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1. 发明申请

US20130150541A1 Vinyl Terminated Higher Olefin Copolymers and Methods to Produce Thereof 有权
标题翻译：乙烯基封端的高级烯烃共聚物及其生产方法
公开(公告)号：US20130150541A1
公开(公告)日：2013-06-13
申请号：US13754422
申请日：2013-01-30
申请人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F232/08 , C08F210/14
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

2. 发明授权

US08399724B2 Vinyl terminated higher olefin copolymers and methods to produce thereof 有权
标题翻译：乙烯基封端的较高级烯烃共聚物及其制备方法
公开(公告)号：US08399724B2
公开(公告)日：2013-03-19
申请号：US13072249
申请日：2011-03-25
申请人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F210/06 , C08F210/14 , C08F4/6592 , C10M107/06
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

3. 发明申请

US20120245310A1 Vinyl Terminated Higher Olefin Copolymers and Methods to Produce Thereof 有权
标题翻译：乙烯基封端的高级烯烃共聚物及其生产方法
公开(公告)号：US20120245310A1
公开(公告)日：2012-09-27
申请号：US13072249
申请日：2011-03-25
申请人： Donna J. CROWTHER , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. CROWTHER , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F10/00 , C08F4/42 , C08F10/14
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

4. 发明授权

US07985816B2 Catalyst system and process for olefin polymerization 有权
标题翻译：催化剂体系和烯烃聚合方法
公开(公告)号：US07985816B2
公开(公告)日：2011-07-26
申请号：US12849351
申请日：2010-08-03
申请人： Donna J. Crowther , Peijun Jiang , George Rodriguez
发明人： Donna J. Crowther , Peijun Jiang , George Rodriguez
IPC分类号： C08F4/6592 , B01J31/22
CPC分类号： C08F210/06 , B01J31/0239 , B01J31/146 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R1R2R3AH]+ [Y]−, wherein [Y]− is a non-coordinating anion (NCA), A is nitrogen or phosphorus, R1 and R2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non-aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C1 to C10 alkyl, C5 to C15 aryl, C6 to C25 arylalkyl, and C6 to C25 alkylaryl, and R3 is a hydrogen atom or C1 to C10 alkyl, or R3 is a C1 to C10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
摘要翻译：本申请涉及用于烯烃聚合的新型催化剂体系，其包含具有下式的新的离子活化剂：[R 1 R 2 R 3 AH] + [Y] - ，其中[Y] - 是非配位阴离子（NCA），A是氮或磷，R 1和R 2是烃基或含杂原子的烃基，并且与A一起形成第一个3至10元非芳族环，其中任何数量的相邻环成员可以任选地是至少一个第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系，其中所述至少一个第二环或环系与所述第一环稠合，并且其中第一和/或至少一个第二环或环系是碳原子或杂原子，并且可以被一个或多个选自氢原子，卤素原子，C 1至C 10烷基，C 5至C 15芳基，C 6至C 25芳烷基，和C 6至C 25烷基芳基，R 3是氢原子或C1至C10烷基，或R3是连接到所述第一环和/或所述至少一个第二环或环系统的C1至C10亚烷基。本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃，优选丙烯的方法。

5. 发明授权

US06300433B1 Olefin copolymerization process with bridged hafnocenes 有权
标题翻译：烯烃共聚方法与桥连氢键
公开(公告)号：US06300433B1
公开(公告)日：2001-10-09
申请号：US09422533
申请日：1999-10-21
申请人： George Rodriguez , Donna J. Crowther
发明人： George Rodriguez , Donna J. Crowther
IPC分类号： C08F452
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F210/14 , C08F2/06 , C08F2500/03 , C08F2500/04 , C08F2500/12 , C08F2500/08
摘要： The invention is directed to olefin polymerization processes using bridged hafnocene catalyst complexes that are surprisingly stable under high temperature olefin polymerization processes such that olefin copolymers can be prepared with high molecular weights and catalyst activities. More specifically, the invention is a polymerization process for ethylene copolymers having a melt index of about 0.850 to about 0.930 comprising contacting, under homogeneous polymerization conditions at a reaction temperature at or above 60° C. to 250° C., ethylene and one or more comonomers capable of insertion polymerization with a bridged hafnocene catalyst complex derived from A) a biscyclopentadienyl hafnium organometallic compound having i) at least one unsubstituted cyclopentadienyl ligand or aromatic fused-ring substituted cyclopentadienyl ligand, ii) one aromatic fused-ring substituted cyclopentadienyl ligand, iii) and a covalent bridge connecting the two cyclopentadienyl ligands, said bridge comprising a single carbon or silicon atom with two aryl groups, each substituted with a C1-C20 hydrocarbyl or hydrocarbylsilyl group at least one of which is a linear C3 or greater substitutent; and B) an activating cocatalyst.
摘要翻译：本发明涉及使用在高温烯烃聚合方法中出人意料地稳定的桥联茂茂催化剂络合物的烯烃聚合方法，使得可以以高分子量和催化剂活性制备烯烃共聚物。更具体地，本发明是一种熔体指数为约0.850至约0.930的乙烯共聚物的聚合方法，其包括在均相聚合条件下在等于或高于60℃至250℃的反应温度下接触乙烯和一种或能够与来自A）双环戊二烯基铪有机金属化合物的桥连的茂金属催化剂络合物进行插入聚合的更多共聚单体，其具有i）至少一个未取代的环戊二烯基配体或芳族稠环取代的环戊二烯基配体，ii）一个芳族稠环取代的环戊二烯基配体， iii）和连接两个环戊二烯基配体的共价桥，所述桥包含单个碳或硅原子与两个芳基，每个被C1-C20烃基或烃基甲硅烷基取代，其中至少一个是直链C3或更大的取代基; 和B）活化助催化剂。

