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1. 发明授权

US07691924B2 Flame retardant thermoplastic resin composition 有权
标题翻译：阻燃热塑性树脂组合物
公开(公告)号：US07691924B2
公开(公告)日：2010-04-06
申请号：US11507030
申请日：2006-08-21
申请人： Jong-Cheol Lim , Sang Hyun Hong , Kyung-Hoon Seo , Sam-Joo Yang
发明人： Jong-Cheol Lim , Sang Hyun Hong , Kyung-Hoon Seo , Sam-Joo Yang
IPC分类号： C08K5/357 , C08K5/5399 , C08K5/521
CPC分类号： C08F279/02 , C08F279/04 , C08K5/5399 , C08L21/00 , C08L25/00 , C08L27/12 , C08L33/00 , C08L35/06 , C08L51/04 , C08L55/02 , C08L69/00 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： The present invention relates to a flame retardant polycarbonate thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified vinyl-grafted copolymer, a phosphorous mixture of a cyclic phosphazene oligomer compound and a phosphate ester morpholide compound or a phosphoric acid ester as a flame retardant, and, optionally, a fluorinated polyolefin resin, which has good flame retardancy, heat resistance, mechanical strength, impact strength, heat stability, processability, and appearance.
摘要翻译：本发明涉及一种阻燃聚碳酸酯热塑性树脂组合物，其包含聚碳酸酯树脂，橡胶改性的乙烯基接枝共聚物，环状磷腈低聚物化合物和磷酸酯吗啉化合物的磷混合物或磷酸酯作为阻燃剂和可选地具有良好的阻燃性，耐热性，机械强度，冲击强度，热稳定性，加工性和外观的氟化聚烯烃树脂。

2. 发明授权

US07138445B2 Flame retardant thermoplastic resin composition 失效
标题翻译：阻燃热塑性树脂组合物
公开(公告)号：US07138445B2
公开(公告)日：2006-11-21
申请号：US10731757
申请日：2003-12-08
申请人： Jae Ho Yang , Sang Hyun Hong , Gyu Chul Lee , Bok Nam Jang , Young Gil Jang , Sung Hee Ahn , Su Hak Bae , Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
发明人： Jae Ho Yang , Sang Hyun Hong , Gyu Chul Lee , Bok Nam Jang , Young Gil Jang , Sung Hee Ahn , Su Hak Bae , Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
IPC分类号： C08K5/5399 , C08L25/00 , C08L69/00 , C08L71/12
CPC分类号： C08L77/00 , C07F9/6533 , C08F279/02 , C08F279/04 , C08K5/06 , C08K5/1515 , C08K5/49 , C08K5/523 , C08K5/5399 , C08L25/12 , C08L27/18 , C08L33/06 , C08L51/04 , C08L53/00 , C08L55/02 , C08L61/06 , C08L61/14 , C08L67/02 , C08L69/00 , C08L71/12 , C08L71/123 , C08L77/02 , C08L77/06 , C08L2666/02 , C08L2666/14 , C08L2666/24 , C08L2666/04 , C08L2666/16 , C08L61/04 , C08L71/00
摘要： The present invention relates to a flame retardant thermoplastic resin composition that contains a phenol resin derivative having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of a phenol resin derivative, and (C) about 0.1˜50 parts by weight of a phosphoric acid ester morpholide compound or a mixture of phosphoric acid ester morpholide compounds. Another flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of polyphenylene ether, (C) about 0.1˜100 parts by weight of a phenol resin derivative, and (D) about 0.1˜50 parts by weight of a phosphoric acid ester morpholide compound or a mixture of phosphoric acid ester morpholide compounds. The thermoplastic resin composition containing polyphenylene ether resin may also contain up to 5.0 parts by weight of an anti-dripping agent based on 100 parts by weight of the base resin.
摘要翻译：本发明涉及一种阻燃热塑性树脂组合物，其含有具有良好的成型性的酚醛树脂衍生物，而与基础树脂无关。根据本发明的阻燃热塑性树脂组合物包含（A）100重量份作为基础树脂的热塑性树脂，（B）约0.1〜100重量份的酚醛树脂衍生物，和（C）约0.1 约50重量份的磷酸酯吗啉化合物或磷酸酯吗啉化合物的混合物。根据本发明的另一种阻燃热塑性树脂组合物包含（A）100重量份作为基础树脂的热塑性树脂，（B）约0.1〜100重量份的聚苯醚，（C）约0.1〜100重量份的酚醛树脂衍生物，和（D）约0.1〜50重量份的磷酸酯吗啉化合物或磷酸酯吗啉化合物的混合物。含有聚苯醚树脂的热塑性树脂组合物还可以含有最多5.0重量份的基于100重量份的基础树脂的防滴剂。

