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1. 发明授权

US5066757A One-can heat-curable resin compositions and precoated metal 失效
标题翻译：单罐热固化树脂组合物和预涂金属
公开(公告)号：US5066757A
公开(公告)日：1991-11-19
申请号：US460552
申请日：1990-01-03
申请人： Shigeaki Miyabayashi , Takuro Sakamoto , Hiroshi Kanai , Joji Oka
发明人： Shigeaki Miyabayashi , Takuro Sakamoto , Hiroshi Kanai , Joji Oka
IPC分类号： C09D175/04 , B05D7/14 , B05D7/24 , B32B15/08 , C08G18/40 , C08G18/42 , C08G18/58 , C08G18/80 , C09D175/00 , C09D175/06
CPC分类号： C08G18/8061 , C08G18/4081 , C08G18/8003 , C09D175/06
摘要： A one-can heat-curable resin composition which comprises: (1) a polyester polyol having at least three functional groups; (2) an adduct of an epoxy resin with at least one member selected from the group consisting of an alkanol amine and a monovalent phenol; and (3) a blocked organic polyisocyanate or a blocked prepolymer having terminal NCO groups obtained by reaction of an organic polyisocyanate with an active hydrogen-containing compound, when used in the production of precoated metal, gives good coated plates, which can be advantageously used in manufacturing household electric appliances and so on.
摘要翻译：一种可热固化树脂组合物，其包含：（1）具有至少三个官能团的聚酯多元醇; （2）环氧树脂与选自链烷醇胺和一价酚的至少一种的加成物; 和（3）当用于预涂金属的生产中使用时，通过有机多异氰酸酯与活性含氢化合物的反应获得的具有末端NCO基团的封端有机聚异氰酸酯或封端预聚物得到良好的涂层板，其可以有利地使用在制造家用电器等方面。

2. 发明授权

US4880891A One-can thermosetting resin compositions and precoated metal 失效
标题翻译：单罐热固性树脂组合物和预涂金属
公开(公告)号：US4880891A
公开(公告)日：1989-11-14
申请号：US200378
申请日：1988-05-31
申请人： Shigeaki Miyabayashi , Yoshikatsu Matsuura , Hiroshi Kanai , Joji Oka
发明人： Shigeaki Miyabayashi , Yoshikatsu Matsuura , Hiroshi Kanai , Joji Oka
IPC分类号： B05D7/14 , B05D7/24 , C08G18/10 , C08G18/42 , C08G18/73 , C08G18/75 , C08G18/76 , C08G18/80 , C09D175/00 , C09D175/06
CPC分类号： C08G18/8077 , C08G18/10 , C08G18/4241 , C08G18/758 , C08G18/765 , C08G18/8061 , Y10T428/31605
摘要： A one-can thermosetting resin composition comprising (1) a polyester polyol obtained by allowing an aliphatic dicarboxylic acid to react with an aliphatic glycol and polyol having at least three functional groups and (2) a blocked product of .alpha.,.alpha.,.alpha.'.alpha.'-tetramethyl-xylylene diisocyanate or 4,4'-methylene bis (cyclohexyl isocyanate), or a blocked product of an NCO-terminated prepolymer obtained by allowing .alpha.,.alpha.,.alpha.'.alpha.'-tetramethylxylylene diisocyanate and/or 4,4'-methylene bis(cyclohexylisocyanate) to react with an active hydrogen compound, gives tough coating films in yellowing and thermal degradation, and also exhibits increased hardness as well as high flexibility, stain resistance and chemical resistance. Especially, when the resin composition is used for preparing precoated metals, it gives good steel plates, thus being advantageously utilized for, among others, light electric appliances.
摘要翻译：一种单罐热固性树脂组合物，其包含（1）通过使脂族二羧酸与具有至少三个官能团的脂族二醇和多元醇反应得到的聚酯多元醇和（2）α，α，α' 或四甲基亚二甲苯基二异氰酸酯或4,4'-亚甲基双（环己基异氰酸酯）或NCO-封端的预聚物的封闭产物，其通过使α，α，α'-四甲基亚二甲苯基二异氰酸酯和/或4,4' 亚甲基双（环己基异氰酸酯）与活性氢化合物反应，产生黄色和热降解的韧性涂膜，并且还显示出增加的硬度以及高柔韧性，耐污性和耐化学性。特别是，当树脂组合物用于制备预涂金属时，它提供了良好的钢板，因此有利地用于轻型电器。