6. 发明授权

US07799879B2 Catalyst system and process for olefin polymerization 有权
标题翻译：催化剂体系和烯烃聚合方法
公开(公告)号：US07799879B2
公开(公告)日：2010-09-21
申请号：US12184713
申请日：2008-08-01
申请人： Donna J. Crowther , Peijun Jiang , George Rodriguez
发明人： Donna J. Crowther , Peijun Jiang , George Rodriguez
IPC分类号： C08F4/603 , C08F4/643 , C08F4/6592 , B01J31/12 , B01J31/22
CPC分类号： C08F210/06 , B01J31/0239 , B01J31/146 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R1R2R3AH]+[Y]−, wherein [Y]− is a non-coordinating anion (NCA), A is nitrogen or phosphorus, R1 and R2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non-aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C1 to C10 alkyl, C5 to C15 aryl, C6 to C25 arylalkyl, and C6 to C25 alkylaryl, and R3 is a hydrogen atom or C1 to C10 alkyl, or R3 is a C1 to C10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
摘要翻译：本申请涉及用于烯烃聚合的新型催化剂体系，其包含具有下式的新的离子活化剂：[R 1 R 2 R 3 AH] + [Y] - ，其中[Y] - 是非配位阴离子（NCA），A是氮或磷，R 1和R 2是烃基或含杂原子的烃基，并且与A一起形成第一个3至10元非芳族环，其中任何数量的相邻环成员可以任选地是至少一个第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系，其中所述至少一个第二环或环系与所述第一环稠合，并且其中第一和/或至少一个第二环或环系是碳原子或杂原子，并且可以被一个或多个选自氢原子，卤素原子，C 1至C 10烷基，C 5至C 15芳基，C 6至C 25芳烷基，和C 6至C 25烷基芳基，R 3是氢原子或C1至C10烷基，或R3是连接到所述第一环和/或所述至少一个第二环或环系的C1至C10亚烷基。本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃，优选丙烯的方法。

7. 发明申请

US20100298510A1 Catalyst System and Process for Olefin Polymerization 有权
标题翻译：催化剂体系和烯烃聚合方法
公开(公告)号：US20100298510A1
公开(公告)日：2010-11-25
申请号：US12849351
申请日：2010-08-03
申请人： Donna J. Crowther , Peijun Jiang , George Rodriguez
发明人： Donna J. Crowther , Peijun Jiang , George Rodriguez
IPC分类号： C08F4/58 , C08F4/42
CPC分类号： C08F210/06 , B01J31/0239 , B01J31/146 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R1R2R3AH]+ [Y]−, wherein [Y]− is a non-coordinating anion (NCA), A is nitrogen or phosphorus, R1 and R2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non-aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C1 to C10 alkyl, C5 to C15 aryl, C6 to C25 arylalkyl, and C6 to C25 alkylaryl, and R3 is a hydrogen atom or C1 to C10 alkyl, or R3 is a C1 to C10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
摘要翻译：本申请涉及用于烯烃聚合的新型催化剂体系，其包含具有下式的新的离子活化剂：[R 1 R 2 R 3 AH] + [Y] - ，其中[Y] - 是非配位阴离子（NCA），A是氮或磷，R 1和R 2是烃基或含杂原子的烃基，并且与A一起形成第一个3至10元非芳族环，其中任何数量的相邻环成员可以任选地是至少一个第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系，其中所述至少一个第二环或环系与所述第一环稠合，并且其中第一和/或至少一个第二环或环系是碳原子或杂原子，并且可以被一个或多个选自氢原子，卤素原子，C 1至C 10烷基，C 5至C 15芳基，C 6至C 25芳烷基，和C 6至C 25烷基芳基，R 3是氢原子或C1至C10烷基，或R3是连接到所述第一环和/或所述至少一个第二环或环系统的C1至C10亚烷基。本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃，优选丙烯的方法。

