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1. 发明授权

US06433110B1 Process for producing alkene polymers by gas phase polymerisation 失效
标题翻译：通过气相聚合制备烯烃聚合物的方法
公开(公告)号：US06433110B1
公开(公告)日：2002-08-13
申请号：US09125317
申请日：1998-12-04
申请人： John Lynch , David Fischer , Hans-Helmut Görtz , Günther Schweier
发明人： John Lynch , David Fischer , Hans-Helmut Görtz , Günther Schweier
IPC分类号： C08F416
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F110/02 , Y10S526/901 , Y10S526/943 , C08F2/34 , C08F2500/12
摘要： Polymerizable alkanes are prepared by gas-phase polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported castalyst systems.
摘要翻译：在催化剂体系存在下，通过气相聚合制备可聚合烷烃，其中使用的催化剂体系是支撑的催化剂体系。

2. 发明授权

US06350829B1 Supported catalyst systems 失效
标题翻译：负载催化剂体系
公开(公告)号：US06350829B1
公开(公告)日：2002-02-26
申请号：US09125377
申请日：1998-08-17
申请人： John Lynch , David Fischer , Hans-Helmut Görtz , Günther Schweier
发明人： John Lynch , David Fischer , Hans-Helmut Görtz , Günther Schweier
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F110/02 , C08F2500/12
摘要： Supported catalyst systems are obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, Ch1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3 the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q II where M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl or alkoxy each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, o is an integer from 1 to 3 and p and q are integers from 0 to 2 the sum o+p+q corresponding to the valency of M2.
摘要翻译：负载型催化剂体系可以通过以下方式获得：A）无机载体与通式I的金属化合物的反应，其中M1是碱金属，碱土金属或元素周期表Ⅲ或IV族主要金属，R1是氢，Ch1 在烷基中具有1至10个碳原子，在芳基中具有6至20个碳原子的C 10 - 烷基，C 6 -C 15 - 芳基，烷芳基或芳基烷基，R 2至R 4各自为氢，卤素，C 1 -C 10 - 烷基，在烷基中具有1-10个碳原子且在芳基中具有6-20个碳原子的C 6 -C 15 - 芳基，烷基芳基，芳烷基，烷氧基或二烷基氨基，r是1至4的整数，且t和u分别为从0到3的整数与M1的化合价对应的总和r + s + t + u，B）根据A）获得的材料与金属二卤化物形式的茂金属络合物和形成金属茂离子的化合物的反应，C）随后与通式II的金属化合物反应，其中M 2是碱金属，碱土金属 Al或元素周期表中III族的金属，R5是氢，C1-C10-烷基，C6-C15 - 芳基，烷基芳基或芳基烷基，其烷基中具有1-10个碳原子，在该基团中具有6-20个碳原子芳基，R 6和R 7是烷基中具有1至10个碳原子且芳基中具有6至20个碳原子的氢，卤素，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基，芳基烷基或烷氧基，o是1至3的整数，p和q是0至2的整数，对应于M2的化合价的和o + p + q。

3. 发明授权

US06326444B2 Preparation of polymers of alkenes by suspension polymerization 失效
标题翻译：通过悬浮聚合制备烯烃聚合物
公开(公告)号：US06326444B2
公开(公告)日：2001-12-04
申请号：US09117657
申请日：1998-08-04
申请人： John Lynch , David Fischer , Hans-Helmut Görtz , Günther Schweier
发明人： John Lynch , David Fischer , Hans-Helmut Görtz , Günther Schweier
IPC分类号： C08F402
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F110/02 , Y10S526/943 , C08F2/14 , C08F2500/17
摘要： Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3 )t(R4 )u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 to R7 are variously halogen, alkoxy, dialkylamino, hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r, s, t and u are integers from 1 to 4 the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q II.
摘要翻译：烯烃的聚合物通过在催化剂体系存在下通过悬浮聚合制备，其中使用的催化剂体系是负载的催化剂体系可通过以下方法获得：A）无机载体与通式I的金属化合物的反应，其中M 1是碱金属，碱土金属或元素周期表主要III或IV族金属，R 1至R 7各自为卤素，烷氧基，二烷基氨基，氢，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基或芳烷基，各自具有1至10个烷基中的碳原子和芳基中的6至20个碳原子，r，s，t和u是1至4的整数，对应于M1的化合价的和r + s + t + u，B）反应根据A）获得的材料与金属二卤化物形式的茂金属络合物和形成金属茂离子的化合物，C）随后与通式II的金属化合物反应

