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1. 发明授权

US06265339B1 Process for preparing carrier-borne transition metal catalysts 失效
标题翻译：制备载体过渡金属催化剂的方法
公开(公告)号：US06265339B1
公开(公告)日：2001-07-24
申请号：US09202534
申请日：1998-12-16
申请人： Wolfgang Bidell , Franz Langhauser , Ulrich Moll , Ian David McKenzie , David Fischer , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Peter John Vaughan Jones , John Russell Grasmeder
发明人： Wolfgang Bidell , Franz Langhauser , Ulrich Moll , Ian David McKenzie , David Fischer , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Peter John Vaughan Jones , John Russell Grasmeder
IPC分类号： C08F416
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/61927 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/24
摘要： A process for preparing a supported transition metal catalyst comprising a particulate organic or inorganic support material, a transition metal complex and a compound capable of forming metallocenium ions comprises the following process steps: a) contacting a solution of a compound capable of forming metallocenium ions with a second solvent in which this compound is only sparingly soluble, in the presence of the support material, b) removing at least part of the solvent from the support material and c) contacting a solution of a mixture of a compound capable of forming metallocenium ions and a transition metal complex with a second solvent in which this mixture is only sparingly soluble, in the presence of the support material obtained as described in a) and b).
摘要翻译：一种制备负载型过渡金属催化剂的方法，其包括颗粒状有机或无机载体材料，过渡金属络合物和能够形成金属茂离子的化合物包括以下工艺步骤：a）使能够形成金属茂离子的化合物的溶液与在载体材料存在下，该化合物只有微溶的第二溶剂，b）从载体材料中除去至少一部分溶剂，和c）使能够形成金属茂离子的化合物的混合物和在如a）和b）中所述获得的载体材料存在下，其中该混合物仅仅是微溶的第二溶剂的过渡金属络合物。

2. 发明授权

US06583253B1 Propene terpolymers with a low extractable portion 有权
标题翻译：具有低可提取部分的丙烯三元共聚物
公开(公告)号：US06583253B1
公开(公告)日：2003-06-24
申请号：US09701943
申请日：2000-12-05
申请人： David Fischer , Peter John Vaughan Jones , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Ulrich Moll
发明人： David Fischer , Peter John Vaughan Jones , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Günther Schweier , Bernd Lothar Marczinke , Meinolf Kersting , Ulrich Moll
IPC分类号： C08F21000
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/06 , Y10S526/904 , Y10S526/943 , C08F4/65916 , C08F210/08 , C08F2500/03 , C08F210/14
摘要： Propene terpolymers consist of from 80 to 99.5 mol % of structural units derived from propene, from 0.1 to 15 mol % of structural units derived from ethene or a C4-C6-1-olefin (I) and from 0.1 to 15 mol % of structural units derived from a further C4-C12-1-olefin (II) which is different from the C4-C6-1-olefin (I), which propene terpolymers have a proportion of regioregular ′1-2′-inserted propene units corresponding to the formula (1) [ ′ ⁢ 1 - 2 ′ ] [ ′ ⁢ 1 - 2 ′ ] + [ ′ ⁢ 2 - 1 ′ ] + [ ′ ⁢ 1 - 3 ′ ] ( 1 ) of more than 0.99, have a melting point (TM), determined from the DSC peak maximum, of less than 135° C. and a weight average molecular weight (MW) of more than 80,000 g/mol and have a xylene-soluble proportion (XS) in % by weight of the propene terpolymer which obeys the following inequality (2) XS≦1411.21 exp(−0.0591 TM[° C.])−0.05 (2).
摘要翻译：丙烯三元共聚物由80至99.5摩尔％的衍生自丙烯的结构单元，0.1至15摩尔％的衍生自乙烯或C 4 -C 6 -1-烯烃（I）的结构单元和0.1至15摩尔％的结构单元组成衍生自不同于C 4 -C 6 -1-烯烃（I）的另外的C 4 -C 12 -1-烯烃（II）的单元，该丙烯三元共聚物具有对应于区域规则'1-2'插入的丙烯单元的比例式（1）大于0.99，由DSC峰值最大值确定的熔点（TM）小于135℃，重均分子量（MW）大于80,000g / mol，具有二甲苯可溶比例（XS）按丙烯三元共聚物的重量百分比计，遵循以下不等式（2）

