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    • 6. 发明授权
      US5153075A Permanent antistatic acid copolymer/quaternary amine polymeric films 失效
    • Permanent antistatic acid copolymer/quaternary amine polymeric films
    • 永久抗静电酸共聚物/季胺聚合物膜
    • US5153075A
    • 1992-10-06
    • US558043
    • 1990-07-25
    • Marvin R. Havens , William P. Roberts
    • Marvin R. Havens , William P. Roberts
    • B32B27/28 , C07C211/63 , C07C217/08 , C07C303/32 , C08J5/18 , C08K5/19
    • C08J5/18 , B32B27/28 , C07C211/63 , C07C217/08 , C07C303/32 , C08K5/19 , C08J2323/02 , Y10S260/20 , Y10S260/21 , Y10T428/31913 , Y10T428/31928
    • An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N]+ [X]- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, fluoride, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.8 alkyl phosphate, sulfate, C.sub.1 to C.sub.8 alkyl sulfate, formate, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.24 alkaryl or aryl sulfonate, acetate, citrate, trifluoroacetate, propionate, tartrate or carbonate.
    • 公开了一种永久抗静电的酸共聚物/季胺混合物。 酸共聚物是（i）主要含摩尔％的式RCH = CH 2的α-烯烃，其中R是H或C 1至C 8烷基的共聚物，和（ii）少量的摩尔％的α ，β-烯属不饱和羧酸。 季胺具有式[（R 1）（R 2）（R 3）（R 4）N] + [X] - 其中R 1选自H，芳基或任选具有一个或多个不连续C = O或NHC = O或-S-或-O-，或与R2相同; R 2，R 3和R 4各自相同或不同，并且选自H，任选被一个或多个OH取代的C 1至C 18烷基或 - （R 5 -O）a H，其中a是1至10的整数，R 5是 乙烯或丙烯; X是选自氯化物，溴化物，碘化物，氟化物，硝酸盐，氟硼酸盐，磷酸盐，C1至C8烷基磷酸盐，硫酸盐，C1至C8烷基硫酸盐，甲酸盐，C1至C8烷基或C6至C24烷芳基或芳基磺酸盐的阴离子， 乙酸盐，柠檬酸盐，三氟乙酸盐，丙酸盐，酒石酸盐或碳酸盐。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 7. 发明授权
      US5096761A Antistatically conductive masking film for electrostatic spray painting 失效
    • Antistatically conductive masking film for electrostatic spray painting
    • 用于静电喷漆的防静电导电掩膜
    • US5096761A
    • 1992-03-17
    • US560464
    • 1990-07-25
    • William P. Roberts , Charles R. Morgan , Marvin R. Havens
    • William P. Roberts , Charles R. Morgan , Marvin R. Havens
    • B05B15/04 , B05D1/32 , C09D5/24 , C09D123/02 , C09D123/08 , H01B1/12 , H01B1/22 , H01B1/24
    • B05D1/32 , B05B15/045 , C09D123/02 , C09D123/08 , C09D5/24 , H01B1/12 , H01B1/22 , H01B1/24 , Y10S428/922 , Y10T428/24802 , Y10T428/24851 , Y10T428/24893 , Y10T428/28
    • A masking film suitable for masking during electrostatic spray painting is disclosed. In one embodiment the masking film is made from an acid copolymer/quaternary amine mixture which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.8 alkyl phosphate, sulfate, C.sub.1 to C.sub.8 alkyl sulfate, formate, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.24 alkaryl or aryl sulfonate, acetate, citrate, trifluoroacetate, propionate, tartrate or carbonate. In a second embodiment, the masking film is made from a polyolefin containing a particulate conductive filler.