3. 发明授权

US06437029B1 Flame retardant polycarbonate resin composition 有权
公开(公告)号：US06437029B1
公开(公告)日：2002-08-20
申请号：US09752814
申请日：2000-12-29
申请人： Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
发明人： Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
IPC分类号： C08L6900
CPC分类号： C08K5/5399 , C07F9/6533 , C08F279/02 , C08F279/04 , C08K5/523 , C08L25/12 , C08L27/18 , C08L33/06 , C08L51/04 , C08L55/02 , C08L69/00 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The present invention relates to a flame retardant thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified styrene-grafted copolymer, a styrene-containing copolymer, a (meth)acrylic acid ester copolymer, a phosphoric acid ester as a flame retardant and a fluorinated polyolefin resin, which does not show coalescence of the domain resin that might be caused by the low viscosity at a high temperature, and poor flame retardancy, weld-line strength and mechanical properties such as impact strength, and which has a good balance of physical properties such as impact strength, heat resistance, heat stability, processability and appearance.

4. 发明授权

US06900256B2 Thermoplastic resin compositions containing polyphosphate ester morpholides as flame retardants 有权
标题翻译：含有聚磷酸酯吗啉作为阻燃剂的热塑性树脂组合物
公开(公告)号：US06900256B2
公开(公告)日：2005-05-31
申请号：US10223450
申请日：2002-08-19
申请人： Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
发明人： Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
IPC分类号： C08J5/00 , C07F9/6533 , C08F279/02 , C08F279/04 , C08K5/521 , C08K5/523 , C08K5/5399 , C08L25/00 , C08L25/12 , C08L27/12 , C08L27/18 , C08L33/04 , C08L33/06 , C08L51/00 , C08L51/04 , C08L55/02 , C08L69/00 , C08L71/12
CPC分类号： C08K5/5399 , C07F9/6533 , C08F279/02 , C08F279/04 , C08K5/523 , C08L25/12 , C08L27/18 , C08L33/06 , C08L51/04 , C08L55/02 , C08L69/00 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The present invention relates to polyphosphate ester morpholides, compositions comprising mixtures thereof and thermoplastic resin compositions containing the polyphosphate ester morpholide composition as a flame retardant. The flame retardant compositions comprise mixtures of polyphosphate ester morpholides which are represented by the following general formula I: in which X is 1 or 2; R1 is a C6-C20 aryl group, an alkyl substituted C6-C20 aryl group or a derivative thereof; R2 is a C6-C30 arylene group, an alkyl substituted C6-C30 arylene group or a derivative thereof; n is the average number of morpholide repeating units, m is the average number of R1 repeating units, and n+m is 1 to 5. In accordance with the present invention, it is possible to provide a flame retardant thermoplastic resin compositions having improved flame retardancy even when small amounts of the flame retardant are used. The thermoplastic compositions according to the present invention also have a desirable balance of properties such as workability, impact strength, heat resistance, appearance and the like.
摘要翻译：本发明涉及多磷酸酯吗啉，包含其混合物的组合物和含有聚磷酸酯吗啉化合物作为阻燃剂的热塑性树脂组合物。阻燃剂组合物包含由以下通式I表示的聚磷酸酯吗啉的混合物：其中X为1或2; R 1是C 6 -C 20芳基，烷基取代的C 6 -C 20芳基， 20芳基或其衍生物; R 2是C 6 -C 30亚芳基，烷基取代的C 6 -C 30亚烷基，亚芳基或其衍生物; n是平均的吗啉重复单元数，m是R 1重复单元的平均数，n + m是1〜5。根据本发明，可以提供一种阻燃热塑性树脂组合物即使使用少量的阻燃剂也具有改善的阻燃性。根据本发明的热塑性组合物还具有所需的性能平衡，例如可加工性，冲击强度，耐热性，外观等。