4. 发明授权

US06812185B2 Preparation of a metal-containing supported catalyst or a supported catalyst component by impregnation of a support material 有权
标题翻译：通过浸渍载体材料制备含金属的负载型催化剂或负载型催化剂组分
公开(公告)号：US06812185B2
公开(公告)日：2004-11-02
申请号：US10402301
申请日：2003-07-30
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： C08F464
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： In a process for preparing a metal-containing supported catalyst or a metal-containing supported catalyst component by impregnation of a support material with an impregnation solution comprising the metal component, the impregnation solution flows through the support material.

5. 发明授权

US06265339B1 Process for preparing carrier-borne transition metal catalysts 失效
标题翻译：制备载体过渡金属催化剂的方法
公开(公告)号：US06265339B1
公开(公告)日：2001-07-24
申请号：US09202534
申请日：1998-12-16
申请人： Wolfgang Bidell , Franz Langhauser , Ulrich Moll , Ian David McKenzie , David Fischer , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Peter John Vaughan Jones , John Russell Grasmeder
发明人： Wolfgang Bidell , Franz Langhauser , Ulrich Moll , Ian David McKenzie , David Fischer , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Peter John Vaughan Jones , John Russell Grasmeder
IPC分类号： C08F416
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/61927 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/24
摘要： A process for preparing a supported transition metal catalyst comprising a particulate organic or inorganic support material, a transition metal complex and a compound capable of forming metallocenium ions comprises the following process steps: a) contacting a solution of a compound capable of forming metallocenium ions with a second solvent in which this compound is only sparingly soluble, in the presence of the support material, b) removing at least part of the solvent from the support material and c) contacting a solution of a mixture of a compound capable of forming metallocenium ions and a transition metal complex with a second solvent in which this mixture is only sparingly soluble, in the presence of the support material obtained as described in a) and b).
摘要翻译：一种制备负载型过渡金属催化剂的方法，其包括颗粒状有机或无机载体材料，过渡金属络合物和能够形成金属茂离子的化合物包括以下工艺步骤：a）使能够形成金属茂离子的化合物的溶液与在载体材料存在下，该化合物只有微溶的第二溶剂，b）从载体材料中除去至少一部分溶剂，和c）使能够形成金属茂离子的化合物的混合物和在如a）和b）中所述获得的载体材料存在下，其中该混合物仅仅是微溶的第二溶剂的过渡金属络合物。

6. 发明授权

US06589905B1 Method for producing a supported catalyst 有权
标题翻译：负载型催化剂的制造方法
公开(公告)号：US06589905B1
公开(公告)日：2003-07-08
申请号：US09720881
申请日：2001-01-02
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： B01J2300
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： The invention relates to a method for producing a supported catalyst which contains metal, or a supported catalyst constituent which contains metal by impregnating a supporting material with an impregnating solution containing the metal constituent, whereby the impregnating solution flows through the supporting material.
摘要翻译：本发明涉及含有金属的负载型催化剂的制造方法或通过用含有金属成分的浸渍溶液浸渍担载材料而含有金属的负载型催化剂成分，由此浸渍液流过支撑材料。

