专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US08940839B2 Diblock copolymers prepared by cross metathesis 有权
标题翻译：通过交叉复分解制备的二嵌段共聚物
公开(公告)号：US08940839B2
公开(公告)日：2015-01-27
申请号：US13072383
申请日：2011-03-25
申请人： John R. Hagadorn , Charles J. Ruff , Renuka N. Ganesh , Patrick Brant
发明人： John R. Hagadorn , Charles J. Ruff , Renuka N. Ganesh , Patrick Brant
IPC分类号： C08G61/04 , C08L65/00
CPC分类号： C08G61/04 , C08G2261/419 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由式：PO-C（R 11）（R 12）-C（R 13）= C（R 14）-C（R 15）（R 16）-PO *表示的多嵌段聚烯烃或其异构体，其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

2. 发明授权

US08669326B2 Amine functionalized polyolefin and methods for preparation thereof 有权
标题翻译：胺官能化聚烯烃及其制备方法
公开(公告)号：US08669326B2
公开(公告)日：2014-03-11
申请号：US13072189
申请日：2011-03-25
申请人： John R. Hagadorn , Donna J. Crowther , Renuka N. Ganesh , Patrick Brant
发明人： John R. Hagadorn , Donna J. Crowther , Renuka N. Ganesh , Patrick Brant
IPC分类号： C08K5/07 , C08L61/00 , C08F8/00
CPC分类号： C08L23/10 , C08L23/36 , C08L51/06
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及官能化聚烯烃的方法，包括使过渡金属酰胺催化剂与胺（优选仲胺）和一种或多种乙烯基封端的材料，优选一种或多种乙烯基封端的聚烯烃相接触。本发明还涉及由其制备的胺官能化的聚烯烃。

3. 发明授权

US09290584B2 Polyalkylene carboxylic acid polyamine additives for fouling mitigation in hydrocarbon refining processes 有权
标题翻译：聚烯烃羧酸多胺添加剂，用于在碳氢化合物精炼过程中减轻污染
公开(公告)号：US09290584B2
公开(公告)日：2016-03-22
申请号：US13176082
申请日：2011-07-05
申请人： Man Kit Ng , Glen B. Brons , David T. Ferrughelli , Hong Cheng , Kevin Mallory , Emmanuel Ulysse , John R. Hagadorn , Donna J. Crowther , Patrick Brant
发明人： Man Kit Ng , Glen B. Brons , David T. Ferrughelli , Hong Cheng , Kevin Mallory , Emmanuel Ulysse , John R. Hagadorn , Donna J. Crowther , Patrick Brant
IPC分类号： C10G29/20 , C08F8/32 , C08F8/04 , C10G75/04 , C10L1/2383 , C10L1/224 , C10L10/00
CPC分类号： C08F8/32 , C08F8/04 , C10G75/04 , C10L1/224 , C10L1/2383 , C10L10/00 , C08F10/06
摘要： Methods and systems for reducing fouling, including particulate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process and adding an antifouling agent containing a polymer base unit and a polyamine group to the crude hydrocarbon are provided. The antifouling agent can be obtained by converting a vinyl terminated polymer, such as polypropylene or poly(ethylene-co-propylene), to a terminal acyl containing functional group, followed by reacting the terminal acyl containing functional group with a polyamine compound.
摘要翻译：提供了一种用于在烃精炼方法中减少污垢（包括颗粒引起的结垢）的方法和系统，包括以下步骤：提供用于精制方法的粗制烃，并向粗制烃中加入含有聚合物基础单元和多胺基团的防污剂。防污剂可以通过将乙烯基封端的聚合物如聚丙烯或聚（乙烯 - 共 - 丙烯）转化成含末端酰基官能团，然后使含末端酰基官能团与多胺化合物反应来获得。

4. 发明申请

US20130150541A1 Vinyl Terminated Higher Olefin Copolymers and Methods to Produce Thereof 有权
标题翻译：乙烯基封端的高级烯烃共聚物及其生产方法
公开(公告)号：US20130150541A1
公开(公告)日：2013-06-13
申请号：US13754422
申请日：2013-01-30
申请人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F232/08 , C08F210/14
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

5. 发明申请

US20120245290A1 Diblock Copolymers Prepared by Cross Metathesis 有权
标题翻译：通过交叉复分解制备的二嵌段共聚物
公开(公告)号：US20120245290A1
公开(公告)日：2012-09-27
申请号：US13072383
申请日：2011-03-25
申请人： John R. Hagadorn , Charles J. Ruff , Renuka N. Ganesh , Patrick Brant
发明人： John R. Hagadorn , Charles J. Ruff , Renuka N. Ganesh , Patrick Brant
IPC分类号： C08F299/00 , C08L53/00
CPC分类号： C08G61/04 , C08G2261/419 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)═C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由式：PO-C（R 11）（R 12）-C（R 13）= C（R 14）-C（R 15）（R 16）-PO *表示的多嵌段聚烯烃或其异构体，其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