5. 发明授权

US06576161B2 Polyphosphate ester morpholides, mixtures thereof, and thermoplastic resin compositions containing polyphosphate ester morpholides as flame retardants 有权
标题翻译：聚磷酸酯吗啉，其混合物和含有聚磷酸酯吗啉作为阻燃剂的热塑性树脂组合物
公开(公告)号：US06576161B2
公开(公告)日：2003-06-10
申请号：US09997781
申请日：2001-11-28
申请人： Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
发明人： Jong-Cheol Lim , Kyung-Hoon Seo , Sam-Joo Yang
IPC分类号： C08K551
CPC分类号： C08K5/5399 , C07F9/6533 , C08F279/02 , C08F279/04 , C08K5/523 , C08L25/12 , C08L27/18 , C08L33/06 , C08L51/04 , C08L55/02 , C08L69/00 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The present invention relates to polyphosphate ester morpholides, compositions comprising mixtures thereof and thermoplastic resin compositions containing the polyphosphate ester morpholide composition as a flame retardant. The flame retardant compositions comprise mixtures of polyphosphate ester morpholides which are represented by the following general formula I: in which X is 1 or 2; R1 is a C6-C20 aryl group, an alkyl substituted C6-C20 aryl group or a derivative thereof; R2 is a C6-C30 arylene group, an alkyl substituted C6-C30 arylene group or a derivative thereof; n is the average number of morpholide repeating units, m is the average number of R1 repeating units, and n+m is 1 to 5. In accordance with the present invention, it is possible to provide a flame retardant thermoplastic resin compositions having improved flame retardancy even when small amounts of the flame retardant are used. The thermoplastic compositions according to the present invention also have a desirable balance of properties such as workability, impact strength, heat resistance, appearance and the like.
摘要翻译：本发明涉及多磷酸酯吗啉，包含其混合物的组合物和含有聚磷酸酯吗啉化合物作为阻燃剂的热塑性树脂组合物。阻燃剂组合物包含由以下通式I表示的聚磷酸酯吗啉的混合物：其中X为1或2; R1是C6-C20芳基，烷基取代的C6-C20芳基或其衍生物; R2是C6-C30亚芳基，烷基取代的C6-C30亚芳基或其衍生物; n是平均的吗啉重复单元数，m是R1重复单元的平均数，n + m是1〜5。根据本发明，可以提供具有改进的火焰的阻燃性热塑性树脂组合物即使使用少量的阻燃剂也是阻燃性的。根据本发明的热塑性组合物还具有所需的性能平衡，例如可加工性，冲击强度，耐热性，外观等。