7. 发明授权

US06583253B1 Propene terpolymers with a low extractable portion 有权
标题翻译：具有低可提取部分的丙烯三元共聚物
公开(公告)号：US06583253B1
公开(公告)日：2003-06-24
申请号：US09701943
申请日：2000-12-05
申请人： David Fischer , Peter John Vaughan Jones , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Ulrich Moll
发明人： David Fischer , Peter John Vaughan Jones , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Ulrich Moll
IPC分类号： C08F21000
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/06 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F210/08 , C08F2500/03 , C08F210/14
摘要： Propene terpolymers consist of from 80 to 99.5 mol % of structural units derived from propene, from 0.1 to 15 mol % of structural units derived from ethene or a C4-C6-1-olefin (I) and from 0.1 to 15 mol % of structural units derived from a further C4-C12-1-olefin (II) which is different from the C4-C6-1-olefin (I), which propene terpolymers have a proportion of regioregular ′1-2′-inserted propene units corresponding to the formula (1) [ ′ ⁢ 1 - 2 ′ ] [ ′ ⁢ 1 - 2 ′ ] + [ ′ ⁢ 2 - 1 ′ ] + [ ′ ⁢ 1 - 3 ′ ] ( 1 ) of more than 0.99, have a melting point (TM), determined from the DSC peak maximum, of less than 135° C. and a weight average molecular weight (MW) of more than 80,000 g/mol and have a xylene-soluble proportion (XS) in % by weight of the propene terpolymer which obeys the following inequality (2) XS≦1411.21 exp(−0.0591 TM[° C.])−0.05 (2).
摘要翻译：丙烯三元共聚物由80至99.5摩尔％的衍生自丙烯的结构单元，0.1至15摩尔％的衍生自乙烯或C 4 -C 6 -1-烯烃（I）的结构单元和0.1至15摩尔％的结构单元组成衍生自不同于C 4 -C 6 -1-烯烃（I）的另外的C 4 -C 12 -1-烯烃（II）的单元，该丙烯三元共聚物具有对应于区域规则'1-2'插入的丙烯单元的比例式（1）大于0.99，由DSC峰值最大值确定的熔点（TM）小于135℃，重均分子量（MW）大于80,000g / mol，具有二甲苯可溶比例（XS）按丙烯三元共聚物的重量百分比计，遵循以下不等式（2）

8. 发明授权

US06562478B1 Sealable multilayer film made of a grafted terpolymer 失效
标题翻译：由可接枝的三元共聚物制成的可密封多层膜
公开(公告)号：US06562478B1
公开(公告)日：2003-05-13
申请号：US09701941
申请日：2000-12-05
申请人： David Fischer , Bernd Lothar Marczinke , Werner Schöne , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Ulrich Moll , Meinolf Kersting , Günther Schweier , Peter John Vaughan Jones
发明人： David Fischer , Bernd Lothar Marczinke , Werner Schöne , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Ulrich Moll , Meinolf Kersting , Günther Schweier , Peter John Vaughan Jones
IPC分类号： B32B2732
CPC分类号： B32B27/08 , B29C47/0021 , B29C47/065 , B29C47/145 , B29C55/023 , B29K2995/0022 , B32B27/32 , B32B27/327 , B32B38/0008 , B32B2038/0028 , B32B2310/14 , B32B2553/00 , C08F210/06 , C08F210/16 , Y10T428/2495 , Y10T428/31913 , C08F210/08 , C08F2500/03 , C08F2500/20 , C08F210/14
摘要： A sealable coextruded film is made from at least one outer layer and from at least one base layer, where the outer layer is composed of a propylene terpolymer comprising from 80 to 99.5 mol % of structural units derived from propylene, from 0.2 to 15 mol % of structural units derived from ethene or from a C4-C6 1-olefin (I) and from 0.3 to 15 mol % of structural units derived from another C4-C12 1-olefin (II) different from the C4-C6 1-olefin (I), and where the propylene terpolymer has been prepared using metallocene catalysts.
摘要翻译：可密封的共挤出膜由至少一个外层和至少一个基层制成，其中外层由丙烯三元共聚物组成，丙烯三元共聚物包含80-99.5mol％的衍生自丙烯的结构单元，0.2-15mol％衍生自乙烯或来自C 4 -C 6 1-烯烃（I）的结构单元和0.3至15摩尔％的衍生自不同于C 4 -C 6 1-烯烃的另外的C 4 -C 12 1-烯烃（II）的结构单元（ I），并且其中使用茂金属催化剂制备丙烯三元共聚物。