3. 发明授权

US4880890A One-can thermosetting resin compositions and precoated metal 失效
标题翻译：单罐热固性树脂组合物和预涂金属
公开(公告)号：US4880890A
公开(公告)日：1989-11-14
申请号：US200377
申请日：1988-05-31
申请人： Shigeaki Miyabayashi , Yoshikatsu Matsuura , Hiroshi Kanai , Joji Oka
发明人： Shigeaki Miyabayashi , Yoshikatsu Matsuura , Hiroshi Kanai , Joji Oka
IPC分类号： B05D7/14 , B05D7/24 , C08G18/10 , C08G18/42 , C08G18/73 , C08G18/75 , C08G18/80
CPC分类号： C08G18/8077 , C08G18/10 , C08G18/4241 , C08G18/73 , C08G18/757 , Y10T428/31605
摘要： A one-can thermosetting resin composition comprising (A) a blocked product of hexamethylene diisocyanate or bis(isocyanatomethyl)cyclohexane, or a blocked product of an adduct of hexamethylene diisocyanate or bis(isocyanatomethyl)cyclohexane and (B) a polyester polyol having at least three functional groups, gives tough coating films in yellowing and thermal degradation, and also exhibits increased hardness as well as high flexibility, stain resistance and chemical resistance. Especially, when the resin composition is used for preparing precoated metals, it gives good steel plates, thus being advantageously utilized for, among others, light electric appliances.
摘要翻译：一种单罐热固性树脂组合物，其包含（A）六亚甲基二异氰酸酯或双（异氰酸甲酯基）环己烷的封端产物或六亚甲基二异氰酸酯或双（异氰酸酯基甲基）环己烷的加合物的封闭产物和（B）至少具有三个官能团，呈现黄色和热降解的韧性涂膜，并且还显示出增加的硬度以及高柔韧性，耐污性和耐化学性。特别是，当树脂组合物用于制备预涂金属时，它提供了良好的钢板，因此有利地用于轻型电器。

4. 发明授权

US4861672A One-can heat-curable resin compositions and precoated metal 失效
标题翻译：单罐热固化树脂组合物和预涂金属
公开(公告)号：US4861672A
公开(公告)日：1989-08-29
申请号：US218298
申请日：1988-07-13
申请人： Shigeaki Miyabayashi , Hiroshi Kanai , Joji Oka , Yoshikatsu Matsuura
发明人： Shigeaki Miyabayashi , Hiroshi Kanai , Joji Oka , Yoshikatsu Matsuura
IPC分类号： B08B3/04 , B05D7/14 , B05D7/24 , B08B9/02 , B08B9/027 , C08G18/40 , C08G18/42 , C08G18/58 , C08G18/64 , C08G18/80 , C09D175/00 , C09D175/06
CPC分类号： C08G18/4081 , C08G18/4219 , C08G18/6407 , C08G18/8025 , C08G18/8061 , C08G18/8077 , Y10T428/31605 , Y10T428/31681 , Y10T428/31786
摘要： A one-can heat-curable resin composition which comprises: (1) a polyester polyol having at least three functional groups; (2) an adduct of an epoxy resin having at least one secondary hydroxyl group with a lactone compound or an alkylene oxide; and (3) a blocked organic polyisocyanate or a product of blocking of a prepolymer having terminal NCO groups obtained by reacting an organic polyisocyanate and an active hydrogen-containing compound, gives a tough and durable coat film showing no yellowing or thermal degradation due to heating at all.Furthermore, said film has a high hardness and is excellent in processability and staining resistance, particularly in mustard staining resistance. In particular, the composition, when used in the production of precoated metal, gives good coated steel sheets, which can be advantageously used in manufacturing household electric appliances and so on.
摘要翻译：一种可热固化树脂组合物，其包含：（1）具有至少三个官能团的聚酯多元醇; （2）具有至少一个仲羟基的环氧树脂与内酯化合物或烯化氧的加成物; 和（3）封闭的有机多异氰酸酯或通过使有机多异氰酸酯和含活性氢化合物反应获得的具有末端NCO基团的预聚物的封闭产物，得到坚固且耐用的涂膜，其不会由于加热而显示不发黄或热降解在所有此外，所述膜具有高硬度，加工性和耐污染性优异，特别是芥末耐染色性。特别地，组合物在用于预涂金属的制造中使用时，可以得到良好的涂层钢板，其可以有利地用于制造家用电器等。

