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    • 8. 发明授权
    • Paint composition for under coating
    • 涂层组合物
    • US4826895A
    • 1989-05-02
    • US139616
    • 1987-12-30
    • Hiroshi KanaiJoji OkaHidehiko Kojo
    • Hiroshi KanaiJoji OkaHidehiko Kojo
    • C09D5/00C08G59/06C08G59/14C08G59/56C09D163/00C08K3/36
    • C08G59/56C08G59/066C08G59/1422C09D163/00
    • The paint composition for under coating of the present invention comprises 60 to 90% by weight of an epoxy polyol resin optionally together with a hardener therefor and 10 to 40% by weight of silica particles. Said epoxy polyol resin is obtained by reacting an optionally substituted glycidyl-etherified product of an alkylene oxide adduct of a dihydric phenol with a phosphorus acid having at least one P--OH bond, an ester or a salt thereof to thereby give a precondensate, reacting said precondensate with a dihydric phenol to give an epoxy resin of a high molecular weight, and further reacting said epoxy resin with a compound having an amino group capable of reacting with an epoxy group. Said silica particles comprise a primary particle having an average particle size of 1 to 10 m.mu., a surface area of 270 m.sup.2 /g or above and a concentration of silanol groups on the particle surface of 0.25 mM/100 m.sup.2 or above.
    • 本发明的底涂层用涂料组合物含有60〜90重量%的环氧多元醇树脂,任选地与其硬化剂一起,还含有10〜40重量%的二氧化硅粒子。 所述环氧多元醇树脂是通过使任意取代的二元酚的烯化氧加成物的缩水甘油醚化产物与具有至少一个P-OH键的磷酸,其酯或其盐反应得到预缩合物,使 与二元酚预缩合得到高分子量的环氧树脂,并进一步使所述环氧树脂与具有与环氧基反应的氨基的化合物反应。 所述二氧化硅粒子包含平均粒径为1〜10μm,表面积为270m 2 / g以上的一次粒子,粒子表面的硅烷醇基浓度为0.25mM / 100m 2以上。