituted thiophene, 3-substituted selenophene, 3-substituted thiazol or 3-substituted selenazol by a) reacting a 3-substituted 2,5-dihalothiophene, 2,5-dihaloselenophene, 2,5-dihalothiazol or 2,5-dihaloselenazol with reactive zinc, magnesium and/or an organomagnesium halide to give an organozinc or organomagnesium intermediate containing one halozinc or one halomagnesium group, b) bringing the organozinc or the organomagnesium intermediate into contact with a Ni(II), Ni(O), Pd(II) or Pd(0) catalyst to initiate the polymerization reaction, and c) polymerizing the organozinc or the organomagnesium intermediate to give a regioregular head-to-tail homopolymer or copolymer of 3-substituted thiophene, 3-substituted selenophene, 3-substituted thiazol or 3-substituted selenazol characterized in that the polymerization reaction is carried out at a temperature rising from a lower temperature T1 to a higher temperature T2 during a time t1, wherein T1 is in the range of from −40 to 5° C. and T2 is in the range of from −20 to 40° C., wherein T2−T1 is at least 10° C. and the average rate of increase (T2−T1)/t1 is in the range of from 0.05° C./min to 1° C./min.
摘要翻译：制备3-取代噻吩，3-取代的硒吩，3-取代的噻唑或3-取代的硒吩的区域性均聚物或共聚物的方法，通过以下步骤a）使3-取代的2,5-二卤代噻吩，2,5-二卤代硒吩，2 ，5-二卤噻唑或2,5-二卤代硒唑与反应性锌，镁和/或有机卤化镁反应，得到含有一个卤素或一个卤代镁基团的有机锌或有机镁中间体，b）使有机锌或有机镁中间体与Ni （II），Ni（O），Pd（II）或Pd（O）催化剂以引发聚合反应，和c）使有机锌或有机镁中间体聚合，得到区域性的头 - 尾均聚物或3- 取代噻吩，3-取代硒吩，3-取代噻唑或3-取代硒吩，其特征在于聚合反应在从较低温度T1升高至更高温度T2 dur的温度下进行时间t1，其中T1在-40至5℃的范围内，T2在-20至40℃的范围内，其中T2-T1至少为10℃，平均值为增加率（T2-T1）/ t1在0.05℃/分钟至1℃/分钟的范围内。

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