6. 发明授权

US08785562B2 Amphiphilic block polymers prepared by alkene metathesis 有权
标题翻译：通过烯烃复分解制备的两亲嵌段聚合物
公开(公告)号：US08785562B2
公开(公告)日：2014-07-22
申请号：US13072261
申请日：2011-03-25
申请人： John R. Hagadorn , Patrick Brant
发明人： John R. Hagadorn , Patrick Brant
IPC分类号： C08F290/04 , C08F290/06 , C08G61/12
CPC分类号： C08F290/04 , C08F4/80 , C08F290/042 , C08F290/06 , C08F290/062 , C08G61/12 , C08G2261/126 , C08G2261/419 , Y10S525/91 , Y10S525/925
摘要： The invention relates to a multiblock polyolefin, and methods to make a multiblock polyolefin, represented by the formula (X) or (XII): PO—C(R11)(R12)—C(R13)═C(R14)—C(O)—O—((CR15R16)z—(CR17R18)m—O)n—R19 (X) or PO—C(R11)(R12)—C(R13)═C(R14)—C(O)—O—((CR15R16)z—(CR17R18)mO)n—C(O)—C(R14)═C(R13)—C(R12)(R11)—PO (XX) wherein R11, R12, R13, and R14 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R15, R16, R17, and R18 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R19 is a C1 to a C20 substituted or unsubstituted hydrocarbyl group or a hydrogen; z is ≧1 to about 5; m is ≧1 to about 5; PO is a polyolefin hydrocarbyl group comprising 10 to 4000 carbon atoms; and n is from 1 to about 10,000.
摘要翻译：本发明涉及多嵌段聚烯烃和由式（X）或（XII）表示的多嵌段聚烯烃的方法：PO-C（R11）（R12）-C（R13）= C（R14）-C（ O）-O - （（CR15R16）z-（CR17R18）m-O）n-R19（X）或PO-C（R11）（R12）-C（R13）= C（R14）-C（O） O - （（CR15R16）z-（CR17R18）mO）n-C（O）-C（R14）= C（R13）-C（R12）（R11）-PO（XX）其中R11，R12，R13和 R 14各自独立地为取代或未取代的C1至C4烃基或氢; R 15，R 16，R 17和R 18各自独立地为取代或未取代的C 1至C 4烃基或氢; R19是C1至C20取代或未取代的烃基或氢; z为≥1-约5; m为≥1-5; PO是包含10至4000个碳原子的聚烯烃烃基; n为1〜约10,000。

7. 发明授权

US08283419B2 Olefin functionalization by metathesis reaction 有权
标题翻译：烯烃通过复分解反应进行功能化
公开(公告)号：US08283419B2
公开(公告)日：2012-10-09
申请号：US12488093
申请日：2009-06-19
申请人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
发明人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
IPC分类号： C08F255/00 , C08F255/02 , C08F210/06 , C08F110/06
CPC分类号： C08F210/06 , C08F210/16 , C08F220/06 , C08F220/14 , C08F255/02 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜共聚低聚物中存在90mol％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

8. 发明申请

US20120245310A1 Vinyl Terminated Higher Olefin Copolymers and Methods to Produce Thereof 有权
标题翻译：乙烯基封端的高级烯烃共聚物及其生产方法
公开(公告)号：US20120245310A1
公开(公告)日：2012-09-27
申请号：US13072249
申请日：2011-03-25
申请人： Donna J. CROWTHER , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. CROWTHER , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F10/00 , C08F4/42 , C08F10/14
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

9. 发明申请

US20090318647A1 Olefin Functionalization By Metathesis Reaction 有权
标题翻译：烯烃功能化通过复分解反应
公开(公告)号：US20090318647A1
公开(公告)日：2009-12-24
申请号：US12488093
申请日：2009-06-19
申请人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, JR. , Donna J. Crowther , Patrick Brant
发明人： John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, JR. , Donna J. Crowther , Patrick Brant
IPC分类号： C08F4/80 , C08F118/02 , C08F210/02 , C08F220/06 , C08F4/72
CPC分类号： C08F210/06 , C08F210/16 , C08F220/06 , C08F220/14 , C08F255/02 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（加入的乙烯的摩尔％）+100），当共聚物中存在10至60mol％的乙烯时 - 低聚物，和2）X = 45，当共聚低聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83×（摩尔乙烯加入）-83），当70〜共聚低聚物中存在90mol％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

10. 发明授权

US08426659B2 Vinyl terminated higher olefin polymers and methods to produce thereof 有权
标题翻译：乙烯基封端的较高级烯烃聚合物及其生产方法
公开(公告)号：US08426659B2
公开(公告)日：2013-04-23
申请号：US13072288
申请日：2011-03-25
申请人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
发明人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
IPC分类号： C10M107/10 , C10M143/08
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65925 , C08F110/14 , C08F210/14 , C08F4/65927
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式