6. 发明授权

US5643981A Flameproof thermoplastic resin compositions 失效
标题翻译：防火热塑性树脂组合物
公开(公告)号：US5643981A
公开(公告)日：1997-07-01
申请号：US333073
申请日：1994-11-01
申请人： Sam-Joo Yang , Bok-Nam Jang
发明人： Sam-Joo Yang , Bok-Nam Jang
IPC分类号： C08K5/521 , C08K3/00 , C08L27/12 , C08L55/02 , C08L69/00 , C08K5/523 , C08L51/00
CPC分类号： C08L69/00 , C08L27/12 , C08L55/02
摘要： The flameproof thermoplastic resin compositions of this invention comprise from 2 to 20 parts by weight of aromatic diphosphates, from 2 to 7 parts by weight of phosphorous compounds and from 0.1 to 2.0 parts by weight of polyfluoroalkyl resins per 100 parts by weight of the resin mixture consisting of from 60 to 98% by weight of polycarbonate resins, from 2 to 40% by weight of styrene-containing graft copolymer resins, and from 0 to 20% by weight of styrene-containing copolymer resins. The structural formula of said aromatic diphosphates is as follows (I): ##STR1## in which, R.sup.1 and R.sup.2 are same or different lower alkyls, R.sup.3 and R.sup.4 are same or different hydrogen atom or alkyl groups, Y is a single bond or --CH.sub.2 --, --C(CH.sub.3).sub.2 --, --S--, --SO.sub.2 --, --O--, --CO--, or --N.dbd.N--, k is 0 or 1, and m is an integer of 0 to 4.
摘要翻译：本发明的防火热塑性树脂组合物包含2至20重量份芳族二磷酸酯，2至7重量份磷化合物和0.1至2.0重量份多氟烷基树脂/ 100重量份树脂混合物由60至98重量％的聚碳酸酯树脂，2至40重量％的含苯乙烯的接枝共聚物树脂和0至20重量％的含苯乙烯的共聚物树脂组成。所述芳族二磷酸酯的结构式如下（Ⅰ）：其中R1和R2是相同或不同的低级烷基，R3和R4是相同或不同的氢原子或烷基，Y 是单键或-CH 2 - ， - C（CH 3）2 - ， - S - ， - SO 2 - ， - O - ， - CO-或-N = N-，k是0或1，m是 0到4的整数。

7. 发明授权

US5674924A Flameproof thermoplastic resin compositions 失效
标题翻译：防火热塑性树脂组合物
公开(公告)号：US5674924A
公开(公告)日：1997-10-07
申请号：US573464
申请日：1995-12-15
申请人： Kyu-Cheol Lee , Sam-Joo Yang , Bok-Nam Jang
发明人： Kyu-Cheol Lee , Sam-Joo Yang , Bok-Nam Jang
IPC分类号： C08K5/523 , C08L25/02 , C08L27/12 , C08L69/00 , C08K5/521 , C08L55/02
CPC分类号： C08K5/523 , C08L69/00 , C08L25/02 , C08L27/12 , Y10S525/902
摘要： The present invention relates to flameproof thermoplastic resin compositions comprising (A) a base resin consisting of (1) 80 to 96% by weight of a thermoplastic, halogen-free polycarbonate, and (2) 4 to 20% by weight of a core-shell type ABS resin with a graft index of 40 or above, which is obtained by grafting 25 to 45% by weight of a styrene and 10 to 15% by weight of an acrylonitrile onto 45 to 60% by weight of a butadiene rubber, (B) 5 to 20 parts by weight, per 100 parts by weight of the base resin(A), of a phosphate composition, and (C) 0.1 to 2.0 parts by weight, per 100 parts by weight of the base resin(A), of a perfluoroalkane polymer. The phosphate composition is represented as the general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 independently of one another are C.sub.6 -C.sub.20 aryl or alkyl-substituted C.sub.6 -C.sub.20 aryl, n is 0 to 5, and the average n of the phosphate composition is, n is 0 to 5, about 0.3 to 0.8.
摘要翻译：本发明涉及防火热塑性树脂组合物，其包含（A）由（1）80至96重量％的热塑性无卤聚碳酸酯和（2）4至20重量％的芯 - 接枝率为40以上的壳型ABS树脂，其通过将25〜45重量％的苯乙烯和10〜15重量％的丙烯腈接枝到45〜60重量％的丁二烯橡胶中而获得（ B）相对于100重量份基础树脂（A）为5〜20重量份，磷酸酯组合物为100重量份，（C）为0.1〜2.0重量份，相对于100重量份的基础树脂（A）的全氟烷烃聚合物。磷酸酯组合物由通式（I）表示：其中R 1，R 2，R 3，R 4和R 5彼此独立地是C 6 -C 20芳基或烷基取代的C 6 -C 20芳基，n是 0〜5，磷酸盐组合物的平均n为，n为0〜5，约0.3〜0.8。

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