3. 发明授权

US06562478B1 Sealable multilayer film made of a grafted terpolymer 失效
标题翻译：由可接枝的三元共聚物制成的可密封多层膜
公开(公告)号：US06562478B1
公开(公告)日：2003-05-13
申请号：US09701941
申请日：2000-12-05
申请人： David Fischer , Bernd Lothar Marczinke , Werner Schöne , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Ulrich Moll , Meinolf Kersting , Günther Schweier , Peter John Vaughan Jones
发明人： David Fischer , Bernd Lothar Marczinke , Werner Schöne , Franz Langhauser , Wolfgang Bidell , Roland Hingmann , Ulrich Moll , Meinolf Kersting , Günther Schweier , Peter John Vaughan Jones
IPC分类号： B32B2732
CPC分类号： B32B27/08 , B29C47/0021 , B29C47/065 , B29C47/145 , B29C55/023 , B29K2995/0022 , B32B27/32 , B32B27/327 , B32B38/0008 , B32B2038/0028 , B32B2310/14 , B32B2553/00 , C08F210/06 , C08F210/16 , Y10T428/2495 , Y10T428/31913 , C08F210/08 , C08F2500/03 , C08F2500/20 , C08F210/14
摘要： A sealable coextruded film is made from at least one outer layer and from at least one base layer, where the outer layer is composed of a propylene terpolymer comprising from 80 to 99.5 mol % of structural units derived from propylene, from 0.2 to 15 mol % of structural units derived from ethene or from a C4-C6 1-olefin (I) and from 0.3 to 15 mol % of structural units derived from another C4-C12 1-olefin (II) different from the C4-C6 1-olefin (I), and where the propylene terpolymer has been prepared using metallocene catalysts.
摘要翻译：可密封的共挤出膜由至少一个外层和至少一个基层制成，其中外层由丙烯三元共聚物组成，丙烯三元共聚物包含80-99.5mol％的衍生自丙烯的结构单元，0.2-15mol％衍生自乙烯或来自C 4 -C 6 1-烯烃（I）的结构单元和0.3至15摩尔％的衍生自不同于C 4 -C 6 1-烯烃的另外的C 4 -C 12 1-烯烃（II）的结构单元（ I），并且其中使用茂金属催化剂制备丙烯三元共聚物。

4. 发明授权

US06733717B1 Injection stretch-blow molded containers made of olefin polymers 有权
标题翻译：由烯烃聚合物制成的注射拉伸吹塑容器
公开(公告)号：US06733717B1
公开(公告)日：2004-05-11
申请号：US09601356
申请日：2000-08-01
申请人： Bernd Lothar Marczinke , Peter John Vaughan Jones , Meinolf Kersting , David Fischer , Franz Langhauser , Ulrich Moll , Wolfgang Bidell
发明人： Bernd Lothar Marczinke , Peter John Vaughan Jones , Meinolf Kersting , David Fischer , Franz Langhauser , Ulrich Moll , Wolfgang Bidell
IPC分类号： B29C4906
CPC分类号： B29C49/0005 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/06 , C08F110/06 , C08F210/06 , Y10T428/1352 , C08F2500/12 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： Injection stretch blow molded containers are obtainable from olefin polymers, comprising homopolymers of propylene or copolymers of propylene with other C2-C10-alk-1-enes, which are obtainable by polymerizing the corresponding monomers with metallocene catalysts. Processes for producing injection stretch blow molded containers from olefin polymers, and also the use of olefin polymers for producing injection stretch blow molded containers, are described.
摘要翻译：注射拉伸吹塑容器可从包含丙烯均聚物或丙烯与其它C 2 -C 10 - 烷-1-烯的共聚物的烯烃聚合物获得，其可通过使金属茂催化剂聚合相应的单体而获得。用于生产注射拉伸吹塑成型描述了烯烃聚合物的容器，以及烯烃聚合物用于生产注射拉伸吹塑容器的用途。

5. 发明授权

US06589905B1 Method for producing a supported catalyst 有权
标题翻译：负载型催化剂的制造方法
公开(公告)号：US06589905B1
公开(公告)日：2003-07-08
申请号：US09720881
申请日：2001-01-02
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： B01J2300
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： The invention relates to a method for producing a supported catalyst which contains metal, or a supported catalyst constituent which contains metal by impregnating a supporting material with an impregnating solution containing the metal constituent, whereby the impregnating solution flows through the supporting material.
摘要翻译：本发明涉及含有金属的负载型催化剂的制造方法或通过用含有金属成分的浸渍溶液浸渍担载材料而含有金属的负载型催化剂成分，由此浸渍液流过支撑材料。