9. 发明授权

US06197900B1 Preparation of multiphase homo- or copolymers of C2-C10-alk-1-enes in one reaction zone 失效
标题翻译：在一个反应区中制备C2-C10-烷-1-烯的多相均聚物或共聚物
公开(公告)号：US06197900B1
公开(公告)日：2001-03-06
申请号：US08850701
申请日：1997-05-02
申请人： Stefan Seelert , Franz Langhauser , Jürgen Kerth , Patrik Müller , David Fischer , Günther Schweier
发明人： Stefan Seelert , Franz Langhauser , Jürgen Kerth , Patrik Müller , David Fischer , Günther Schweier
IPC分类号： C08F444
CPC分类号： C08F10/06 , C08F4/63904 , C08F4/63912 , C08F4/63916 , C08F4/63927 , C08F10/00 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F210/06
摘要： Multiphase homo- or copolymers of C2-C10-alk-1-enes are prepared by a process in which polymerization is effected in the presence of two different catalyst systems in one reaction zone, one of the catalyst systems containing, as active components, a metallocene complex of the general formula (I) or (II) where M1 is a metal of group IVb, Vb or VIb of the Periodic Table, R1 and R2 are identical or different and are each hydrogen, C1-C10-alkyl, C1-C10-alkoxy, C6-C10-aryl, C6-C10-aryloxy, C2-C10-alkenyl, C7-C40-arylalkyl, C7-C40-alkylaryl, C8-C40-arylalkenyl or halogen, R3 and R4 are identical or different and are each hydrogen, halogen, C1-C10-alkyl which may be halogenated, C6-C10-aryl or an —NR210, —SR10, —OSiR310, —SiR310 or —PR210 radical, where R10 is halogen, C1-C10-alkyl or C6-C10-aryl, and R5 and R6 are identical or different and have the meanings stated for R3 and R4, with the proviso that R5 and R6 are not hydrogen.
摘要翻译：通过在一个反应区中在两种不同催化剂体系存在下进行聚合的方法制备C2-C10-烷-1-烯的多相均聚物或共聚物，其中一个催化剂体系含有活性组分通式（I）或（II）的茂金属络合物，其中M1是元素周期表IVb，Vb或VIb族金属，R1和R2相同或不同，分别为氢，C1-C10-烷基，C1-C10 - 烷氧基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳氧基，C 2 -C 10 - 烯基，C 7 -C 40 - 芳基烷基，C 7 -C 40 - 烷基芳基，C 8 -C 40 - 芳基烯基或卤素，R 3和R 4相同或不同，每个氢，卤素，可以被卤化的C 1 -C 10 - 烷基，C 6 -C 10 - 芳基或-NR 2 10，-SR 10，-OSiR 3 10，-SiR 3 10或-PR 2 10基团，其中R 10是卤素，C 1 -C 10 - 烷基或C 6 -C 10 - 芳基和R 5和R 6相同或不同，并具有对R 3和R 4所述的含义，条件是R 5和R 6不是氢。

10. 发明授权

US6100353A Supported metallocene catalyst systems 失效
标题翻译：负载金属茂催化剂体系
公开(公告)号：US6100353A
公开(公告)日：2000-08-08
申请号：US523888
申请日：1995-09-06
申请人： John Lynch , David Fischer , Franz Langhauser , Hans-Helmut Gortz , Jurgen Kerth , Gunther Schweier
发明人： John Lynch , David Fischer , Franz Langhauser , Hans-Helmut Gortz , Jurgen Kerth , Gunther Schweier
IPC分类号： C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/655 , C08F4/68 , C08F10/00 , C08F4/42
CPC分类号： C08F10/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F4/6392 , Y10S526/943
摘要： Supported catalyst systems are obtainable bya) application of a mixture ofA) at least one metallocene complex andB) at elast one metal compoundto a carrier which, if required, may have been pretreated, andb) subsequent activation by reaction with a solution or suspension of a compound forming metallocenium ions.
摘要翻译：负载型催化剂体系可以通过以下方式获得：a）至少一种茂金属络合物和B）在弹性一种金属化合物上的混合物施用到载体上，所述载体如果需要，可以进行预处理，和b）随后通过与形成金属茂离子的化合物的溶液或悬浮液。

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