    • 公开了一种适用于静电喷涂期间掩蔽的掩模膜。 在一个实施方案中，掩模膜由永久抗静电的酸共聚物/季胺混合物制成。 酸共聚物是（i）主要含摩尔％的式RCH = CH 2的α-烯烃，其中R是H或C 1至C 8烷基的共聚物，和（ii）少量的摩尔％的α ，β-烯属不饱和羧酸。 季胺具有式[（R 1）（R 2）（R 3）（R 4）N] + [X] - 其中R 1选自H，芳基或任选具有一个或多个不连续C = O或NHC = O或-S-或-O-，或与R2相同; R 2，R 3和R 4各自相同或不同，并且选自H，任选被一个或多个OH取代的C 1至C 18烷基或 - （R 5 -O）a -H，其中a是1至10的整数， R5是乙烯或丙烯; X为阴离子，选自氯化物，溴化物，碘化物，硝酸盐，氟硼酸盐，磷酸盐，C1至C8烷基磷酸盐，硫酸盐，C1至C8烷基硫酸盐，甲酸盐，C1至C8烷基或C6至C24烷芳基或芳基磺酸盐， 柠檬酸盐，三氟乙酸盐，丙酸盐，酒石酸盐或碳酸盐。 在第二实施例中，掩模膜由含有颗粒状导电填料的聚烯烃制成。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 9. 发明授权
      US4999252A Permanent antistatic acid copolymer/quaternary amine mixtures films 失效
    • Permanent antistatic acid copolymer/quaternary amine mixtures films
    • 永久抗静电酸共聚物/季胺混合物膜
    • US4999252A
    • 1991-03-12
    • US249488
    • 1988-09-26
    • Marvin R. Havens , William P. Roberts
    • Marvin R. Havens , William P. Roberts
    • B32B27/28 , C07C211/63 , C07C217/08 , C07C303/32 , C08J5/18 , C08K5/19
    • C08K5/19 , B32B27/28 , C07C211/63 , C07C217/08 , C07C303/32 , C08J5/18 , C08J2323/02 , Y10S260/18 , Y10S260/20 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913
    • An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, fluoride, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.8 alkyl phosphate, sulfate, C.sub.1 to C.sub.8 alkyl sulfate, formate, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.24 alkaryl or aryl sulfonate, acetate, citrate, trifluoroacetate, propionate, tartrate or carbonate.
    • 公开了一种永久抗静电的酸共聚物/季胺混合物。 酸共聚物是（i）主要含摩尔％的式RCH = CH 2的α-烯烃，其中R是H或C 1至C 8烷基的共聚物，和（ii）少量的摩尔％的α ，β-烯属不饱和羧酸。 季胺具有式[（R 1）（R 2）（R 3）（R 4）N] + [X] - 其中R 1选自H，芳基或任选具有一个或多个不连续C = O或NHC = O或-S-或-O-，或与R2相同; R 2，R 3和R 4各自相同或不同，并且选自H，任选被一个或多个OH取代的C 1至C 18烷基或 - （R 5 -O）a H，其中a是1至10的整数，R 5是 乙烯或丙烯; X是选自氯化物，溴化物，碘化物，氟化物，硝酸盐，氟硼酸盐，磷酸盐，C1至C8烷基磷酸盐，硫酸盐，C1至C8烷基硫酸盐，甲酸盐，C1至C8烷基或C6至C24烷芳基或芳基磺酸盐的阴离子， 乙酸盐，柠檬酸盐，三氟乙酸盐，丙酸盐，酒石酸盐或碳酸盐。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 10. 发明授权
      US5171641A Permanent antistatic acid copolymer/quaternary amine polymeric films 失效
    • Permanent antistatic acid copolymer/quaternary amine polymeric films
    • 永久抗静电酸共聚物/季胺聚合物膜
    • US5171641A
    • 1992-12-15
    • US558354
    • 1990-07-25
    • William P. Roberts , Marvin R. Havens
    • William P. Roberts , Marvin R. Havens
    • B32B27/28 , C07C211/63 , C07C217/08 , C07C303/32 , C08J5/18 , C08K5/19
    • C08J5/18 , B32B27/28 , C07C211/63 , C07C217/08 , C07C303/32 , C08K5/19 , C08J2323/02 , Y10T428/31913
    • An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.8 alkyl phosphate, sulfate, C.sub.1 to C.sub.8 alkyl sulfate, formate, C.sub.1 to C.sub.8 alkyl or C.sub.6 to C.sub.24 alkaryl or aryl sulfonate, acetate, citrate, trifluoroacetate, propionate, tartrate or carbonate.
    • 公开了一种永久抗静电的酸共聚物/季胺混合物。 酸共聚物是（i）主要含摩尔％的式RCH = CH 2的α-烯烃，其中R是H或C 1至C 8烷基的共聚物，和（ii）少量的摩尔％的α ，β-烯属不饱和羧酸。 季胺具有式[（R 1）（R 2）（R 3）（R 4）N] + [X] - 其中R 1选自H，芳基或任选具有一个或多个不连续C = O或NHC = O或-S-或-O-，或与R2相同; R 2，R 3和R 4各自相同或不同，并且选自H，任选被一个或多个OH取代的C 1至C 18烷基或 - （R 5 -O）a H，其中a是1至10的整数，R 5是 乙烯或丙烯; X为阴离子，选自氯化物，溴化物，碘化物，硝酸盐，氟硼酸盐，磷酸盐，C1至C8烷基磷酸盐，硫酸盐，C1至C8烷基硫酸盐，甲酸盐，C1至C8烷基或C6至C24烷芳基或芳基磺酸盐， 柠檬酸盐，三氟乙酸盐，丙酸盐，酒石酸盐或碳酸盐。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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