5. 发明授权

US5166288A Coating composition for coating metal plate 失效
标题翻译：涂层金属板涂料组合物
公开(公告)号：US5166288A
公开(公告)日：1992-11-24
申请号：US456750
申请日：1989-12-26
申请人： Hiroshi Kanai , Joji Oka , Takao Hirayama , Tsuneo Tanuma
发明人： Hiroshi Kanai , Joji Oka , Takao Hirayama , Tsuneo Tanuma
IPC分类号： C09D167/02 , C08L67/00 , C09D167/00
CPC分类号： C09D167/00
摘要： A coating composition for coating a metal plate, and containing (i) 100 parts by weight of a polyester-melamine resin composed of (a) a polyester resin having a glass transition temperature of 5.degree. to 40.degree. C. and a number average molecular weight of 15,000 to 30,000 and (b) a melamine resin at a weight ratio (a)/(b) of 75/25 to 55/45 and (ii) 1 to 2 parts by weight of an amine-blocked derivative of a long-chain alkylbenzenesulfonic acid.
摘要翻译：一种用于涂覆金属板的涂料组合物，并且包含（i）100重量份由（a）玻璃化转变温度为5至40℃的聚酯树脂和数均分子量的聚酯 - 三聚氰胺树脂重量比为15,000至30,000，和（b）以重量比（a）/（b）为75/25至55/45的三聚氰胺树脂和（ii）1至2重量份长的胺封闭的衍生物链烷基苯磺酸。

6. 发明授权

US4826895A Paint composition for under coating 失效
标题翻译：涂层组合物
公开(公告)号：US4826895A
公开(公告)日：1989-05-02
申请号：US139616
申请日：1987-12-30
申请人： Hiroshi Kanai , Joji Oka , Hidehiko Kojo
发明人： Hiroshi Kanai , Joji Oka , Hidehiko Kojo
IPC分类号： C09D5/00 , C08G59/06 , C08G59/14 , C08G59/56 , C09D163/00 , C08K3/36
CPC分类号： C08G59/56 , C08G59/066 , C08G59/1422 , C09D163/00
摘要： The paint composition for under coating of the present invention comprises 60 to 90% by weight of an epoxy polyol resin optionally together with a hardener therefor and 10 to 40% by weight of silica particles. Said epoxy polyol resin is obtained by reacting an optionally substituted glycidyl-etherified product of an alkylene oxide adduct of a dihydric phenol with a phosphorus acid having at least one P--OH bond, an ester or a salt thereof to thereby give a precondensate, reacting said precondensate with a dihydric phenol to give an epoxy resin of a high molecular weight, and further reacting said epoxy resin with a compound having an amino group capable of reacting with an epoxy group. Said silica particles comprise a primary particle having an average particle size of 1 to 10 m.mu., a surface area of 270 m.sup.2 /g or above and a concentration of silanol groups on the particle surface of 0.25 mM/100 m.sup.2 or above.
摘要翻译：本发明的底涂层用涂料组合物含有60〜90重量％的环氧多元醇树脂，任选地与其硬化剂一起，还含有10〜40重量％的二氧化硅粒子。所述环氧多元醇树脂是通过使任意取代的二元酚的烯化氧加成物的缩水甘油醚化产物与具有至少一个P-OH键的磷酸，其酯或其盐反应得到预缩合物，使与二元酚预缩合得到高分子量的环氧树脂，并进一步使所述环氧树脂与具有与环氧基反应的氨基的化合物反应。所述二氧化硅粒子包含平均粒径为1〜10μm，表面积为270m 2 / g以上的一次粒子，粒子表面的硅烷醇基浓度为0.25mM / 100m 2以上。