6. 发明授权

US06812185B2 Preparation of a metal-containing supported catalyst or a supported catalyst component by impregnation of a support material 有权
标题翻译：通过浸渍载体材料制备含金属的负载型催化剂或负载型催化剂组分
公开(公告)号：US06812185B2
公开(公告)日：2004-11-02
申请号：US10402301
申请日：2003-07-30
申请人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
发明人： David Fischer , Wolfgang Bidell , Ulrich Moll , Joachim Rösch , Franz Langhauser , Roland Hingmann , Heike Gregorius , Carsten Süling , Günther Schweier
IPC分类号： C08F464
CPC分类号： C08F10/06 , C08F4/65904 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F2500/17 , C08F2500/03
摘要： In a process for preparing a metal-containing supported catalyst or a metal-containing supported catalyst component by impregnation of a support material with an impregnation solution comprising the metal component, the impregnation solution flows through the support material.

7. 发明授权

US06200922B1 Catalyst systems of the Ziegler-Natta type 失效
标题翻译：齐格勒 - 纳塔型催化剂系统
公开(公告)号：US06200922B1
公开(公告)日：2001-03-13
申请号：US08869761
申请日：1997-06-05
申请人： Stephan Hüffer , Wolfgang Bidell , Patrik Müller , Ulrich Moll , Roland Hingmann , Günther Schweier
发明人： Stephan Hüffer , Wolfgang Bidell , Patrik Müller , Ulrich Moll , Roland Hingmann , Günther Schweier
IPC分类号： B01J2106
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6465 , C08F4/025 , C08F4/6546 , C08F2500/12 , C08F2500/24
摘要： The catalyst systems comprise as active constituents a) a titanium-containing solid component comprising a compound of titanium, a compound of magnesium, a halogen, an inorganic oxide as support and a carboxylic ester as electron donor compound, and also, as cocatalyst, b) an aluminum compound and c) optionally a further electron donor compound, wherein the inorganic oxide used has a pH of from 1 to 6, an average particle diameter of from 5 to 200 &mgr;m, an average primary particle diameter of from 1 to 20 &mgr;M and voids or channels having an average diameter of from 0.1 to 20 &mgr;m and a macroscopic share of the volume of the overall particle within the range from 5 to 30%.
摘要翻译：催化剂体系包括作为活性成分的含钛固体组分，其包含钛化合物，镁化合物，卤素，作为载体的无机氧化物和作为电子给体化合物的羧酸酯的化合物，以及作为助催化剂的b）铝化合物和任选的另外的电子给体化合物，其中使用的无机氧化物的pH为1至6，平均粒径为5至200μm，平均一次粒径为1至20μm，空隙或平均直径为0.1-20μm的通道，并且整个颗粒的体积的宏观份额在5至30％的范围内。