8. 发明申请

US20100029873A1 Catalyst System And Process For Olefin Polymerization 有权
标题翻译：催化剂体系和烯烃聚合方法
公开(公告)号：US20100029873A1
公开(公告)日：2010-02-04
申请号：US12184713
申请日：2008-08-01
申请人： Donna J. Crowther , Peijun Jiang , George Rodriguez
发明人： Donna J. Crowther , Peijun Jiang , George Rodriguez
IPC分类号： C08F4/00 , B01J31/02 , B01J31/18 , C08F4/32
CPC分类号： C08F210/06 , B01J31/0239 , B01J31/146 , B01J31/1616 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2500/08 , C08F2500/20 , C08F2500/03 , C08F2500/17
摘要： The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R1R2R3AH]+ [Y]−, wherein [Y]− is a non-coordinating anion (NCA), A is nitrogen or phosphorus, R1 and R2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non-aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C1 to C10 alkyl, C5 to C15 aryl, C6 to C25 arylalkyl, and C6 to C25 alkylaryl, and R3 is a hydrogen atom or C1 to C10 alkyl, or R3 is a C1 to C10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
摘要翻译：本申请涉及用于烯烃聚合的新型催化剂体系，其包含具有下式的新的离子活化剂：[R 1 R 2 R 3 AH] + [Y] - ，其中[Y] - 是非配位阴离子（NCA），A是氮或磷，R 1和R 2是烃基或含杂原子的烃基，并且与A一起形成第一个3至10元非芳族环，其中任何数量的相邻环成员可以任选地是至少一个第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系，其中所述至少一个第二环或环系与所述第一环稠合，并且其中第一和/或至少一个第二环或环系是碳原子或杂原子，并且可以被一个或多个选自氢原子，卤素原子，C 1至C 10烷基，C 5至C 15芳基，C 6至C 25芳烷基，和C 6至C 25烷基芳基，R 3是水解 n原子或C1至C10烷基，或R3是连接到所述第一环和/或所述至少一个第二环或环系的C1至C10亚烷基。本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃，优选丙烯的方法。

9. 发明申请

US20210078404A1 Vehicle Kill Switch Assembly 有权
公开(公告)号：US20210078404A1
公开(公告)日：2021-03-18
申请号：US16574883
申请日：2019-09-18
申请人： George Rodriguez
发明人： George Rodriguez
IPC分类号： B60K28/04 , B60N2/00 , F02P11/00 , B60K26/02
摘要： A vehicle kill switch assembly includes a switch that is coupled to a vehicle. The switch is positioned beneath a driver's seat of the vehicle and the switch is electrically coupled to the ignition system of the vehicle. The ignition system is turned off when the switch is disengaged. A biasing unit is coupled to the vehicle and the driver's seat is coupled to the biasing unit. The biasing unit biases the driver's seat upwardly in the vehicle and the biasing unit is compressed when the driver sits in the driver's seat. The switch is engaged when the biasing unit is compressed to facilitate the vehicle to be driven. Conversely, the switch is disengaged when the biasing unit biases the driver's seat upwardly to inhibit the vehicle from being driven.

10. 发明授权

US08501892B2 Propylene ethylene polymers and production process 有权
标题翻译：丙烯乙烯聚合物和生产工艺
公开(公告)号：US08501892B2
公开(公告)日：2013-08-06
申请号：US13219090
申请日：2011-08-26
申请人： Sudhin Datta , Bruce A. Harrington , Weiguo Hu , Periagaram S. Ravishankar , George Rodriguez
发明人： Sudhin Datta , Bruce A. Harrington , Weiguo Hu , Periagaram S. Ravishankar , George Rodriguez
IPC分类号： C08F210/06 , C08F210/02 , C08F210/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y10S526/941 , Y10S526/943 , C08F2/06 , C08F4/65927 , C08F2500/21 , C08F2500/20 , C08F2500/15 , C08F2500/17
摘要： Ethylene propylene copolymers, substantially free of diene, are described. The copolymers will have a uniform distribution of both tacticity and comonomer between copolymer chains. Further, the copolymers will exhibit a statistically insignificant intramolecular difference of tacticity. The copolymers are made in the presence of a metallocene catalyst.
摘要翻译：描述了基本上不含二烯的乙烯丙烯共聚物。共聚物在共聚物链之间具有均匀分布的立构规整度和共聚单体。此外，共聚物将显示统计学上不明显的立构规整度的分子内差异。共聚物在茂金属催化剂的存在下制备。

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