7. 发明申请

US20120040194A1 SURFACE-TREATED PRECOATED METAL SHEET, PROCESS FOR PRODUCING SAME, AND SURFACE-TREATING SOLUTION 审中-公开
标题翻译：表面处理预处理金属片，其生产方法和表面处理溶液
公开(公告)号：US20120040194A1
公开(公告)日：2012-02-16
申请号：US13201868
申请日：2010-02-17
申请人： Takao Kanai , Hiromasa Nomura , Tomonari Hamamura , Hiroshi Kanai , Hiroyuki Oyokawa
发明人： Takao Kanai , Hiromasa Nomura , Tomonari Hamamura , Hiroshi Kanai , Hiroyuki Oyokawa
IPC分类号： B32B15/08 , B05D3/02 , B01J31/06
CPC分类号： C09D183/04 , B01J35/004 , B01J37/0217 , B01J37/0244 , B05D5/08 , B05D2202/00 , C08K3/22 , C09D5/08 , C09D7/61 , Y10T428/31663
摘要： Disclosed is a surface-treated precoated metal sheet of which resistance against contamination with a photocatalyst and a self-cleaning function can be retained for a long period. Also disclosed are a method and a surface-treating solution for producing the surface-treated precoated metal sheet properly. The surface-treated precoated metal sheet is characterized by comprising a precoated metal sheet comprising an under metal sheet and an organic resin coating layer provided on the surface of the under metal sheet and a coating film having at least two layers, having a photocatalytic activity and formed on the precoated metal sheet, wherein the coating film having at least two layers comprises an inorganic-organic composite resin composed of a condensed product of an alkoxysilane selected from a group consisting of an alkoxysilane having an organic group selected from a group consisting of an alkyl group having 1 to 12 carbon atoms, an aryl group, a carboxyl group, a hydroxy group and a combination of two or more of these groups, an alkoxysilane having an epoxy group, an alkoxysilane having an amino group, a tetraalkoxysilane and a combination of two or more of the alkoxysilanes and contains a substance having a photocatalytic activity in such an amount that the content of the substance is highest in the outermost layer of the coating film and is gradually decreased toward an inner layer of the coating film.
摘要翻译：公开了一种表面处理的预涂金属片，其可以长时间保留耐光感染性和自清洁功能的污染。还公开了适当地制造表面处理的预涂金属片的方法和表面处理溶液。表面处理的预涂金属片的特征在于包括预涂金属片，其包含下金属片和设置在金属片下表面的有机树脂涂层和具有至少两层具有光催化活性的涂膜，形成在预涂金属片上，其中具有至少两层的涂膜包括无机 - 有机复合树脂，该无机 - 有机复合树脂由选自以下的烷氧基硅烷的烷氧基硅烷的缩合产物构成，所述烷氧基硅烷具有选自以下的有机基团：具有1至12个碳原子的烷基，芳基，羧基，羟基和这些基团中的两个或更多个的组合，具有环氧基的烷氧基硅烷，具有氨基的烷氧基硅烷，四烷氧基硅烷和组合的两种或更多种烷氧基硅烷，并且含有具有光催化活性的物质，其量使得物质的含量在涂膜的最外层中最高，并且朝向涂膜的内层逐渐减小。

8. 发明授权

US07803462B2 Titanium materials with coating layer, laminated glass using the same and methods of manufacturing the same 失效
标题翻译：具有涂层的钛材料，使用其的夹层玻璃及其制造方法
公开(公告)号：US07803462B2
公开(公告)日：2010-09-28
申请号：US10498746
申请日：2003-10-14
申请人： Takehiro Takahashi , Michio Kaneko , Hiroshi Osawa , Hiroshi Kanai
发明人： Takehiro Takahashi , Michio Kaneko , Hiroshi Osawa , Hiroshi Kanai
IPC分类号： B32B9/00
CPC分类号： C23C26/00 , B32B17/061 , B32B17/10036 , B32B17/10788 , C03C27/00 , C03C27/08 , C23C8/80 , C23C28/00 , Y10T428/26
摘要： The titanium materials of the present invention have an oxide film on the surface and an interference color of the oxide film. In forming a transparent coating layer on the surface of the titanium materials, provisions are made so that the oxide film has an thickness of 150 nm to 600 nm, or the interference color due to the anodic oxide film is developed by the actions of both wavelengths strengthened and weakened by interference and the color phases of the color developed by the wavelength strengthened by interference and that of complementary colors of the color developed by the wavelength weakened by interference are as close to each as not more than 90 degrees apart on the color wheel, or the L* value on the L*a*b* calorimetric system is not less than 33. The laminated glasses of the present invention having excellent ornamentality comprise at least said titanium sheet interposed between multiple sheet glasses layered together by means of adhesive layers.
摘要翻译：本发明的钛材料的表面具有氧化膜和氧化膜的干涉色。在钛材料的表面上形成透明涂层时，要规定氧化膜的厚度为150nm〜600nm，或由于阳极氧化膜的干涉色由两波长的作用而发展被干扰强化和削弱，由被干扰强化的波长所产生的颜色的颜色相和由被干涉减弱的波长产生的颜色的互补色的颜色相位在色轮上分别接近不超过90度，或L * a * b *量热系统的L *值不小于33.本发明具有优异装饰性的夹层玻璃至少包括介于通过粘合剂层层叠在一起的多片玻璃之间的钛片。