8. 发明授权

US6156691A Ziegler-Natta catalyst systems modified during their preparation 失效
标题翻译：齐格勒 - 纳塔催化剂体系在制备过程中改进
公开(公告)号：US6156691A
公开(公告)日：2000-12-05
申请号：US928394
申请日：1997-09-12
申请人： Stephan Huffer , Ulrich Moll , Ian David McKenzie , Franz Langhauser , Peter Kolle , Roland Hingmann , Gunther Schweier , Rainer Hemmerich , Jurgen Kerth
发明人： Stephan Huffer , Ulrich Moll , Ian David McKenzie , Franz Langhauser , Peter Kolle , Roland Hingmann , Gunther Schweier , Rainer Hemmerich , Jurgen Kerth
IPC分类号： C08F4/02 , C08F4/642 , C08F4/646 , C08F4/654 , C08F4/658 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： In catalyst systems of the Ziegler-Natta type modified during their preparation and comprising as active constituentsa) a titanium-containing solid component which is obtained by reacting a compound of titanium with a compound of magnesium, a halogen, an inorganic oxide as support, a C.sub.1 -C.sub.8 -alkanol and a carboxylic ester as electron donor compound,and also as cocatalystb) an aluminum compound andc) if desired, a further electron donor compound,the titanium-containing solid component a) is prepared by first, in a first stage, admixing an inorganic oxide as support with a solution of a chlorine-free compound of magnesium in an inert solvent, stirring this mixture for from 0.5 to 5 hours at from 10 to 120.degree. C. and subsequently reacting it while stirring continually in an inert solvent with a C.sub.1 -C.sub.8 -alkanol in an at least 1.3-fold excess, based on the compound of magnesium, to give a chlorine-free intermediate, then, without purification or extraction of the intermediate, adding a compound of trivalent or tetravalent titanium and a carboxylic ester as electron donor compound to this intermediate, stirring the resulting mixture for at least 30 minutes at from 20 to 130.degree. C., subsequently filtering off and washing the solid thus obtained and subsequently, in a second stage, extracting the solid obtained from the first stage in an inert solvent comprising at least 5% by weight of titanium tetrachloride and washing it with a liquid alkane.
摘要翻译：在其制备过程中改性的齐格勒 - 纳塔型催化剂体系中，包含作为活性成分的含钛固体成分a）通过使钛化合物与镁，卤素，无机氧化物作为载体反应而得到的含钛固体成分，作为电子给体化合物的C1-C8-链烷醇和羧酸酯，以及作为助催化剂的b）铝化合物，和c）如果需要，另外的电子给体化合物，含钛固体组分a）首先在第一阶段，将无机氧化物作为载体与无氯化合物的镁在惰性溶剂中的溶液混合，在10至120℃下搅拌该混合物0.5至5小时，随后在持续搅拌下反应在基于镁化合物的至少1.3倍过量的C 1 -C 8烷醇的惰性溶剂中，得到无氯中间体，然后不经纯化或萃取中间体，加入一种磅三价或四价钛和羧酸酯作为电子给体化合物，在20至130℃下搅拌所得混合物至少30分钟，随后过滤并洗涤由此获得的固体，随后在第二阶段，在包含至少5重量％的四氯化钛的惰性溶剂中萃取从第一阶段获得的固体，并用液体烷烃洗涤。

9. 发明授权

US6107231A Ziegler-Natta catalyst systems modified during their preparation 失效
标题翻译：齐格勒 - 纳塔催化剂体系在制备过程中改进
公开(公告)号：US6107231A
公开(公告)日：2000-08-22
申请号：US928526
申请日：1997-09-12
申请人： Stephan Huffer , Ulrich Moll , Peter Kolle , Roland Hingmann
发明人： Stephan Huffer , Ulrich Moll , Peter Kolle , Roland Hingmann
IPC分类号： C08F4/642 , C08F4/646 , C08F4/654 , C08F10/00 , C08F110/06 , B01J38/56
CPC分类号： C08F10/00 , C08F110/06
摘要： In catalyst systems of the Ziegler-Natta type comprising as active constituentsa) a titanium-containing solid component which is obtained by reacting a compound of titanium with a compound of magnesium, a halogen, an inorganic oxide as support, a C.sub.1 -C.sub.8 -alkanol and a carboxylic ester as electron donor compound,and also as cocatalyst,b) an aluminum compound andc) if desired, a further electron donor compound,the reaction of the individual components for preparing the titanium-containing solid component a) is carried out in the presence of an aromatic hydrocarbon as solvent.
摘要翻译：在包含作为活性成分的齐格勒 - 纳塔型催化剂体系中，a）通过使钛化合物与镁，卤素，作为载体的无机氧化物，C1-C8- 链烷醇和羧酸酯作为电子给体化合物，以及作为助催化剂，b）铝化合物和c）如果需要，还可以进一步施加电子给体化合物，用于制备含钛固体组分a）的各组分的反应在芳族烃作为溶剂的存在下。

10. 发明授权

US06348547B1 Oxidized metallocene-polyolefin waxes 失效
标题翻译：氧化茂金属 - 聚烯烃蜡
公开(公告)号：US06348547B1
公开(公告)日：2002-02-19
申请号：US09171824
申请日：1998-10-27
申请人： Andreas Deckers , Arend Jouke Kingma , Ulrich Moll , Wilhelm Weber
发明人： Andreas Deckers , Arend Jouke Kingma , Ulrich Moll , Wilhelm Weber
IPC分类号： C08F806
CPC分类号： C09G1/08 , A23B7/16 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F8/06 , C08F10/02 , C08F110/02 , C08L23/30 , C08F2500/02 , C08F2500/23
摘要： Oxidized waxes are obtainable by oxidation of polyolefins obtainable by means of metallocene catalysis and having a molecular weight Mw in the range from 1000 to 40,000 g/mol.
摘要翻译：通过氧化可通过茂金属催化并且分子量Mw在1000至40,000g / mol范围内的聚烯烃获得氧化蜡。

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