9. 发明申请

US20090318806A1 ULTRASONOGRAPH 有权
公开(公告)号：US20090318806A1
公开(公告)日：2009-12-24
申请号：US11915884
申请日：2006-05-25
申请人： Hiroshi Kanai , Hideyuki Hasegawa , Hisashi Hagiwara
发明人： Hiroshi Kanai , Hideyuki Hasegawa , Hisashi Hagiwara
IPC分类号： A61B8/14
CPC分类号： A61B8/0858 , A61B5/02007 , A61B5/7221 , A61B5/7239 , A61B8/463 , A61B8/485 , G01S7/52042 , G01S7/5205 , G01S7/52077
摘要： An ultrasonic diagnostic apparatus according to the present invention includes: a transmitting section that generates a drive signal to drive a probe in order to transmit an ultrasonic wave toward a subject to be deformed periodically under stress; a receiving section for receiving an echo, produced when the ultrasonic wave is reflected from the subject, at the probe to generate a received echo signal; a computing section for figuring out a thickness change waveform, representing a variation in distance between two arbitrary measuring points on the subject, based on the received echo signal; and a reference waveform generating section for outputting a reference waveform. The apparatus obtains subject's internal information by comparing the thickness change waveform and the reference waveform to each other.
摘要翻译：根据本发明的超声波诊断装置包括：发送部，其产生用于驱动探头的驱动信号，以便在应力下周期性地朝向被摄体发送超声波; 接收部，其在所述探头处接收在所述超声波从所述被检体反射时产生的回波，以产生接收到的回波信号; 计算部，用于根据所接收的回波信号求出厚度变化波形，表示被检体上两个任意的测量点之间的距离的变化; 以及用于输出参考波形的参考波形生成部。该装置通过将厚度变化波形和参考波形相互比较来获得被摄体的内部信息。

10. 发明授权

US07393578B2 Precoated metal sheet for light reflectors 有权
标题翻译：光反射器预涂金属板
公开(公告)号：US07393578B2
公开(公告)日：2008-07-01
申请号：US10545619
申请日：2004-02-23
申请人： Kohei Ueda , Hiroshi Kanai , Ikuya Inoue , Nobukatsu Komatsu
发明人： Kohei Ueda , Hiroshi Kanai , Ikuya Inoue , Nobukatsu Komatsu
IPC分类号： B32B15/08 , B32B15/18 , B32B27/20
CPC分类号： G02B5/021 , B05D5/083 , B05D7/16 , B05D7/52 , F21V7/22 , G02B5/0242 , G02B5/0284 , G02B5/08 , Y10T428/24355 , Y10T428/24975 , Y10T428/3154 , Y10T428/31678
摘要： The present invention provides a precoated metal sheet, for light reflectors, having a high diffuse reflectance of visible light, and also provides the electric or electronic apparatus using it. The precoated metal sheet comprises a metal sheet or plated metal sheet, a visible light reflective undercoat having a thickness of 3 to 30 micrometers provided on at least one surface of the metal sheet or plated metal sheet, and a visible light reflective overcoat having a thickness of 10 to 40 micrometers provided on the visible light reflective undercoat. The visible light reflective undercoat comprises a binder resin and a titanium oxide, a content of the titanium oxide in the visible light reflective undercoat being 40 to 150 parts by weight based on 100 parts by weight of a solid content of the binder resin, and the visible light reflective overcoat comprises a fluororesin-containing binder resin and a titanium oxide, a content of the titanium oxide in the visible light reflective overcoat being 40 to 150 parts by weight based on 100 parts by weight of a solid content of the binder resin.
摘要翻译：本发明提供了一种用于光反射器的具有高可见光漫反射率的预涂金属片，并且还提供了使用它的电子或电子设备。预涂金属片包括金属片或电镀金属片，设置在金属片或电镀金属片的至少一个表面上的厚度为3至30微米的可见光反射底涂层和具有厚度的可见光反射外涂层设置在可见光反射底涂层上的10至40微米。可见光反射底涂层包含粘合剂树脂和氧化钛，基于100重量份的粘合剂树脂的固体含量，可见光反射底涂层中的氧化钛的含量为40〜150重量份，可见光反射外涂层包含含氟树脂的粘合剂树脂和氧化钛，基于100重量份的粘合剂树脂的固体含量，可见光反射外涂层中的氧化钛的含量为40〜150重量份。

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